Methyl nitrite

CH3NO2

methyl nitrite

CAS624-91-9

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Identification

CAS Number
624-91-9
EC Number
210-870-5
UN Number
2455
PubChem CID
12231

Physical-chemical properties

Molecular Formula
CH3NO2
Molar Mass
61.04 g/mol
IUPAC Name
methyl nitrite

Chemical Identifiers

InChI
InChI=1S/CH3NO2/c1-4-2-3/h1H3
InChI Key
BLLFVUPNHCTMSV-UHFFFAOYSA-N

Overview

Methyl nitrite (CAS 624-91-9) is an organic nitrite ester characterized by its gaseous state at room temperature and highly reactive nature. This volatile organic compound belongs to the alkyl nitrite family and serves as an important intermediate in various chemical processes. With the molecular formula CH3NO2 and a molecular weight of 61.04 g/mol, methyl nitrite presents unique handling requirements due to its gaseous properties under standard conditions. The compound is classified under ADR Class 2, indicating its nature as a compressed gas requiring specialized transportation and storage protocols. Methyl nitrite exhibits high volatility and instability, making it prone to decomposition under certain conditions. Its reactive nature stems from the nitrite functional group, which can participate in various chemical transformations. The compound demonstrates significant sensitivity to heat, light, and mechanical shock, necessitating careful handling procedures and appropriate storage conditions. Unlike more stable compounds such as nitrous oxide, methyl nitrite requires immediate use or specialized preservation methods due to its inherent instability. In industrial applications, methyl nitrite finds primary use as a chemical intermediate in organic synthesis reactions, particularly in the production of specialized pharmaceuticals and fine chemicals. The compound also serves applications in analytical chemistry as a reagent for specific chemical transformations. Additionally, it functions as a precursor in the synthesis of other nitrogen-containing organic compounds, where its reactive nitrite group provides valuable synthetic pathways. The gaseous nature and reactivity of methyl nitrite demand specialized handling expertise and appropriate safety infrastructure. OYSI provides technical-grade methyl nitrite with comprehensive safety documentation and handling guidelines to ensure safe industrial application.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2455
ADR Class2
Packing Group
Tunnel Code
Proper Shipping NameMethylnitrit, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is methyl nitrite?

Methyl nitrite is an organic chemical compound with the molecular formula CH3NO2 and CAS number 624-91-9. This substance has a molecular weight of 61.04 g/mol and belongs to the family of nitrite esters. It is characterized by its nitrite functional group attached to a methyl group, making it a simple alkyl nitrite compound used in various chemical applications and industrial processes.

What are the physicochemical properties of methyl nitrite?

Methyl nitrite is typically a colorless to pale yellow gas at room temperature with a characteristic sweet, ethereal odor. It has a boiling point of approximately -12°C and is highly volatile. The compound is moderately soluble in water and readily soluble in organic solvents such as alcohol and ether. It decomposes readily when exposed to light and heat, making it relatively unstable under normal storage conditions.

What is methyl nitrite used for?

Methyl nitrite is primarily used as an intermediate in organic synthesis and chemical manufacturing processes. It serves as a nitrosating agent in various chemical reactions and can be employed in the production of other organic compounds. The substance finds applications in pharmaceutical synthesis, specialty chemical manufacturing, and research laboratories for specific chemical transformations requiring nitrite functionality.

How to handle methyl nitrite safely?

Methyl nitrite should be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas. Work should be conducted in a fume hood to prevent inhalation exposure. Avoid sources of ignition, heat, and direct sunlight. Handle containers carefully to prevent spillage and ensure proper grounding of equipment to prevent static electricity buildup during transfer operations.

How to store methyl nitrite correctly?

Methyl nitrite must be stored in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep containers tightly sealed and store below 5°C to maintain stability. The substance should be kept away from strong oxidizing agents, acids, and bases. Storage areas should be equipped with appropriate ventilation systems and fire suppression equipment. Regular inspection of containers for signs of deterioration is recommended.

What to do in case of contact with methyl nitrite?

In case of skin contact with methyl nitrite, immediately remove contaminated clothing and wash the affected area with plenty of soap and water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention if breathing difficulties occur. For eye contact, flush with clean water for at least 15 minutes. Always seek medical advice after exposure and provide safety data sheet information to healthcare providers.

How to dispose of methyl nitrite appropriately?

Methyl nitrite waste must be disposed of according to local and national hazardous waste regulations. The substance should not be released into the environment or disposed of through regular waste streams. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be neutralized through controlled decomposition under appropriate safety conditions, but professional waste management services are recommended for larger quantities.

How to transport methyl nitrite?

Methyl nitrite is classified under ADR Class 2 for transport purposes, indicating it is considered a gas for transportation regulations. Packaging must comply with appropriate UN specifications and be properly labeled with required hazard markings. Transportation should be conducted by qualified carriers familiar with chemical transport regulations. Vehicles must be equipped with appropriate safety equipment and emergency response information during transit.

Is methyl nitrite subject to particular regulations?

Methyl nitrite is subject to standard chemical regulations including REACH registration requirements in Europe and CLP classification and labeling provisions. While not currently listed as a Substance of Very High Concern (SVHC), it must comply with general chemical safety regulations. Users must ensure proper risk assessment, safety data sheet availability, and compliance with workplace exposure limits and environmental protection requirements in their respective jurisdictions.

Where to buy methyl nitrite in Europe?

Methyl nitrite is available through specialized chemical distributors across Europe, including OYSI, a European distributor of technical chemicals. When purchasing, ensure the supplier provides complete documentation including certificates of analysis, safety data sheets, and regulatory compliance information. Choose suppliers with appropriate storage and handling capabilities to maintain product quality and safety standards throughout the supply chain.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.