Butyl 2-(2,4-dichlorophenoxy)acetate

C12H14Cl2O3

butyl 2-(2,4-dichlorophenoxy)acetate

CAS94-80-4
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
94-80-4
EC Number
202-364-8
UN Number
3082
Index Number
607-308-00-X
PubChem CID
7206

Physical-chemical properties

Molecular Formula
C12H14Cl2O3
Molar Mass
277.14 g/mol
IUPAC Name
butyl 2-(2,4-dichlorophenoxy)acetate

Chemical Identifiers

InChI
InChI=1S/C12H14Cl2O3/c1-2-3-6-16-12(15)8-17-11-5-4-9(13)7-10(11)14/h4-5,7H,2-3,6,8H2,1H3
InChI Key
UQMRAFJOBWOFNS-UHFFFAOYSA-N

Overview

Butyl 2-(2,4-dichlorophenoxy)acetate (CAS 94-80-4) is an organochlorine ester compound with selective herbicidal properties and moderate toxicity characteristics. This synthetic chemical compound belongs to the phenoxyacetic acid derivative family and serves as an important intermediate in agricultural chemistry applications. With its molecular formula C12H14Cl2O3 and molecular weight of 277.14 g/mol, butyl 2-(2,4-dichlorophenoxy)acetate exhibits the characteristic structure of chlorinated aromatic compounds combined with an aliphatic ester group. The presence of two chlorine atoms on the benzene ring at the 2,4-positions contributes to its biological activity and chemical stability. From a safety perspective, this compound requires careful handling due to its classification as Acute Tox. 4 and Skin Sens. 1, indicating moderate acute toxicity and potential for skin sensitization. The GHS07 and GHS09 pictograms reflect both health hazards and significant environmental concerns, particularly regarding aquatic ecosystems where it demonstrates both acute and chronic toxicity. As a Class 9 ADR substance, it falls under miscellaneous dangerous goods for transportation purposes. The compound finds primary application in the synthesis of selective herbicides for agricultural use, where its phenoxyacetic structure provides effective weed control mechanisms. It also serves as a chemical intermediate in the production of plant growth regulators and related agrochemicals. Unlike structurally different compounds such as 4-chlorobut-2-ynyl N-(3-chlorophenyl)carbamate, which operates through different biochemical pathways, butyl 2-(2,4-dichlorophenoxy)acetate maintains the classical phenoxy herbicide mode of action. OYSI maintains reliable supply chains for butyl 2-(2,4-dichlorophenoxy)acetate, ensuring consistent availability for European industrial customers requiring this specialized chemical intermediate.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3082
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameButyl-2,4-dichlorphenoxyacetat
Marine PollutantNo

Frequently Asked Questions

What is butyl 2-(2,4-dichlorophenoxy)acetate?

Butyl 2-(2,4-dichlorophenoxy)acetate is an organic chemical compound with the molecular formula C12H14Cl2O3 and CAS number 94-80-4. This substance has a molecular weight of 277.14 g/mol and belongs to the phenoxyacetic acid ester family. It is classified as a hazardous chemical with moderate acute toxicity, skin sensitizing properties, and significant aquatic toxicity. The compound carries GHS07 and GHS09 pictograms with a 'Warning' signal word.

What are the physicochemical properties of butyl 2-(2,4-dichlorophenoxy)acetate?

Butyl 2-(2,4-dichlorophenoxy)acetate is typically a liquid at room temperature with a characteristic organic solvent odor. As an ester compound containing chlorinated aromatic rings, it exhibits limited water solubility but good solubility in organic solvents such as alcohols, ketones, and hydrocarbons. The presence of two chlorine atoms on the phenoxy ring influences its chemical stability and biological activity. Its molecular structure provides moderate volatility and lipophilic characteristics.

What is butyl 2-(2,4-dichlorophenoxy)acetate used for?

Butyl 2-(2,4-dichlorophenoxy)acetate serves primarily as an active ingredient in herbicide formulations and plant growth regulators. It is used in agricultural applications for selective weed control, particularly against broadleaf weeds in cereal crops. The compound may also function as an intermediate in the synthesis of other agrochemical products. Its phenoxyacetic acid structure makes it effective in disrupting plant hormone systems, leading to controlled plant growth modification or elimination.

How to handle butyl 2-(2,4-dichlorophenoxy)acetate safely?

Butyl 2-(2,4-dichlorophenoxy)acetate requires careful handling due to its acute toxicity and skin sensitizing properties. Workers must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Adequate ventilation is essential to minimize inhalation exposure. Handle in well-ventilated areas or use local exhaust ventilation. Avoid generating aerosols or vapors, and ensure no eating, drinking, or smoking in work areas where this substance is present.

How to store butyl 2-(2,4-dichlorophenoxy)acetate correctly?

Butyl 2-(2,4-dichlorophenoxy)acetate should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers upright and properly labeled according to CLP requirements. Store away from incompatible materials such as strong bases, oxidizing agents, and reactive metals. Ensure storage areas have appropriate spill containment measures due to its aquatic toxicity classification. Regular container inspection is recommended to prevent leakage and environmental contamination.

What to do in case of contact with butyl 2-(2,4-dichlorophenoxy)acetate?

Immediate action is required following contact with butyl 2-(2,4-dichlorophenoxy)acetate due to its toxicity and skin sensitizing properties. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with clean water for 15-20 minutes and remove contact lenses if easily removable. If inhaled, move to fresh air immediately. Seek medical attention promptly, especially if symptoms develop or persist.

How to dispose of butyl 2-(2,4-dichlorophenoxy)acetate properly?

Butyl 2-(2,4-dichlorophenoxy)acetate must be disposed of as hazardous waste through licensed waste management facilities due to its environmental toxicity classification. Never discharge to sewers, waterways, or soil as it poses significant risks to aquatic organisms. Small quantities should be absorbed with inert material and placed in appropriate hazardous waste containers. Large quantities require professional hazardous waste collection services. Always follow local and national waste disposal regulations and maintain proper waste documentation for regulatory compliance.

How to transport butyl 2-(2,4-dichlorophenoxy)acetate?

Butyl 2-(2,4-dichlorophenoxy)acetate is classified as ADR Class 9 (Miscellaneous Dangerous Substances), Packing Group III for transportation purposes. This classification requires appropriate UN-specification packaging, proper labeling with Class 9 hazard labels, and transport documentation including shipping papers. Vehicles must carry appropriate emergency equipment and drivers need ADR certification for dangerous goods transport. Ensure containers are properly secured, upright, and protected from damage during transport to prevent environmental release.

Is butyl 2-(2,4-dichlorophenoxy)acetate subject to specific regulations?

Butyl 2-(2,4-dichlorophenoxy)acetate is regulated under multiple European frameworks including REACH registration requirements and CLP classification obligations. While not currently listed as a Substance of Very High Concern (SVHC), its acute toxicity and environmental hazard classifications trigger specific labeling, safety data sheet, and handling requirements. The substance may also be subject to biocidal product regulations if used in certain applications. Users must comply with occupational exposure limits and environmental discharge restrictions where applicable.

Where to buy butyl 2-(2,4-dichlorophenoxy)acetate in Europe?

Butyl 2-(2,4-dichlorophenoxy)acetate is available through OYSI, a specialized European distributor of technical chemicals and industrial raw materials. OYSI provides this substance to qualified industrial users with proper safety documentation, technical support, and regulatory compliance assistance. Due to its hazardous classification, purchases typically require verification of intended use and appropriate handling capabilities. Contact OYSI's technical sales team for availability, specifications, and regulatory guidance for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.