Naphtho[1,2-b]phenanthrene

C22H14

naphtho[1,2-b]phenanthrene

CAS53-70-3
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
53-70-3
EC Number
200-181-8
UN Number
3077
Index Number
601-041-00-2
PubChem CID
5889

Physical-chemical properties

Molecular Formula
C22H14
Molar Mass
278.30 g/mol
IUPAC Name
naphtho[1,2-b]phenanthrene

Chemical Identifiers

InChI
InChI=1S/C22H14/c1-3-7-19-15(5-1)9-11-17-14-22-18(13-21(17)19)12-10-16-6-2-4-8-20(16)22/h1-14H
InChI Key
LHRCREOYAASXPZ-UHFFFAOYSA-N

Overview

Naphtho[1,2-b]phenanthrene (CAS 53-70-3) is a polycyclic aromatic hydrocarbon with significant carcinogenic properties and environmental persistence concerns. This complex aromatic compound, also known by its EC number 200-181-8, represents a highly condensed polycyclic structure consisting of fused benzene rings arranged in a specific naphtho-phenanthrene configuration. With a molecular formula of C22H14 and molecular weight of 278.3 g/mol, naphtho[1,2-b]phenanthrene belongs to the family of polycyclic aromatic hydrocarbons (PAHs) that are characterized by their stable ring systems and limited biodegradability. The compound exhibits classification as Carcinogenic Category 1B under the CLP regulation, indicating strong evidence for carcinogenic potential in humans. Additionally, it carries Aquatic Acute 1 and Aquatic Chronic 1 classifications, reflecting its severe environmental impact on aquatic ecosystems. The GHS08 and GHS09 pictograms emphasize both health hazards and environmental dangers, while the "Danger" signal word indicates the highest level of hazard severity. Transportation falls under ADR Class 9 for miscellaneous dangerous substances. Safety considerations require stringent handling protocols due to the carcinogenic nature and environmental persistence of this compound. Like related PAH compounds such as benzo[e]pyrene, naphtho[1,2-b]phenanthrene demonstrates significant bioaccumulation potential and resistance to degradation processes. Primary industrial applications include research in organic synthesis, development of specialized materials, and analytical reference standards for environmental monitoring. The compound serves as an important intermediate in certain chemical manufacturing processes and finds use in academic research focused on PAH behavior and toxicology studies. OYSI maintains reliable supply chains for naphtho[1,2-b]phenanthrene to support European industrial and research requirements.

Safety & Classification

Danger
Classification:

Carc. 1B; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H350

May cause cancer.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameDibenz[a,h]anthracen
Marine PollutantNo

Frequently Asked Questions

What is naphtho[1,2-b]phenanthrene?

Naphtho[1,2-b]phenanthrene is a polycyclic aromatic hydrocarbon (PAH) with the molecular formula C22H14 and CAS number 53-70-3. This complex organic compound consists of fused benzene rings forming a characteristic naphtho-phenanthrene structure. With a molecular weight of 278.3 g/mol, it belongs to a class of compounds known for their carcinogenic properties and environmental persistence.

What are the physicochemical properties of naphtho[1,2-b]phenanthrene?

Naphtho[1,2-b]phenanthrene is typically a crystalline solid at room temperature with a characteristic aromatic structure. As a polycyclic aromatic hydrocarbon, it exhibits low water solubility but dissolves in organic solvents like benzene and toluene. The compound has a relatively high melting point due to its extensive π-electron system and intermolecular interactions typical of PAH compounds.

What is naphtho[1,2-b]phenanthrene used for?

Naphtho[1,2-b]phenanthrene is primarily used in research applications and as an intermediate in organic synthesis. It serves as a starting material for the production of specialized dyes, pharmaceuticals, and other complex organic compounds. Due to its carcinogenic classification (Carc. 1B), its industrial applications are limited and strictly controlled, with most uses confined to laboratory research and specialized chemical manufacturing processes.

How to handle naphtho[1,2-b]phenanthrene safely?

Naphtho[1,2-b]phenanthrene requires strict safety measures due to its carcinogenic properties (GHS08 pictogram). Workers must wear appropriate personal protective equipment including respiratory protection, chemical-resistant gloves, and protective clothing. Handle only in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin contact and ensure proper training on carcinogenic substance handling procedures before use.

How to store naphtho[1,2-b]phenanthrene correctly?

Naphtho[1,2-b]phenanthrene should be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Use tightly sealed containers to prevent environmental release, considering its aquatic toxicity classification (GHS09). Store in designated areas for carcinogenic substances with restricted access and appropriate labeling. Maintain storage conditions that prevent degradation and minimize exposure risks to personnel and environment.

What to do in case of contact with naphtho[1,2-b]phenanthrene?

Immediate action is required due to the carcinogenic nature of naphtho[1,2-b]phenanthrene. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water. In case of eye contact, rinse immediately with plenty of clean water for at least 15 minutes. If inhaled, move to fresh air immediately. Seek medical attention promptly and inform healthcare providers about the carcinogenic properties of the substance.

How to dispose of naphtho[1,2-b]phenanthrene properly?

Naphtho[1,2-b]phenanthrene requires disposal as hazardous waste due to its carcinogenic and aquatic toxic properties. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Never dispose of this substance through regular waste streams or release into the environment. Follow local and national regulations for carcinogenic waste disposal, including proper documentation and tracking requirements throughout the disposal process.

How to transport naphtho[1,2-b]phenanthrene?

Naphtho[1,2-b]phenanthrene is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation. Packages must be properly labeled with appropriate hazard pictograms (GHS08, GHS09) and danger signal word. Use approved packaging that prevents leakage and environmental contamination. Transport documentation must include proper shipping names, hazard classes, and emergency response information according to ADR regulations.

Is naphtho[1,2-b]phenanthrene subject to specific regulations?

Naphtho[1,2-b]phenanthrene is subject to strict regulations under CLP Regulation due to its classification as Carc. 1B and aquatic toxicity. It falls under REACH registration requirements for chemical substances. While not currently listed as SVHC, its carcinogenic properties require compliance with occupational exposure limits and environmental protection measures. Specific authorization may be required for certain uses under various national and European chemical safety regulations.

Where to buy naphtho[1,2-b]phenanthrene in Europe?

Naphtho[1,2-b]phenanthrene is available through specialized chemical distributors like OYSI, a European distributor of technical chemicals. Due to its carcinogenic classification and regulatory requirements, purchase is typically restricted to qualified industrial and research users. Buyers must demonstrate appropriate handling capabilities and regulatory compliance. Contact OYSI for availability, technical specifications, and regulatory documentation required for safe handling and use.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.