Bis(sulfanylidene)titanium

S2Ti

bis(sulfanylidene)titanium

CAS12039-13-3

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Identification

CAS Number
12039-13-3
EC Number
234-883-0
UN Number
3174
PubChem CID
61544

Physical-chemical properties

Molecular Formula
S2Ti
Molar Mass
112.00 g/mol
IUPAC Name
bis(sulfanylidene)titanium

Chemical Identifiers

InChI
InChI=1S/2S.Ti
InChI Key
CFJRPNFOLVDFMJ-UHFFFAOYSA-N

Overview

Bis(sulfanylidene)titanium (CAS 12039-13-3) is an inorganic titanium sulfide compound with the molecular formula S2Ti and distinctive chemical stability properties. This titanium disulfide compound represents an important class of transition metal chalcogenides widely utilized in various industrial applications. With a molecular weight of 112 g/mol and EC number 234-883-0, bis(sulfanylidene)titanium exhibits unique structural and electronic properties that make it valuable for specialized technical processes. The compound features titanium in coordination with two sulfur atoms, creating a stable crystalline structure that demonstrates excellent thermal stability and chemical resistance under specific conditions. From a safety perspective, bis(sulfanylidene)titanium is classified under ADR class 4.2, indicating it may present fire hazards under certain conditions, particularly when finely divided or in contact with moisture. While no specific GHS pictograms are assigned, proper handling protocols should be observed to prevent spontaneous combustion risks associated with this classification. Storage in dry, inert atmospheres is typically recommended to maintain product integrity and minimize reactivity concerns. The compound finds application in several industrial sectors, primarily as a catalyst component in petrochemical processes where its unique electronic properties facilitate specific chemical transformations. Additionally, it serves as a precursor material in advanced materials synthesis, particularly for producing specialized coatings and thin films. Unlike organometallic compounds such as tris(2-methylpropyl)alumane or tripropylalumane, bis(sulfanylidene)titanium offers superior thermal stability in high-temperature applications. Industrial applications include use in solid-state chemistry research, semiconductor manufacturing processes, and as an intermediate in the production of titanium-based advanced materials. Its chemical stability makes it particularly suitable for applications requiring consistent performance under demanding operational conditions. OYSI maintains regular availability of bis(sulfanylidene)titanium for European industrial customers requiring reliable supply chains for their specialized chemical processes.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number3174
ADR Class4.2
Packing GroupIII
Tunnel CodeE
Proper Shipping NameTitandisulfid
Marine PollutantNo

Frequently Asked Questions

What is bis(sulfanylidene)titanium?

Bis(sulfanylidene)titanium is an inorganic compound with the chemical formula S2Ti and CAS number 12039-13-3. This titanium sulfide compound has a molecular weight of 112 g/mol and represents a binary compound formed between titanium and sulfur atoms. It belongs to the family of transition metal sulfides and exhibits properties typical of metal-sulfur compounds used in various industrial applications.

What are the physicochemical properties of bis(sulfanylidene)titanium?

Bis(sulfanylidene)titanium is a solid inorganic compound at room temperature, typically appearing as a dark-colored crystalline material. As a metal sulfide, it exhibits low solubility in water and most organic solvents. The compound demonstrates thermal stability under normal conditions but may decompose at elevated temperatures. Its density and other specific physical properties are characteristic of transition metal sulfides.

What is bis(sulfanylidene)titanium used for?

Bis(sulfanylidene)titanium serves primarily as a precursor in materials science and catalysis applications. It is utilized in the synthesis of advanced materials, particularly in the production of titanium-based compounds and sulfide materials. The compound finds applications in research and development for electronic materials, thin film deposition, and as an intermediate in specialized chemical processes requiring titanium-sulfur compounds.

How to handle bis(sulfanylidene)titanium safely?

Bis(sulfanylidene)titanium should be handled using standard laboratory safety practices including wearing appropriate personal protective equipment such as safety goggles, gloves, and lab coats. Work should be conducted in well-ventilated areas or under fume hoods to avoid dust inhalation. Although no specific GHS hazard classifications are assigned, general precautions for handling inorganic compounds should be followed to minimize exposure risks.

How to store bis(sulfanylidene)titanium properly?

Bis(sulfanylidene)titanium should be stored in tightly sealed containers in a cool, dry place away from moisture and incompatible materials. As it is classified under ADR class 4.2 (substances liable to spontaneous combustion), storage areas should be well-ventilated and protected from heat sources. Containers should be kept upright and properly labeled, with storage conditions maintaining the compound's stability and preventing contamination.

What to do in case of contact with bis(sulfanylidene)titanium?

In case of skin contact with bis(sulfanylidene)titanium, immediately wash the affected area with plenty of soap and water. If eye contact occurs, flush thoroughly with clean water for at least 15 minutes and seek medical attention if irritation persists. In case of inhalation, move to fresh air immediately. If ingestion occurs, do not induce vomiting and seek immediate medical attention while providing the safety data sheet to healthcare professionals.

How to dispose of bis(sulfanylidene)titanium appropriately?

Bis(sulfanylidene)titanium must be disposed of according to local and national hazardous waste regulations. The compound should not be discharged into drains, soil, or waterways. Contact licensed waste disposal companies for proper treatment and disposal. Small quantities may require neutralization or stabilization before disposal. Always consult local environmental authorities and follow applicable waste classification codes for metal-containing compounds.

How to transport bis(sulfanylidene)titanium?

Bis(sulfanylidene)titanium is classified under ADR class 4.2 (substances liable to spontaneous combustion) with packing group III, indicating moderate danger level during transport. Appropriate UN-approved packaging must be used, and vehicles must carry proper documentation and emergency instructions. Transport should comply with ADR regulations including proper labeling, segregation requirements, and driver certification for dangerous goods transportation.

Is bis(sulfanylidene)titanium subject to specific regulations?

Bis(sulfanylidene)titanium is not classified as a Substance of Very High Concern (SVHC) under REACH regulation. However, it remains subject to standard chemical registration and notification requirements within the European Union. Users must comply with workplace safety regulations, environmental protection laws, and proper chemical inventory reporting. Classification under ADR transport regulations requires adherence to dangerous goods transport protocols.

Where to buy bis(sulfanylidene)titanium in Europe?

Bis(sulfanylidene)titanium is available through OYSI, a trusted European distributor of specialty chemicals and technical compounds. OYSI provides high-quality chemical products to industrial and research customers across Europe, ensuring proper documentation, regulatory compliance, and technical support. Contact OYSI directly for availability, specifications, packaging options, and delivery arrangements to meet your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.