Bis(thallium(1+));sulfate

O4STl2

bis(thallium(1+));sulfate

CAS7446-18-6
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7446-18-6
EC Number
231-201-3
UN Number
1707
Index Number
081-003-00-4
PubChem CID
24833

Physical-chemical properties

Molecular Formula
O4STl2
Molar Mass
504.83 g/mol
IUPAC Name
bis(thallium(1+));sulfate

Chemical Identifiers

InChI
InChI=1S/H2O4S.2Tl/c1-5(2,3)4;;/h(H2,1,2,3,4);;/q;2*+1/p-2
InChI Key
YTQVHRVITVLIRD-UHFFFAOYSA-L

Overview

Bis(thallium(1+));sulfate (CAS 7446-18-6) is an inorganic thallium compound with highly toxic properties and industrial applications requiring specialized handling protocols. This thallium sulfate compound represents one of the most hazardous chemical substances in industrial applications, classified under acute toxicity category 2 with the danger signal word and multiple GHS pictograms including skull and crossbones (GHS06), health hazard (GHS08), and environmental hazard (GHS09). The compound's molecular formula O4STl2 indicates its structure as a sulfate salt containing two thallium(I) cations, resulting in a molecular weight of 504.83 g/mol. Its classification under ADR class 6.1 designates it as a toxic substance requiring stringent transportation and storage protocols. The substance exhibits severe toxicological properties, causing acute toxicity through multiple exposure routes and specific target organ toxicity following repeated exposure (STOT RE 1). Additionally, it demonstrates skin irritation potential and chronic aquatic toxicity, necessitating comprehensive environmental protection measures. Unlike related toxic compounds such as N-methylaniline or phenylhydrazine, thallium sulfate's heavy metal content creates unique bioaccumulation concerns and requires specialized disposal procedures. Primary industrial applications include specialized analytical chemistry procedures, certain electronic component manufacturing processes, and as a reagent in specific research applications where thallium's unique properties are essential. The compound's high toxicity profile limits its use to highly controlled industrial environments with appropriate safety infrastructure and trained personnel. As a specialized European distributor of technical chemicals, OYSI maintains availability of bis(thallium(1+));sulfate for qualified industrial customers requiring this high-hazard substance for legitimate commercial applications.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; STOT RE 1; Skin Irrit. 2; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H300

Fatal if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Fatal

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1707
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameThallium(I)-sulfat
Marine PollutantNo

Frequently Asked Questions

What is bis(thallium(1+));sulfate?

Bis(thallium(1+));sulfate is an inorganic chemical compound with the molecular formula O4STl2 and CAS number 7446-18-6. This thallium salt has a molecular weight of 504.83 g/mol and appears as a white crystalline solid. It is classified as extremely hazardous due to its acute toxicity and potential for causing specific target organ damage through repeated exposure. The compound requires strict handling protocols and is subject to extensive regulatory controls due to its severe health and environmental risks.

What are the physicochemical properties of bis(thallium(1+));sulfate?

Bis(thallium(1+));sulfate is a white crystalline solid at room temperature with high density due to the presence of thallium atoms. The compound is moderately soluble in water, forming colorless solutions. It has a molecular weight of 504.83 g/mol and contains two thallium cations bound to a sulfate anion. The substance is odorless and stable under normal conditions but decomposes at high temperatures. Its high toxicity makes it unsuitable for consumer applications.

What is bis(thallium(1+));sulfate used for?

Bis(thallium(1+));sulfate is primarily used in highly specialized industrial applications due to its extreme toxicity. Historical uses included rodenticide formulations, but this application has been largely banned due to safety concerns. Currently, it may be used in very limited quantities for specific analytical chemistry applications, research purposes, or as an intermediate in specialized chemical synthesis. Its use is heavily restricted and requires special permits and handling protocols in most jurisdictions.

How to handle bis(thallium(1+));sulfate safely?

Bis(thallium(1+));sulfate must be handled with extreme caution due to its acute toxicity classification (Acute Tox. 2). Essential PPE includes full chemical-resistant gloves, protective clothing, safety goggles, and respiratory protection. Work must be conducted in well-ventilated areas or under fume hoods. Avoid skin contact, inhalation, and ingestion at all costs. Only trained personnel should handle this substance, and emergency procedures must be readily available. All handling should occur in designated areas with appropriate decontamination protocols.

How to store bis(thallium(1+));sulfate correctly?

Bis(thallium(1+));sulfate must be stored in a secure, locked area with restricted access due to its extreme toxicity. Store in original, tightly sealed containers away from heat, moisture, and incompatible materials. The storage area should be cool, dry, well-ventilated, and equipped with appropriate spill containment measures. Containers must be clearly labeled with hazard warnings. Regular inventory checks are essential, and storage should comply with local regulations for highly toxic substances. Separate from food, feed, and other chemicals.

What to do in case of contact with bis(thallium(1+));sulfate?

Bis(thallium(1+));sulfate exposure requires immediate emergency response due to its extreme toxicity. For skin contact, immediately remove contaminated clothing and flush with copious amounts of water for at least 15 minutes. If inhaled, move to fresh air immediately. For eye contact, flush with water for at least 15 minutes. If ingested, do not induce vomiting. Seek immediate medical attention in all cases of exposure, informing medical personnel of the specific chemical involved. Time is critical due to the severe toxicity.

How to dispose of bis(thallium(1+));sulfate appropriately?

Bis(thallium(1+));sulfate requires specialized hazardous waste disposal due to its extreme toxicity and environmental impact. Disposal must be carried out by licensed hazardous waste contractors following strict regulatory protocols. The substance cannot be disposed of through normal waste streams or sewage systems. Containers must be properly labeled and manifested for hazardous waste transport. Treatment typically involves stabilization or secure landfill disposal at approved facilities. All disposal activities must comply with local environmental regulations and waste management requirements.

How to transport bis(thallium(1+));sulfate?

Bis(thallium(1+));sulfate is classified as ADR Class 6.1, Packing Group II, indicating it is a toxic substance requiring special transport precautions. Transportation must comply with dangerous goods regulations including proper packaging, labeling with GHS pictograms (GHS06, GHS08, GHS09), and documentation. Vehicles must carry appropriate emergency equipment and drivers need hazardous materials certification. The substance requires secure packaging to prevent leakage and must be segregated from incompatible materials during transport. Emergency response information must accompany shipments.

Is bis(thallium(1+));sulfate subject to specific regulations?

Bis(thallium(1+));sulfate is subject to extensive regulatory controls under multiple frameworks including REACH, CLP, and national chemical regulations. Its classification as Acute Tox. 2, STOT RE 1 triggers strict notification and authorization requirements. Many jurisdictions have banned or severely restricted its use due to toxicity concerns. Users must comply with occupational exposure limits, environmental discharge restrictions, and reporting requirements. Import/export may require special permits, and industrial use typically requires risk assessments and safety management systems.

Where to buy bis(thallium(1+));sulfate in Europe?

Bis(thallium(1+));sulfate is available through specialized chemical distributors in Europe, including OYSI, which supplies industrial chemicals to European markets. Due to its extreme toxicity and regulatory restrictions, purchase requires proper business justification, safety documentation, and compliance with local regulations. Buyers typically need to demonstrate legitimate industrial use, appropriate handling capabilities, and waste disposal arrangements. OYSI can provide guidance on regulatory requirements and proper handling protocols for this highly controlled substance to qualified industrial customers.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.