Chloro(dimethyl)alumane;dichloro(methyl)alumane

C3H9Al2Cl3

chloro(dimethyl)alumane;dichloro(methyl)alumane

CAS12542-85-7

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Identification

CAS Number
12542-85-7
EC Number
235-698-8
UN Number
3394
PubChem CID
61568

Physical-chemical properties

Molecular Formula
C3H9Al2Cl3
Molar Mass
205.42 g/mol
IUPAC Name
chloro(dimethyl)alumane;dichloro(methyl)alumane

Chemical Identifiers

InChI
InChI=1S/3CH3.2Al.3ClH/h3*1H3;;;3*1H/q;;;+1;+2;;;/p-3
InChI Key
HYZXMVILOKSUKA-UHFFFAOYSA-K

Overview

Chloro(dimethyl)alumane;dichloro(methyl)alumane (CAS 12542-85-7) is an organoaluminum compound mixture featuring reactive aluminum-carbon bonds and chlorine substituents. This organoaluminum compound represents a mixture of two distinct aluminum species: chloro(dimethyl)alumane and dichloro(methyl)alumane, with the molecular formula C3H9Al2Cl3 and a molecular weight of 205.42 g/mol. The EC number 235-698-8 identifies this substance within European chemical regulations. As a member of the organoaluminum family, it shares structural similarities with other aluminum alkyls such as tripropylalumane and trioctylalumane, though it differs significantly due to the presence of chlorine atoms that modify its reactivity profile. The compound exhibits high reactivity characteristics typical of organoaluminum species, particularly toward moisture and oxygen. Its ADR classification as Class 4.2 indicates pyrophoric properties, meaning it can ignite spontaneously upon contact with air. This reactivity necessitates careful handling under inert atmosphere conditions and proper storage protocols to prevent unwanted reactions. The presence of both alkyl and chloro substituents on the aluminum centers provides unique chemical properties that distinguish it from fully alkylated aluminum compounds. Industrial applications primarily center around its use as a catalyst component in polymerization reactions, particularly in the production of polyolefins where precise control of molecular weight and polymer architecture is required. The compound also serves as an alkylating agent in organic synthesis and as a precursor for specialized aluminum-containing materials. Its dual nature allows for selective reactivity that can be advantageous in specific catalytic processes. OYSI provides this specialized organoaluminum compound to meet the demanding requirements of European chemical industries requiring high-purity reagents for advanced applications.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number3394
ADR Class4.2
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameMethylaluminiumsesquichlorid, flüssig, pyrophor
Marine PollutantNo

Frequently Asked Questions

What is chloro(dimethyl)alumane;dichloro(methyl)alumane?

Chloro(dimethyl)alumane;dichloro(methyl)alumane is an organoaluminum compound with the molecular formula C3H9Al2Cl3 and CAS number 12542-85-7. This chemical consists of two aluminum centers bonded to methyl groups and chlorine atoms, forming a dimeric structure. With a molecular weight of 205.42 g/mol, it belongs to the family of alkylaluminum chlorides used primarily in industrial applications requiring aluminum-carbon bonds.

What are the physicochemical properties of chloro(dimethyl)alumane;dichloro(methyl)alumane?

Chloro(dimethyl)alumane;dichloro(methyl)alumane is typically a colorless to pale yellow liquid or solid at room temperature, depending on concentration and purity. As an organoaluminum compound, it is highly reactive with moisture and oxygen, producing aluminum hydroxide and hydrocarbons. It is soluble in non-polar organic solvents but reacts violently with water and protic solvents, making it air and moisture sensitive.

What is chloro(dimethyl)alumane;dichloro(methyl)alumane used for?

Chloro(dimethyl)alumane;dichloro(methyl)alumane is primarily used as a catalyst and co-catalyst in polymerization reactions, particularly in the production of polyolefins. It serves as an alkylating agent in organic synthesis and as a precursor for other organoaluminum compounds. Industrial applications include Ziegler-Natta catalysis systems, chemical vapor deposition processes, and as a reducing agent in specialized chemical manufacturing operations.

How to handle chloro(dimethyl)alumane;dichloro(methyl)alumane safely?

Chloro(dimethyl)alumane;dichloro(methyl)alumane must be handled under inert atmosphere conditions using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Due to its pyrophoric nature, avoid contact with air, moisture, and incompatible materials. Use non-sparking tools and maintain strict exclusion of water and oxygen during handling procedures.

How to store chloro(dimethyl)alumane;dichloro(methyl)alumane correctly?

Chloro(dimethyl)alumane;dichloro(methyl)alumane should be stored under inert gas atmosphere in tightly sealed containers, preferably under nitrogen or argon. Storage areas must be dry, cool, and well-ventilated, away from sources of ignition, heat, and moisture. Keep containers away from incompatible materials such as water, alcohols, acids, and oxidizing agents. Storage facilities should comply with regulations for pyrophoric substances and include appropriate fire suppression systems.

What to do in case of contact with chloro(dimethyl)alumane;dichloro(methyl)alumane?

In case of skin contact with chloro(dimethyl)alumane;dichloro(methyl)alumane, immediately remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. For eye contact, rinse immediately with water and seek medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. Do not induce vomiting if ingested. Seek immediate medical attention in all cases of exposure and provide safety data sheet to medical personnel.

How to dispose of chloro(dimethyl)alumane;dichloro(methyl)alumane appropriately?

Chloro(dimethyl)alumane;dichloro(methyl)alumane must be disposed of according to local and national hazardous waste regulations. The compound should be carefully neutralized by qualified personnel using appropriate techniques under controlled conditions. Disposal must be conducted by licensed hazardous waste contractors who specialize in organoaluminum compounds. Never dispose of this material in regular waste streams, sewers, or water systems due to its reactive and potentially harmful nature.

How to transport chloro(dimethyl)alumane;dichloro(methyl)alumane?

Chloro(dimethyl)alumane;dichloro(methyl)alumane is classified as ADR Class 4.2 (substances liable to spontaneous combustion), Packing Group I, indicating high danger level. Transportation requires specialized packaging that prevents contact with air and moisture, typically under inert gas. Vehicles must carry appropriate hazard placards and emergency response information. Only trained personnel should handle transportation, and carriers must comply with dangerous goods regulations including proper documentation, labeling, and emergency procedures.

Is chloro(dimethyl)alumane;dichloro(methyl)alumane subject to specific regulations?

Chloro(dimethyl)alumane;dichloro(methyl)alumane is subject to various chemical regulations including REACH registration requirements in Europe for commercial use. While not classified as a Substance of Very High Concern (SVHC), it must comply with CLP regulation for classification, labeling, and packaging. Industrial users must follow workplace safety regulations and may require specific permits for handling pyrophoric substances. Export/import may be subject to additional trade regulations depending on jurisdiction.

Where to buy chloro(dimethyl)alumane;dichloro(methyl)alumane in Europe?

Chloro(dimethyl)alumane;dichloro(methyl)alumane is available through OYSI, a European distributor specializing in technical chemical products. As a specialized organoaluminum compound, it requires proper handling expertise and regulatory compliance. OYSI provides technical support and ensures proper packaging and transportation according to ADR regulations. Contact OYSI directly for availability, technical specifications, safety documentation, and delivery options to your specific European location.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.