Sodium chlorate

ClNaO3

sodium chlorate

CAS7775-09-9
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
Danger

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Identification

CAS Number
7775-09-9
EC Number
231-887-4
UN Number
1495
Index Number
017-005-00-9
PubChem CID
516902

Physical-chemical properties

Molecular Formula
ClNaO3
Molar Mass
106.44 g/mol
IUPAC Name
sodium chlorate

Chemical Identifiers

InChI
InChI=1S/ClHO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
InChI Key
YZHUMGUJCQRKBT-UHFFFAOYSA-M

Overview

Sodium chlorate (CAS 7775-09-9) is an inorganic oxidizing salt with strong oxidative properties and high solubility in water. This white crystalline compound serves as one of the most important industrial oxidizing agents in modern chemical processes. Sodium chlorate belongs to the chlorate family of compounds, sharing similar oxidative characteristics with related substances like potassium chlorate, though it offers superior water solubility and handling properties. The compound readily dissolves in water to form clear, colorless solutions that maintain stability under normal storage conditions. The primary safety considerations for sodium chlorate stem from its powerful oxidizing nature, classified as Oxidizing Solid Category 1 under GHS regulations. This classification requires careful handling protocols, as the substance can intensify fires and may cause combustible materials to ignite more readily. Additionally, its Acute Toxicity Category 3 classification necessitates appropriate personal protective equipment during handling and storage. The compound must be kept away from reducing agents, organic materials, and heat sources to prevent dangerous reactions. Industrial applications of sodium chlorate center primarily around pulp and paper manufacturing, where it serves as a bleaching agent in chlorine dioxide generation systems. The textile industry utilizes this compound for fabric bleaching processes, while the chemical manufacturing sector employs it as an intermediate in various oxidation reactions. Water treatment facilities also incorporate sodium chlorate in specific purification processes. OYSI maintains regular stock availability of technical-grade sodium chlorate to support diverse industrial applications across European markets, ensuring consistent supply for manufacturing operations requiring reliable oxidizing agents.

Safety & Classification

Danger
Classification:

Ox. Sol. 1; Acute Tox. 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H271

May cause fire or explosion; strong oxidiser.

H301

Toxic if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1495
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameNatriumchlorat, fest
Marine PollutantNo

Frequently Asked Questions

What is sodium chlorate?

Sodium chlorate is an inorganic chemical compound with the formula ClNaO3 and CAS number 7775-09-9. It has a molecular weight of 106.44 g/mol and appears as a white crystalline solid. This oxidizing substance is classified as dangerous, with GHS pictograms GHS03 (oxidizing) and GHS06 (toxic). It poses acute toxicity risks and belongs to the oxidizing solids category 1, requiring careful handling in industrial applications.

What are the physicochemical properties of sodium chlorate?

Sodium chlorate is a white crystalline solid that is highly soluble in water. It has a molecular weight of 106.44 g/mol and is odorless. The compound is hygroscopic, meaning it readily absorbs moisture from the air. It decomposes when heated, releasing oxygen gas. As a strong oxidizing agent, it can react vigorously with combustible materials, organic substances, and reducing agents, making it potentially hazardous during storage and handling.

What is sodium chlorate used for?

Sodium chlorate is primarily used as a herbicide and defoliant in agriculture, effectively controlling weeds and facilitating crop harvesting. It serves as an oxidizing agent in various chemical processes and is utilized in the production of chlorine dioxide for water treatment and bleaching applications. The compound is also employed in the manufacturing of matches, explosives, and fireworks due to its oxidizing properties, though its use is highly regulated.

How to handle sodium chlorate safely?

Sodium chlorate requires strict safety measures due to its oxidizing and toxic properties. Personnel must wear appropriate PPE including chemical-resistant gloves, safety goggles, and protective clothing. Work areas should be well-ventilated to prevent dust accumulation. Avoid contact with combustible materials, reducing agents, and organic substances. Use non-sparking tools and equipment. Ensure emergency shower and eyewash facilities are readily available. Never smoke or allow open flames near the substance.

How to store sodium chlorate correctly?

Sodium chlorate must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly sealed to prevent moisture absorption. Store separately from combustible materials, organic substances, acids, and reducing agents to prevent dangerous reactions. Use fire-resistant storage areas with appropriate ventilation systems. Containers should be made of compatible materials and properly labeled. Implement appropriate fire detection and suppression systems in storage areas.

What to do in case of contact with sodium chlorate?

Immediate action is required upon contact with sodium chlorate. For skin contact, remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention. For eye contact, flush with clean water for at least 15 minutes while holding eyelids open. If ingested, do not induce vomiting and seek immediate medical attention. Always consult medical professionals promptly.

How to dispose of sodium chlorate appropriately?

Sodium chlorate disposal must comply with local and national environmental regulations as hazardous waste. Contact licensed waste disposal companies specializing in oxidizing substances. Never dispose of in regular trash, sewers, or water systems. Small quantities may be neutralized by qualified personnel following approved procedures. All disposal activities must be documented and reported according to regulatory requirements. Containers must be completely emptied and decontaminated before disposal.

How to transport sodium chlorate?

Sodium chlorate is classified under ADR transport regulations as Class 5.1 (oxidizing substances), Packing Group II. It requires appropriate UN-specification packaging and hazard labels during transport. Vehicles must be equipped with proper ventilation and emergency equipment. Drivers need ADR certification for dangerous goods transport. The substance must be segregated from incompatible materials and secured to prevent movement during transit. Transport documents and emergency response information must accompany shipments.

Is sodium chlorate subject to specific regulations?

Sodium chlorate is subject to comprehensive regulations under REACH, CLP, and various national legislations. It requires safety data sheets and hazard classification as Ox. Sol. 1 and Acute Tox. 3. While not currently listed as SVHC, its use is restricted in certain applications. Employers must implement risk assessments and control measures. The substance may require registration or notification depending on quantities handled. Users must comply with occupational exposure limits and environmental protection requirements.

Where to buy sodium chlorate in Europe?

Sodium chlorate is available through OYSI, a European distributor specializing in technical chemicals. As an established supplier, OYSI provides quality sodium chlorate with proper documentation including safety data sheets and certificates of analysis. Their European distribution network ensures reliable supply and regulatory compliance. For procurement inquiries, specifications, and availability, contact OYSI directly through their official channels to discuss your specific requirements and quantities needed for industrial applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.