Benzo[k]fluoranthene
C20H12
benzo[k]fluoranthene
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Identification
- CAS Number
- 207-08-9
- EC Number
- 205-916-6
- UN Number
- 3077
- Index Number
- 601-036-00-5
- PubChem CID
- 9158
Physical-chemical properties
- Molecular Formula
- C20H12
- Molar Mass
- 252.30 g/mol
- IUPAC Name
- benzo[k]fluoranthene
Chemical Identifiers
- InChI
- InChI=1S/C20H12/c1-2-6-15-12-19-17-10-4-8-13-7-3-9-16(20(13)17)18(19)11-14(15)5-1/h1-12H
- InChI Key
- HAXBIWFMXWRORI-UHFFFAOYSA-N
Overview
Benzo[k]fluoranthene (CAS 207-08-9) is a polycyclic aromatic hydrocarbon with five fused benzene rings and significant carcinogenic properties. This complex organic compound belongs to the family of polycyclic aromatic hydrocarbons (PAHs), characterized by its distinctive molecular structure of twenty carbon atoms arranged in a highly stable aromatic system. With a molecular formula of C20H12 and molecular weight of 252.3 g/mol, benzo[k]fluoranthene represents one of the heavier members of the PAH family, sharing structural similarities with related compounds such as benzo[e]pyrene, another well-known carcinogenic PAH used in various research applications. The compound exhibits typical PAH characteristics including low water solubility, high thermal stability, and strong fluorescent properties under UV light. However, its classification as a Category 1B carcinogen under GHS regulations requires stringent handling protocols and specialized safety measures. The substance also demonstrates significant environmental persistence and bioaccumulation potential, reflected in its Aquatic Acute 1 and Aquatic Chronic 1 hazard classifications. Primary industrial applications include its use as a reference standard in environmental analytical chemistry, particularly for monitoring PAH contamination in soil, water, and air samples. The compound serves as a crucial component in calibration mixtures for chromatographic analysis and is utilized in toxicological research studies investigating carcinogenic mechanisms. Additionally, it finds application in photochemical research due to its distinct fluorescence properties and photostability characteristics. Safety handling requires appropriate engineering controls, personal protective equipment including respiratory protection, and compliance with ADR Class 9 transportation regulations. Laboratory personnel must implement strict containment procedures to prevent both human exposure and environmental release. OYSI provides high-purity benzo[k]fluoranthene with comprehensive documentation to support analytical and research applications across European markets.
Safety & Classification
Carc. 1B; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Transport (ADR)
| UN Number | 3077 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | - |
| Proper Shipping Name | Benzo[k]fluoranthen |
| Marine Pollutant | No |
Frequently Asked Questions
What is benzo[k]fluoranthene?
Benzo[k]fluoranthene is a polycyclic aromatic hydrocarbon (PAH) with the molecular formula C20H12 and CAS number 207-08-9. This organic compound has a molecular weight of 252.3 g/mol and belongs to the family of fused benzene ring systems. It is classified as a Category 1B carcinogen and poses significant environmental hazards to aquatic life. The substance appears as a crystalline solid and is formed during incomplete combustion of organic materials.
What are the physicochemical properties of benzo[k]fluoranthene?
Benzo[k]fluoranthene is a solid crystalline compound at room temperature, typically appearing as yellowish crystals or powder. It has poor water solubility due to its hydrophobic aromatic structure but dissolves in organic solvents such as benzene, toluene, and chloroform. The compound has a high melting point characteristic of PAHs and exhibits stability under normal conditions. Its aromatic structure makes it relatively non-volatile compared to smaller hydrocarbons.
What is benzo[k]fluoranthene used for?
Benzo[k]fluoranthene is primarily used in research and analytical applications as a reference standard for environmental monitoring and toxicological studies. It serves as a marker compound for PAH contamination in environmental samples and is used in laboratory studies investigating carcinogenic mechanisms. Industrial applications are limited due to its hazardous classification, but it may be used in specialized chemical synthesis as an intermediate compound under strictly controlled conditions.
How to handle benzo[k]fluoranthene safely?
Benzo[k]fluoranthene requires strict safety measures due to its carcinogenic properties. Always wear appropriate personal protective equipment including nitrile gloves, safety goggles, and respiratory protection. Work in a well-ventilated area or fume hood to prevent inhalation exposure. Avoid skin contact and ingestion completely. Use only in designated areas with proper containment measures. All personnel must be trained in carcinogen handling procedures and emergency response protocols before working with this substance.
How to store benzo[k]fluoranthene correctly?
Benzo[k]fluoranthene must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly sealed in a designated hazardous materials storage area with restricted access. Store away from incompatible materials such as strong oxidizing agents. Maintain storage temperature below 25°C and ensure proper labeling according to GHS requirements. Implement appropriate inventory control and limit quantities to minimize exposure risks.
What to do in case of contact with benzo[k]fluoranthene?
Benzo[k]fluoranthene exposure requires immediate action due to its carcinogenic nature. For skin contact, immediately remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move person to fresh air and seek medical attention. For eye contact, flush with clean water for 15 minutes. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always inform medical personnel about the carcinogenic properties.
How to dispose of benzo[k]fluoranthene appropriately?
Benzo[k]fluoranthene disposal requires specialized hazardous waste management procedures due to its carcinogenic and environmental hazard classification. Contact licensed hazardous waste disposal companies for proper treatment and disposal. High-temperature incineration in approved facilities is typically required. Never dispose of in regular waste streams or pour down drains. Maintain detailed disposal records and follow all local, national, and EU waste regulations including the Waste Framework Directive.
How to transport benzo[k]fluoranthene?
Benzo[k]fluoranthene is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transport purposes. Packages must be properly labeled with appropriate hazard markings and UN numbers. Use approved packaging materials and ensure containers are leak-proof and properly sealed. Transport vehicles must comply with ADR regulations and drivers require appropriate training. Shipping documentation must include proper shipping names, hazard classes, and emergency contact information.
Is benzo[k]fluoranthene subject to specific regulations?
Benzo[k]fluoranthene is subject to extensive European regulations under REACH and CLP frameworks due to its carcinogenic properties and environmental hazards. It requires safety data sheets and hazard communication per GHS standards. The substance may be restricted under various national occupational health regulations and environmental protection laws. Users must comply with worker protection directives and may require special permits or notifications depending on usage quantities and applications.
Where to buy benzo[k]fluoranthene in Europe?
Benzo[k]fluoranthene is available through specialized chemical distributors like OYSI, which supplies high-quality research chemicals and analytical standards across Europe. Due to its hazardous classification, purchase requires proper documentation and compliance with regulatory requirements. OYSI provides technical support and ensures proper packaging and transport according to ADR regulations. Contact OYSI directly for availability, specifications, and regulatory compliance assistance for your specific application needs.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.