Bromo(dimethyl)alumane;dibromo(methyl)alumane
C3H9Al2Br3
bromo(dimethyl)alumane;dibromo(methyl)alumane
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Identification
- CAS Number
- 12263-85-3
- EC Number
- 235-532-4
- UN Number
- 3394
- PubChem CID
- 25541
Physical-chemical properties
- Molecular Formula
- C3H9Al2Br3
- Molar Mass
- 338.78 g/mol
- IUPAC Name
- bromo(dimethyl)alumane;dibromo(methyl)alumane
Chemical Identifiers
- InChI
- InChI=1S/3CH3.2Al.3BrH/h3*1H3;;;3*1H/q;;;+1;+2;;;/p-3
- InChI Key
- NZIXICKPQWIFAU-UHFFFAOYSA-K
Overview
Bromo(dimethyl)alumane;dibromo(methyl)alumane (CAS 12263-85-3) is an organoaluminum compound mixture featuring reactive aluminum-carbon bonds and bromide substituents. This specialized organoaluminum compound represents a mixture of two distinct but related aluminum-containing species, characterized by the molecular formula C3H9Al2Br3 and a molecular weight of 338.78 g/mol. The EC number 235-532-4 identifies this compound within European chemical regulations. As an organoaluminum compound, it belongs to a class of highly reactive chemical intermediates that play crucial roles in various industrial processes, particularly in catalysis and organic synthesis applications. The compound's structure incorporates both methyl groups and bromine atoms bonded to aluminum centers, creating a unique reactivity profile that distinguishes it from simpler organoaluminum compounds like tris(2-methylpropyl)alumane or tripropylalumane. The presence of bromine substituents significantly influences the compound's reactivity and handling characteristics compared to fully alkylated aluminum compounds. Safety considerations are paramount when working with this material, as indicated by its ADR classification 4.2, which designates it as a substance liable to spontaneous combustion. This classification reflects the compound's high reactivity, particularly toward moisture and oxygen, requiring specialized storage and handling procedures under inert atmosphere conditions. Personnel must implement appropriate safety protocols including the use of dry, oxygen-free environments and proper protective equipment. Industrial applications typically include use as a catalyst component in polymerization reactions, as a reducing agent in specialized organic synthesis, and as an intermediate in the production of other organoaluminum compounds. The compound's unique brominated structure makes it particularly valuable in selective organic transformations where controlled reactivity is essential. OYSI maintains availability of bromo(dimethyl)alumane;dibromo(methyl)alumane through its European distribution network, supporting customers with technical expertise and proper handling guidance.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 3394 |
| ADR Class | 4.2 |
| Packing Group | I |
| Tunnel Code | B/E |
| Proper Shipping Name | Methylaluminiumsesquibromid, flüssig, pyrophor |
| Marine Pollutant | No |
Frequently Asked Questions
What is bromo(dimethyl)alumane;dibromo(methyl)alumane?
Bromo(dimethyl)alumane;dibromo(methyl)alumane is an organoaluminum compound with the molecular formula C3H9Al2Br3 and CAS number 12263-85-3. This chemical substance has a molecular weight of 338.78 g/mol and consists of aluminum atoms bonded to both methyl groups and bromine atoms. It belongs to the family of organoaluminum halides, which are important intermediates in organometallic chemistry and industrial processes.
What are the physicochemical properties of bromo(dimethyl)alumane;dibromo(methyl)alumane?
Bromo(dimethyl)alumane;dibromo(methyl)alumane is an organoaluminum compound that typically exists as a liquid or solid at room temperature. Like most organoaluminum compounds, it is highly reactive with water and moisture, potentially releasing flammable gases. The compound is sensitive to air and humidity, requiring inert atmosphere handling. Its exact physical appearance, odor, and solubility characteristics depend on storage conditions and purity levels.
What is bromo(dimethyl)alumane;dibromo(methyl)alumane used for?
Bromo(dimethyl)alumane;dibromo(methyl)alumane is primarily used as a reagent in organometallic synthesis and as an intermediate in the production of other aluminum-containing compounds. It serves applications in catalysis, particularly in polymerization reactions and organic transformations. The compound may also be utilized in specialized chemical manufacturing processes where controlled introduction of aluminum and bromine functionalities is required in molecular structures.
How to safely handle bromo(dimethyl)alumane;dibromo(methyl)alumane?
Bromo(dimethyl)alumane;dibromo(methyl)alumane must be handled under inert atmosphere conditions using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or fume hoods to prevent exposure to potentially harmful vapors. Avoid contact with water, moisture, and incompatible materials. Use proper laboratory techniques for handling air-sensitive and potentially pyrophoric organometallic compounds.
How to properly store bromo(dimethyl)alumane;dibromo(methyl)alumane?
Bromo(dimethyl)alumane;dibromo(methyl)alumane should be stored in tightly sealed containers under inert atmosphere, protected from moisture and air. Storage areas must be cool, dry, and well-ventilated, away from heat sources and incompatible materials such as water, alcohols, and oxidizing agents. The compound falls under ADR class 4.2 (substances liable to spontaneous combustion), requiring appropriate hazardous material storage protocols and segregation from other chemical classes.
What to do in case of contact with bromo(dimethyl)alumane;dibromo(methyl)alumane?
In case of skin contact with bromo(dimethyl)alumane;dibromo(methyl)alumane, immediately remove contaminated clothing and rinse the affected area with plenty of water for at least 15 minutes. For eye contact, flush thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. Do not use water directly on spilled material due to potential violent reaction. Seek professional medical advice in all exposure cases.
How to properly dispose of bromo(dimethyl)alumane;dibromo(methyl)alumane?
Bromo(dimethyl)alumane;dibromo(methyl)alumane must be disposed of according to local and national hazardous waste regulations as it contains aluminum and bromine compounds. The material should be carefully neutralized by trained personnel using appropriate quenching agents under controlled conditions. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Never dispose of this substance through regular waste streams or pour down drains due to its reactive nature.
How to transport bromo(dimethyl)alumane;dibromo(methyl)alumane?
Bromo(dimethyl)alumane;dibromo(methyl)alumane is classified under ADR class 4.2 (substances liable to spontaneous combustion), packing group I, indicating high transport hazard. Transportation requires specialized packaging, proper labeling, and documentation according to dangerous goods regulations. Shipments must comply with ADR/RID requirements for road/rail transport and IMDG/IATA codes for sea/air transport. Only authorized carriers experienced in handling pyrophoric materials should transport this substance.
Is bromo(dimethyl)alumane;dibromo(methyl)alumane subject to specific regulations?
Bromo(dimethyl)alumane;dibromo(methyl)alumane is subject to REACH regulation as a chemical substance manufactured or imported in the EU. It is not currently listed as a Substance of Very High Concern (SVHC). The compound must comply with CLP regulation for classification, labeling, and packaging requirements. Additionally, its ADR class 4.2 classification subjects it to dangerous goods transport regulations and specific handling requirements in industrial and laboratory settings.
Where to buy bromo(dimethyl)alumane;dibromo(methyl)alumane in Europe?
Bromo(dimethyl)alumane;dibromo(methyl)alumane is available through OYSI, a specialized European distributor of technical chemicals and organometallic compounds. OYSI provides high-quality chemical products to industrial and research customers across Europe, ensuring proper handling, packaging, and regulatory compliance. As a specialty organoaluminum compound, it requires sourcing from experienced suppliers who understand the technical requirements and safety considerations associated with reactive organometallic materials.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.