Propa-1,2-diene

C3H4

propa-1,2-diene

CAS463-49-0

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Identification

CAS Number
463-49-0
EC Number
207-335-3
UN Number
2200
PubChem CID
10037

Physical-chemical properties

Molecular Formula
C3H4
Molar Mass
40.06 g/mol
IUPAC Name
propa-1,2-diene

Chemical Identifiers

InChI
InChI=1S/C3H4/c1-3-2/h1-2H2
InChI Key
IYABWNGZIDDRAK-UHFFFAOYSA-N

Overview

Propa-1,2-diene (CAS 463-49-0) is an allene hydrocarbon featuring two adjacent double bonds and highly reactive chemical properties. This unique three-carbon compound, also known by its IUPAC name propa-1,2-diene, represents the simplest member of the allene family with the molecular formula C3H4 and a molecular weight of 40.06 g/mol. The distinctive structural feature of this compound lies in its cumulated double bond system, where the central carbon atom forms double bonds with both adjacent carbons, creating a linear geometry with perpendicular π-systems. This unusual bonding arrangement makes propa-1,2-diene significantly more reactive than conventional alkenes and provides it with distinctive chemical behavior in organic synthesis. As a gaseous compound under standard conditions, propa-1,2-diene is classified under ADR class 2, indicating its nature as a compressed or liquefied gas requiring specialized handling procedures. The compound's high reactivity stems from the inherent strain in its cumulated double bond system, making it an excellent building block for various chemical transformations. Unlike simpler gases such as nitrous oxide, propa-1,2-diene readily participates in cycloaddition reactions and polymerization processes due to its unique electronic structure. The primary industrial applications of propa-1,2-diene include its use as a specialty monomer in polymer synthesis, particularly for creating materials with unique mechanical properties. It also serves as an important intermediate in organic synthesis for pharmaceutical and fine chemical production, where its reactive allene functionality enables the construction of complex molecular frameworks. Additionally, the compound finds application in specialty coating formulations where its polymerization characteristics contribute to enhanced film properties. OYSI provides propa-1,2-diene to European industrial customers requiring high-purity allene compounds for specialized chemical processes and research applications.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2200
ADR Class2
Packing Group
Tunnel CodeB/D
Proper Shipping NamePropadien, stabilisiert, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is propa-1,2-diene?

Propa-1,2-diene is an organic compound with the molecular formula C3H4 and CAS number 463-49-0. It belongs to the allene family, characterized by two adjacent double bonds in its carbon chain structure. With a molecular weight of 40.06 g/mol, this hydrocarbon is also known as allene in its simplest form. It represents an important building block in organic chemistry due to its unique cumulative double bond system, making it valuable for various synthetic applications.

What are the physicochemical properties of propa-1,2-diene?

Propa-1,2-diene is a gaseous hydrocarbon at room temperature and atmospheric pressure. It appears as a colorless gas with a characteristic hydrocarbon odor. The compound has limited solubility in water but dissolves readily in organic solvents such as alcohols and ethers. Its unique allene structure gives it distinctive reactivity patterns, particularly in cycloaddition reactions. The molecule exhibits high reactivity due to the strain associated with its cumulative double bond system.

What is propa-1,2-diene used for?

Propa-1,2-diene serves primarily as an intermediate in organic synthesis and chemical manufacturing processes. It is utilized in the production of specialized polymers, pharmaceuticals, and fine chemicals. The compound finds applications in research laboratories for studying reaction mechanisms involving cumulative double bonds. In industrial settings, it acts as a building block for synthesizing more complex organic molecules, particularly in the development of new materials and chemical compounds with specific properties.

How to handle propa-1,2-diene safely?

Propa-1,2-diene should be handled in well-ventilated areas or under fume hoods to prevent gas accumulation. Operators must wear appropriate personal protective equipment including safety glasses, chemical-resistant gloves, and protective clothing. Since it's a flammable gas, eliminate all ignition sources in the work area. Use proper gas-tight equipment and connections to prevent leaks. Regular monitoring for gas concentrations and maintaining good ventilation are essential safety practices when working with this compound.

How to store propa-1,2-diene correctly?

Propa-1,2-diene must be stored in appropriate gas cylinders or pressure vessels designed for flammable gases. Storage areas should be cool, dry, and well-ventilated, away from heat sources and ignition points. The compound should be kept separate from strong oxidizing agents and other incompatible materials. Storage facilities must comply with local regulations for flammable gas storage, including proper labeling, temperature control, and emergency response equipment availability.

What to do in case of contact with propa-1,2-diene?

Propa-1,2-diene exposure primarily occurs through inhalation since it's a gas at room temperature. If inhaled, immediately move the affected person to fresh air and seek medical attention if breathing difficulties occur. In case of skin or eye contact with liquid form (under pressure), flush immediately with plenty of water for at least 15 minutes and seek medical advice. Remove contaminated clothing and wash thoroughly before reuse. Always consult emergency services for severe exposures.

How to dispose of propa-1,2-diene appropriately?

Propa-1,2-diene disposal must comply with local environmental regulations and waste management guidelines. Small quantities can be carefully vented in well-ventilated areas away from ignition sources, following proper safety protocols. Larger amounts should be handled by licensed waste disposal companies specializing in flammable gas treatment. Never release the compound directly into the environment. Contact local environmental authorities for specific disposal requirements and approved waste management facilities in your region.

How to transport propa-1,2-diene?

Propa-1,2-diene is classified under ADR Class 2 for gases, requiring specialized transport procedures for flammable gases. Transportation must use appropriate pressure vessels or gas cylinders designed for this classification. Vehicles must display proper hazard placards and carry necessary documentation. Drivers need hazardous materials training and certification. The compound requires temperature-controlled transport conditions and must be secured to prevent movement during transit. Always follow international dangerous goods regulations for gas transport.

Is propa-1,2-diene subject to particular regulations?

Propa-1,2-diene is subject to standard chemical regulations including REACH registration requirements in Europe for commercial use above specified tonnages. It falls under CLP regulation for classification, labeling, and packaging, though it currently shows no specific hazard classifications. The compound is not listed as a SVHC (Substance of Very High Concern). Users must comply with local workplace safety regulations, environmental protection laws, and transportation requirements for flammable gases.

Where to buy propa-1,2-diene in Europe?

Propa-1,2-diene is available through specialized chemical distributors across Europe, including OYSI, a leading European distributor of technical chemicals. OYSI provides reliable supply chains for research institutions, pharmaceutical companies, and industrial manufacturers requiring this compound. When sourcing propa-1,2-diene, ensure the supplier meets quality standards and regulatory compliance requirements. Contact chemical distributors directly for availability, specifications, packaging options, and delivery arrangements suitable for your specific application needs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.