Bis(thallium(1+));sulfate

O4STl2

bis(thallium(1+));sulfate

CAS7446-18-6
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7446-18-6
EC Number
231-201-3
UN Number
1707
Index Number
081-003-00-4
PubChem CID
24833

Physical-chemical properties

Molecular Formula
O4STl2
Molar Mass
504.83 g/mol
IUPAC Name
bis(thallium(1+));sulfate

Chemical Identifiers

InChI
InChI=1S/H2O4S.2Tl/c1-5(2,3)4;;/h(H2,1,2,3,4);;/q;2*+1/p-2
InChI Key
YTQVHRVITVLIRD-UHFFFAOYSA-L

Overview

Bis(thallium(1+));sulfate (CAS 7446-18-6) is an inorganic thallium compound with highly toxic properties and specialized industrial applications. This thallium sulfate compound represents one of the most hazardous chemical substances in industrial chemistry, classified under acute toxicity category 2 with severe health implications. The molecular formula O4STl2 indicates a sulfate salt containing two thallium(I) cations, resulting in a molecular weight of 504.83 g/mol. Its classification under ADR class 6.1 and the presence of GHS06, GHS08, and GHS09 pictogrammes emphasize its extreme toxicity to humans and environmental hazards. The compound exhibits significant safety concerns, particularly regarding acute toxicity through multiple exposure routes and specific target organ toxicity following repeated exposure (STOT RE 1). Additionally, it presents moderate skin irritation potential and chronic aquatic toxicity. These hazard classifications necessitate stringent handling protocols and specialized safety equipment during industrial operations. Unlike other toxic compounds such as N-methylaniline or phenylhydrazine, thallium sulfate requires even more rigorous containment measures due to thallium's systemic toxicity profile. Industrial applications of bis(thallium(1+));sulfate are highly specialized and strictly regulated, primarily involving analytical chemistry procedures, specialized glass manufacturing, and certain research applications where thallium's unique properties are essential. The compound may also serve specific roles in electronics manufacturing and specialized catalyst systems, though these applications are increasingly limited due to environmental and health regulations. Given its extreme hazard profile, this compound requires expert handling and comprehensive safety documentation. OYSI provides bis(thallium(1+));sulfate to qualified industrial customers with appropriate safety certifications and regulatory compliance requirements.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; STOT RE 1; Skin Irrit. 2; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H300

Fatal if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Fatal

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1707
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameThallium(I)-sulfat
Marine PollutantNo

Frequently Asked Questions

What is bis(thallium(1+));sulfate?

Bis(thallium(1+));sulfate is an inorganic chemical compound with the molecular formula O4STl2 and CAS number 7446-18-6. This thallium salt has a molecular weight of 504.83 g/mol and appears as a crystalline solid. It is classified as highly toxic with acute toxicity category 2, causing specific target organ toxicity after repeated exposure. The compound is also a skin irritant and poses chronic aquatic toxicity risks, making it subject to strict safety regulations.

What are the physicochemical properties of bis(thallium(1+));sulfate?

Bis(thallium(1+));sulfate is a white crystalline solid at room temperature with high density due to thallium content. The compound is water-soluble, forming clear solutions that are highly toxic. It has a molecular weight of 504.83 g/mol and contains two thallium(I) cations bound to a sulfate anion. The substance is odorless and stable under normal conditions but requires careful handling due to its extreme toxicity and potential for bioaccumulation.

What is bis(thallium(1+));sulfate used for?

Bis(thallium(1+));sulfate is primarily used in specialized analytical chemistry applications and research laboratories. It serves as a reagent in certain chemical syntheses and analytical procedures requiring thallium compounds. Due to its extreme toxicity, its use has been largely restricted and replaced by safer alternatives in most applications. The compound may also be used in very limited industrial processes where thallium's unique properties are essential, though such applications are heavily regulated.

How to handle bis(thallium(1+));sulfate safely?

Bis(thallium(1+));sulfate requires extreme caution during handling due to its acute toxicity category 2 classification. Personnel must wear complete personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or fume hoods to prevent inhalation. Avoid skin contact and ingestion at all costs. Emergency procedures must be readily available, and only trained personnel should handle this substance under strict supervision.

How to store bis(thallium(1+));sulfate correctly?

Bis(thallium(1+));sulfate must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Storage areas should be secure and restricted to authorized personnel only due to the compound's extreme toxicity. The substance should be kept away from acids, strong oxidizers, and reducing agents. Secondary containment is recommended to prevent environmental contamination. Regular inventory checks and proper labeling with hazard warnings are essential for safe storage management.

What to do in case of contact with bis(thallium(1+));sulfate?

Bis(thallium(1+));sulfate exposure requires immediate emergency response due to its acute toxicity. For skin contact, immediately remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. If inhaled, move person to fresh air immediately. In case of eye contact, rinse with water for 15 minutes. For ingestion, do not induce vomiting and seek immediate medical attention. Call emergency services immediately for any exposure, as thallium poisoning requires specialized medical treatment.

How to dispose of bis(thallium(1+));sulfate appropriately?

Bis(thallium(1+));sulfate must be disposed of as hazardous waste through licensed waste management companies specializing in toxic metal compounds. The substance cannot be disposed of in regular waste streams due to its extreme toxicity and environmental persistence. Disposal must comply with local and international hazardous waste regulations including proper documentation and tracking. Small quantities should be collected and stored safely until sufficient amounts are available for professional disposal to minimize costs while ensuring environmental protection.

How to transport bis(thallium(1+));sulfate?

Bis(thallium(1+));sulfate is classified under ADR transport regulations as Class 6.1 (toxic substances) with Packing Group II, indicating high toxicity. Transport requires appropriate UN specification packaging with proper hazard labels and documentation. Vehicles must carry emergency response information and drivers need hazardous materials training. The substance must be segregated from incompatible materials during transport and secured to prevent container damage. Professional logistics companies experienced in toxic chemical transport should handle shipments.

Is bis(thallium(1+));sulfate subject to particular regulations?

Bis(thallium(1+));sulfate is subject to extensive regulations under REACH and CLP frameworks in Europe due to its extreme toxicity. The compound requires safety data sheets, hazard classification labeling with GHS pictograms (GHS06, GHS08, GHS09), and the danger signal word. Its use may be restricted or require authorization depending on application and quantity. Companies handling this substance must comply with occupational health regulations, environmental protection laws, and waste management directives. Regular monitoring and reporting may be mandatory.

Where to buy bis(thallium(1+));sulfate in Europe?

Bis(thallium(1+));sulfate can be sourced through specialized chemical distributors like OYSI, which supplies technical chemicals across Europe. Due to the compound's extreme toxicity and regulatory restrictions, purchases typically require proper licensing, safety documentation, and intended use justification. Buyers must demonstrate appropriate handling facilities, trained personnel, and waste disposal arrangements. OYSI can provide technical support, safety documentation, and regulatory compliance assistance for customers requiring this highly specialized and controlled chemical compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.