Tridodecylalumane

C36H75Al

tridodecylalumane

CAS1529-59-5

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Identification

CAS Number
1529-59-5
EC Number
216-219-1
UN Number
3394
Index Number
013-004-00-2
PubChem CID
16682963

Physical-chemical properties

Molecular Formula
C36H75Al
Molar Mass
535.00 g/mol
IUPAC Name
tridodecylalumane

Chemical Identifiers

InChI
InChI=1S/3C12H25.Al/c3*1-3-5-7-9-11-12-10-8-6-4-2;/h3*1,3-12H2,2H3;
InChI Key
XBEXIHMRFRFRAM-UHFFFAOYSA-N

Overview

Tridodecylalumane (CAS 1529-59-5) is an organoaluminum compound characterized by three long dodecyl chains attached to a central aluminum atom. This specialized organoaluminum compound belongs to the family of trialkylaluminum derivatives, featuring three twelve-carbon alkyl chains bonded to aluminum. With a molecular formula of C36H75Al and molecular weight of 535 g/mol, tridodecylalumane represents one of the higher molecular weight members in this chemical class. The compound's structure consists of aluminum as the central metal atom coordinated with three dodecyl groups, providing unique properties that distinguish it from shorter-chain analogs such as tripropylalumane or trioctylalumane. Due to its organoaluminum nature, tridodecylalumane exhibits pyrophoric characteristics, classified under ADR Class 4.2 for spontaneously combustible substances. The compound requires careful handling under inert atmosphere conditions to prevent oxidation and potential ignition upon contact with air or moisture. The long dodecyl chains contribute to its lipophilic properties and influence its reactivity profile compared to other trialkylaluminum compounds. In industrial applications, tridodecylalumane serves primarily as a catalyst component in polymerization processes, particularly in the production of polyolefins where its extended alkyl chains can influence polymer characteristics. The compound also finds use as a co-catalyst in Ziegler-Natta catalysis systems and as an alkylating agent in specialized organic synthesis reactions. Additionally, it functions as a precursor for aluminum-containing materials in advanced manufacturing processes. OYSI maintains reliable supply chains for tridodecylalumane and related organoaluminum compounds, ensuring consistent availability for industrial customers across European markets requiring specialized catalyst systems and advanced chemical intermediates.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number3394
ADR Class4.2
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameTridodecylaluminium, flüssig, pyrophor
Marine PollutantNo

Frequently Asked Questions

What is tridodecylalumane?

Tridodecylalumane is an organoaluminum compound with the molecular formula C36H75Al and CAS number 1529-59-5. This chemical consists of an aluminum atom bonded to three dodecyl groups (C12H25), creating a large organometallic molecule with a molecular weight of 535 g/mol. It belongs to the family of trialkylaluminum compounds, which are important in various industrial applications requiring aluminum-carbon bonds.

What are the physicochemical properties of tridodecylalumane?

Tridodecylalumane is typically a viscous liquid or waxy solid at room temperature due to its high molecular weight and long alkyl chains. The compound is highly sensitive to moisture and air, readily reacting with water and oxygen. It exhibits low solubility in polar solvents but dissolves well in non-polar organic solvents like hydrocarbons. The presence of three long dodecyl chains gives it amphiphilic properties.

What is tridodecylalumane used for?

Tridodecylalumane is primarily used as a catalyst or co-catalyst in polymerization reactions, particularly in the production of polyolefins. It serves as an alkylating agent in organic synthesis and as a precursor for preparing other organoaluminum compounds. The compound is also utilized in materials science for surface modification and as a coupling agent to improve adhesion between organic and inorganic materials in composite manufacturing.

How to handle tridodecylalumane safely?

Tridodecylalumane must be handled under inert atmosphere (nitrogen or argon) to prevent reaction with moisture and oxygen. Wear appropriate PPE including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods. Avoid contact with water, alcohols, and acids as these can cause violent reactions. Use dry, clean equipment and ensure all containers are properly sealed to maintain product integrity.

How to store tridodecylalumane correctly?

Tridodecylalumane should be stored in tightly sealed containers under inert atmosphere in a cool, dry place away from moisture, heat, and ignition sources. Keep containers in secondary containment to prevent spills. Store separately from water, alcohols, acids, and oxidizing agents to avoid incompatible reactions. Maintain storage temperature below 25°C and ensure adequate ventilation in storage areas to prevent accumulation of any vapors.

What to do in case of contact with tridodecylalumane?

Tridodecylalumane contact requires immediate action due to its reactive nature. For skin contact, remove contaminated clothing and flush affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse immediately with water and seek medical attention. If inhaled, move to fresh air immediately. Never use water directly on large spills as this may cause violent reactions. Seek medical attention for all exposures.

How to dispose of tridodecylalumane appropriately?

Tridodecylalumane waste must be disposed of according to local and national hazardous waste regulations. The compound should be carefully quenched with appropriate alcohols or other compatible reagents under controlled conditions by trained personnel. Resulting waste should be collected and disposed of through licensed hazardous waste contractors. Never dispose of untreated material in sewers, soil, or regular waste streams due to its reactive nature.

How to transport tridodecylalumane?

Tridodecylalumane is classified under ADR Class 4.2 (Substances liable to spontaneous combustion), Packing Group I, indicating high danger level. Transportation requires specialized packaging meeting UN specifications for spontaneously combustible substances. Packages must be properly labeled, marked, and accompanied by appropriate shipping documents. Only trained personnel should handle transportation, and vehicles must comply with ADR requirements for Class 4.2 dangerous goods.

Is tridodecylalumane subject to specific regulations?

Tridodecylalumane is subject to REACH regulation in Europe, requiring registration for commercial use above specified tonnages. While not classified as SVHC (Substance of Very High Concern), it must comply with CLP regulation for classification, labeling, and packaging. Users must maintain safety data sheets and ensure proper risk assessments. Transport is regulated under ADR/RID for dangerous goods, and workplace exposure may be subject to occupational health regulations.

Where to buy tridodecylalumane in Europe?

Tridodecylalumane is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this organoaluminum compound with proper documentation, safety data sheets, and regulatory compliance for European markets. As a professional chemical distributor, OYSI ensures appropriate packaging, handling, and delivery according to ADR transport requirements. Contact OYSI directly for availability, specifications, and technical support for your tridodecylalumane requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.