Butyl 2-(2,4-dichlorophenoxy)acetate

C12H14Cl2O3

butyl 2-(2,4-dichlorophenoxy)acetate

CAS94-80-4
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
94-80-4
EC Number
202-364-8
UN Number
3082
Index Number
607-308-00-X
PubChem CID
7206

Physical-chemical properties

Molecular Formula
C12H14Cl2O3
Molar Mass
277.14 g/mol
IUPAC Name
butyl 2-(2,4-dichlorophenoxy)acetate

Chemical Identifiers

InChI
InChI=1S/C12H14Cl2O3/c1-2-3-6-16-12(15)8-17-11-5-4-9(13)7-10(11)14/h4-5,7H,2-3,6,8H2,1H3
InChI Key
UQMRAFJOBWOFNS-UHFFFAOYSA-N

Overview

Butyl 2-(2,4-dichlorophenoxy)acetate (CAS 94-80-4) is a chlorinated phenoxyacetic acid ester with selective herbicidal properties and moderate aquatic toxicity. This synthetic organic compound, also known by its IUPAC designation butyl 2-(2,4-dichlorophenoxy)acetate, belongs to the phenoxyacetic acid derivative family and serves primarily as an active ingredient in agricultural formulations. With a molecular formula of C12H14Cl2O3 and molecular weight of 277.14 g/mol, this substance exhibits the characteristic structure of auxin-type herbicides, featuring a dichlorophenoxy group attached to an acetate ester moiety. The compound presents moderate safety concerns, classified under GHS pictograms GHS07 and GHS09 with a "Warning" signal word. Key hazard classifications include Acute Toxicity Category 4, Skin Sensitization Category 1, and both acute and chronic aquatic toxicity Category 1, indicating potential environmental persistence. As an ADR Class 9 material, it requires careful handling during transportation and storage operations. Primary industrial applications include selective herbicide formulations for broadleaf weed control in cereal crops and turf management systems. The compound's mechanism involves disrupting plant hormone regulation, making it effective against dicotyledonous weeds while showing selectivity toward monocotyledonous crops. Agricultural chemical manufacturers utilize this active ingredient in combination products, often alongside other phenoxyacetic derivatives. Unlike structurally different compounds such as 4-chlorobut-2-ynyl N-(3-chlorophenyl)carbamate, this phenoxyacetate ester demonstrates specific auxin-mimetic activity patterns. The substance finds additional applications in research and development of crop protection technologies, where its well-characterized toxicological profile supports regulatory compliance efforts. OYSI maintains reliable supply chains for butyl 2-(2,4-dichlorophenoxy)acetate to support European agricultural chemical manufacturers and research institutions.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3082
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameButyl-2,4-dichlorphenoxyacetat
Marine PollutantNo

Frequently Asked Questions

What is butyl 2-(2,4-dichlorophenoxy)acetate?

Butyl 2-(2,4-dichlorophenoxy)acetate is an organic chemical compound with the molecular formula C12H14Cl2O3 and CAS number 94-80-4. This substance belongs to the phenoxyacetic acid derivatives family and has a molecular weight of 277.14 g/mol. It is classified as a hazardous substance with acute toxicity, skin sensitization properties, and significant aquatic toxicity. The compound requires careful handling due to its environmental and health hazard classifications under the GHS system.

What are the physicochemical properties of butyl 2-(2,4-dichlorophenoxy)acetate?

Butyl 2-(2,4-dichlorophenoxy)acetate is typically a liquid at room temperature with a molecular weight of 277.14 g/mol. As an ester derivative of dichlorophenoxyacetic acid, it generally exhibits low water solubility but good solubility in organic solvents. The presence of two chlorine atoms and the phenoxy group influence its chemical stability and reactivity. Specific physical properties such as boiling point, density, and vapor pressure should be confirmed through technical data sheets for precise applications.

What is butyl 2-(2,4-dichlorophenoxy)acetate used for?

Butyl 2-(2,4-dichlorophenoxy)acetate is primarily used as an intermediate in chemical synthesis and agricultural applications. It serves as a precursor or derivative in the production of plant growth regulators and herbicidal compounds. The substance may also find applications in research and development within the pharmaceutical and agrochemical industries. Its specific phenoxyacetic acid structure makes it valuable for developing selective herbicides and plant growth control agents in professional agricultural settings.

How to handle butyl 2-(2,4-dichlorophenoxy)acetate safely?

Butyl 2-(2,4-dichlorophenoxy)acetate requires careful handling due to its Acute Tox. 4 and Skin Sens. 1 classifications. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing to prevent skin contact. Work in well-ventilated areas or use local exhaust ventilation to minimize inhalation exposure. Avoid eating, drinking, or smoking during handling. Wash hands thoroughly after use and before breaks. The Warning signal word indicates moderate hazard level requiring standard chemical safety protocols.

How to store butyl 2-(2,4-dichlorophenoxy)acetate correctly?

Butyl 2-(2,4-dichlorophenoxy)acetate should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and use original packaging when possible. Store away from incompatible materials such as strong oxidizing agents and alkalis. Maintain storage temperature within recommended ranges to prevent degradation. Implement appropriate containment measures to prevent environmental release, considering its Aquatic Acute 1 and Aquatic Chronic 1 classifications. Ensure storage areas comply with local chemical storage regulations.

What to do in case of contact with butyl 2-(2,4-dichlorophenoxy)acetate?

Butyl 2-(2,4-dichlorophenoxy)acetate contact requires immediate action due to its skin sensitization properties. For skin contact, immediately remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with plenty of clean water for 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical advice. Always consult safety data sheets for complete first aid procedures.

How to dispose of butyl 2-(2,4-dichlorophenoxy)acetate properly?

Butyl 2-(2,4-dichlorophenoxy)acetate disposal must comply with local environmental regulations due to its aquatic toxicity classification. The substance should never be discharged to sewers, waterways, or soil. Arrange disposal through licensed hazardous waste contractors who can handle chlorinated organic compounds appropriately. Small quantities may require incineration at high temperatures in approved facilities. Container disposal should follow local regulations for chemical packaging. Maintain disposal records and ensure compliance with waste tracking requirements in your jurisdiction.

How to transport butyl 2-(2,4-dichlorophenoxy)acetate?

Butyl 2-(2,4-dichlorophenoxy)acetate is classified as ADR Class 9 (Miscellaneous Dangerous Goods), Packing Group III, indicating moderate transport hazard. Transportation requires appropriate UN specification packaging and hazard labeling including GHS07 and GHS09 pictograms. Vehicles must carry appropriate transport documentation and emergency response information. Drivers need ADR training for Class 9 substances. Ensure packages are properly secured and protected from damage during transit. Comply with quantity limitations and routing restrictions as specified in ADR regulations.

Is butyl 2-(2,4-dichlorophenoxy)acetate subject to specific regulations?

Butyl 2-(2,4-dichlorophenoxy)acetate is subject to European REACH regulation requiring registration for commercial use. The substance falls under CLP regulation with mandatory hazard classification and labeling requirements including Warning signal word and specific pictograms (GHS07, GHS09). While not currently listed as SVHC, its aquatic toxicity may trigger environmental discharge restrictions. Users must comply with occupational exposure limits, waste disposal regulations, and transport requirements. Regular regulatory monitoring is recommended as classifications may change based on new scientific data.

Where to buy butyl 2-(2,4-dichlorophenoxy)acetate in Europe?

Butyl 2-(2,4-dichlorophenoxy)acetate is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this substance to industrial customers across Europe with proper regulatory compliance and technical support. As a professional chemical distributor, OYSI ensures products meet quality standards and regulatory requirements including REACH registration and CLP labeling. Contact OYSI directly for availability, specifications, and technical documentation. Purchase requires compliance with end-use restrictions and appropriate handling capabilities given the substance's hazard classification.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.