Thallium(1+) thiocyanate

CNSTl

thallium(1+) thiocyanate

CAS3535-84-0
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
3535-84-0
EC Number
222-571-7
UN Number
1707
Index Number
615-031-00-0
PubChem CID
3082002

Physical-chemical properties

Molecular Formula
CNSTl
Molar Mass
262.47 g/mol
IUPAC Name
thallium(1+) thiocyanate

Chemical Identifiers

InChI
InChI=1S/CHNS.Tl/c2-1-3;/h3H;/q;+1/p-1
InChI Key
JSSGUHHJIJMEQF-UHFFFAOYSA-M

Overview

Thallium(1+) thiocyanate (CAS 3535-84-0) is an inorganic salt compound with high toxicity and specialized analytical applications. This crystalline compound represents one of the most hazardous thallium salts commercially available, combining the extreme toxicity of thallium ions with the chemical versatility of thiocyanate groups. The molecular formula CNSTl reflects its simple ionic structure, where thallium exists in its +1 oxidation state paired with the linear thiocyanate anion. With a molecular weight of 262.47 g/mol, this white to pale yellow solid demonstrates significant solubility in water and polar organic solvents. The safety profile of thallium(1+) thiocyanate demands exceptional precautionary measures due to its classification as Acute Tox. 2 through multiple exposure routes and its potential for causing specific target organ toxicity with repeated exposure (STOT RE 2). The GHS06 skull and crossbones pictogram, alongside GHS08 health hazard and GHS09 environmental symbols, emphasizes the severe risks associated with handling this material. Unlike less toxic compounds such as N-methylaniline, thallium thiocyanate requires specialized containment and disposal procedures due to its persistence and bioaccumulation potential. Primary industrial applications include specialized analytical chemistry procedures, particularly in qualitative inorganic analysis where its unique precipitation reactions serve diagnostic purposes. The compound also finds use in certain electrochemical applications and as a research reagent in academic institutions studying thallium chemistry. Advanced materials research occasionally employs this compound in the synthesis of specialized optical or electronic materials. Transportation under ADR Class 6.1 regulations reflects the stringent handling requirements necessary throughout the supply chain. OYSI maintains availability of thallium(1+) thiocyanate for qualified industrial and research customers requiring this specialized chemical reagent.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Acute Tox. 4 *; Acute Tox. 2 *; STOT RE 2; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H312

Harmful in contact with skin.

H300

Fatal if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Fatal

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1707
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameThallium(I)-thiocyanat
Marine PollutantNo

Frequently Asked Questions

What is thallium(1+) thiocyanate?

Thallium(1+) thiocyanate is a highly toxic inorganic compound with the chemical formula CNSTl and CAS number 3535-84-0. This substance has a molecular weight of 262.47 g/mol and belongs to the thallium salt family. It is classified as extremely hazardous with multiple acute toxicity classifications and poses serious health risks including organ damage through repeated exposure. The compound also presents environmental hazards to aquatic life.

What are the physicochemical properties of thallium(1+) thiocyanate?

Thallium(1+) thiocyanate is typically a crystalline solid at room temperature with characteristic salt-like appearance. As an inorganic thallium compound, it demonstrates moderate to good solubility in polar solvents, particularly water. The substance exhibits stability under normal conditions but requires careful handling due to its toxic nature. Its molecular structure consists of thallium cations coordinated with thiocyanate anions, contributing to its chemical reactivity and toxicological properties.

What is thallium(1+) thiocyanate used for?

Thallium(1+) thiocyanate is primarily used in specialized analytical chemistry applications and research laboratories. It serves as a reagent in certain chemical synthesis processes and analytical procedures where thallium compounds are required. Due to its extreme toxicity, its industrial applications are highly restricted and limited to specialized facilities with appropriate safety controls. The compound may also be used in academic research for studying thallium chemistry and toxicology.

How to handle thallium(1+) thiocyanate safely?

Thallium(1+) thiocyanate requires extreme safety precautions due to its Acute Tox. 2 classification. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work exclusively in well-ventilated areas or under fume hoods. Avoid any skin contact, inhalation, or ingestion. Use only the minimum quantities necessary and ensure all personnel are trained in emergency procedures. Implement strict contamination control measures and maintain emergency shower/eyewash stations nearby.

How to store thallium(1+) thiocyanate correctly?

Thallium(1+) thiocyanate must be stored in a secure, well-ventilated area away from incompatible materials and heat sources. Keep containers tightly sealed and properly labeled with appropriate hazard warnings. Store in a designated toxic materials cabinet with restricted access and inventory control. Maintain dry conditions to prevent degradation and ensure secondary containment to prevent environmental release. Regular inspection of containers and storage areas is essential to detect any leaks or deterioration.

What to do in case of contact with thallium(1+) thiocyanate?

Immediate medical attention is required for any exposure to thallium(1+) thiocyanate due to its extreme toxicity. For skin contact, remove contaminated clothing and flush with copious amounts of water for at least 15 minutes. If inhaled, move to fresh air immediately. For eye contact, rinse with water for 15-20 minutes. Never induce vomiting if ingested. Contact poison control and emergency medical services immediately. Provide the safety data sheet to medical personnel for proper treatment guidance.

How to dispose of thallium(1+) thiocyanate properly?

Thallium(1+) thiocyanate disposal requires specialized hazardous waste management procedures due to its high toxicity classification. Never dispose of this substance through normal waste streams or sewage systems. Contact licensed hazardous waste disposal companies experienced in handling toxic inorganic compounds. All waste containers must be properly labeled and documented according to local and European waste regulations. Disposal must comply with REACH and national toxic substance disposal requirements.

How to transport thallium(1+) thiocyanate?

Thallium(1+) thiocyanate is classified under ADR Class 6.1 (toxic substances) Packing Group II, requiring specialized transport procedures. Use approved packaging designed for toxic materials and ensure proper labeling with GHS06, GHS08, and GHS09 pictograms. Transport documentation must include proper shipping names and hazard classifications. Only use carriers certified for dangerous goods transport and ensure compliance with European transport regulations. Emergency response information must accompany all shipments.

Is thallium(1+) thiocyanate subject to specific regulations?

Thallium(1+) thiocyanate is subject to strict regulatory oversight under REACH and CLP regulations due to its extreme toxicity. The substance requires comprehensive safety data sheets and hazard communication under the 'Danger' signal word classification. Users must comply with occupational exposure limits and workplace safety regulations. While not listed as SVHC, its multiple acute toxicity classifications and environmental hazard profile subject it to rigorous handling and reporting requirements throughout the supply chain.

Where to buy thallium(1+) thiocyanate in Europe?

Thallium(1+) thiocyanate is available through OYSI, a specialized European distributor of technical chemicals with expertise in handling highly toxic substances. Due to the extreme hazard classification of this compound, purchase requires proper licensing and safety documentation. OYSI ensures full regulatory compliance and provides comprehensive safety data sheets and handling guidance. Contact OYSI directly to discuss availability, quantities, and specific regulatory requirements for your application and location.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.