Tris-decylalumane
C30H63Al
tris-decylalumane
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Identification
- CAS Number
- 1726-66-5
- EC Number
- 217-040-1
- UN Number
- 3394
- Index Number
- 013-004-00-2
- PubChem CID
- 16682965
Physical-chemical properties
- Molecular Formula
- C30H63Al
- Molar Mass
- 450.80 g/mol
- IUPAC Name
- tris-decylalumane
Chemical Identifiers
- InChI
- InChI=1S/3C10H21.Al/c3*1-3-5-7-9-10-8-6-4-2;/h3*1,3-10H2,2H3;
- InChI Key
- USJZIJNMRRNDPO-UHFFFAOYSA-N
Overview
Tris-decylalumane (CAS 1726-66-5) is an organoaluminum compound with three long-chain decyl groups attached to an aluminum center, exhibiting pyrophoric properties and high reactivity. This specialized organoaluminum compound represents a significant advancement in organometallic chemistry, featuring an aluminum atom covalently bonded to three decyl chains (C₁₀H₂₁). With a molecular formula of C₃₀H₆₃Al and molecular weight of 450.8 g/mol, tris-decylalumane belongs to the trialkylaluminum family, which includes related compounds such as tripropylalumane and trioctylalumane. The extended carbon chain length of the decyl groups distinguishes this compound from shorter-chain analogs, imparting unique solubility characteristics and reactivity profiles. The compound exhibits typical organoaluminum properties, including high sensitivity to moisture and oxygen, necessitating careful handling under inert atmosphere conditions. Its classification under ADR Class 4.2 indicates its pyrophoric nature, meaning it can spontaneously ignite upon contact with air. This reactivity stems from the highly polarized aluminum-carbon bonds and the electron-deficient aluminum center, making it an excellent Lewis acid and alkylating agent. Primary industrial applications include its use as a catalyst in polymerization processes, particularly in the production of polyolefins where precise molecular weight control is essential. The compound also serves as an alkylating agent in organic synthesis and as a cocatalyst in Ziegler-Natta catalytic systems. Additionally, it finds application in specialty chemical manufacturing where controlled reactivity and selectivity are paramount. OYSI maintains reliable supply chains for tris-decylalumane, ensuring consistent availability for European industrial customers requiring this specialized organoaluminum compound.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 3394 |
| ADR Class | 4.2 |
| Packing Group | I |
| Tunnel Code | B/E |
| Proper Shipping Name | Tridecylaluminium, flüssig, pyrophor |
| Marine Pollutant | No |
Frequently Asked Questions
What is tris-decylalumane?
Tris-decylalumane is an organoaluminum compound with the molecular formula C30H63Al and CAS number 1726-66-5. This chemical consists of an aluminum atom bonded to three decyl groups (C10H21), making it a trialkylaluminum compound with a molecular weight of 450.8 g/mol. It belongs to the family of organometallic compounds and is characterized by its high reactivity due to the aluminum-carbon bonds.
What are the physicochemical properties of tris-decylalumane?
Tris-decylalumane is typically a colorless to pale yellow liquid at room temperature with low volatility due to its high molecular weight of 450.8 g/mol. As an organoaluminum compound, it is highly sensitive to moisture and air, reacting vigorously with water and alcohols. It is soluble in non-polar organic solvents such as hydrocarbons and ethers but must be handled under inert atmosphere conditions.
What is tris-decylalumane used for?
Tris-decylalumane is primarily used as a catalyst or co-catalyst in polymerization reactions, particularly in the production of polyolefins and other synthetic polymers. It serves as an alkylating agent in organic synthesis and can be employed in Ziegler-Natta catalysis systems. Additionally, it finds applications in the preparation of other organometallic compounds and as a reducing agent in specialized chemical processes.
How to handle tris-decylalumane safely?
Tris-decylalumane must be handled under strict inert atmosphere conditions using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent exposure to vapors. Due to its pyrophoric nature (ADR class 4.2), avoid contact with air, moisture, and oxidizing materials. Always use proper transfer techniques and inert gas protection.
How to store tris-decylalumane correctly?
Tris-decylalumane must be stored under inert atmosphere (nitrogen or argon) in tightly sealed containers to prevent contact with moisture and air. Storage areas should be cool, dry, and well-ventilated, away from heat sources, oxidizing agents, and incompatible materials. As a Group I dangerous good (ADR 4.2), it requires specialized storage conditions with appropriate fire prevention measures and emergency response equipment readily available.
What to do in case of contact with tris-decylalumane?
Tris-decylalumane contact requires immediate action due to its reactive nature. For skin contact, do not use water - instead brush off any solid material and seek immediate medical attention. In case of eye contact, flush with mineral oil (never water) and get emergency medical care. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention while providing safety data sheet to medical personnel.
How to dispose of tris-decylalumane appropriately?
Tris-decylalumane disposal must comply with local and national hazardous waste regulations due to its reactive and pyrophoric properties. Small quantities should be carefully quenched with suitable solvents under controlled conditions by trained personnel. Larger quantities require professional hazardous waste disposal services. Never dispose of in regular waste streams or pour down drains. Contact specialized chemical waste disposal companies for safe destruction and regulatory compliance.
How to transport tris-decylalumane?
Tris-decylalumane is classified under ADR as Class 4.2 (substances liable to spontaneous combustion), Packing Group I, indicating high danger level. Transportation requires specialized packaging meeting UN specifications, proper labeling with hazard placards, and compliance with dangerous goods regulations. Shipments must be accompanied by proper documentation including safety data sheets and emergency response information. Only certified dangerous goods carriers should handle transportation.
Is tris-decylalumane subject to particular regulations?
Tris-decylalumane is subject to various chemical regulations including REACH registration requirements in Europe for manufacture, import, and use above threshold quantities. While not currently listed as a SVHC (Substance of Very High Concern), it must comply with CLP regulation for classification and labeling. Additional workplace safety regulations apply due to its hazardous properties, and environmental regulations govern its disposal and emissions.
Where to buy tris-decylalumane in Europe?
Tris-decylalumane is available through OYSI, a specialized European distributor of technical chemicals with expertise in organometallic compounds. As a professional chemical supplier, OYSI can provide this specialized reagent with proper documentation, safety data sheets, and technical support. Contact OYSI directly for availability, specifications, and regulatory compliance information. Due to the specialized nature of this compound, sourcing through experienced distributors ensures proper handling and documentation.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.