Sodium alumanuide
AlH4Na
sodium alumanuide
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Identification
- CAS Number
- 13770-96-2
- EC Number
- 237-400-1
- UN Number
- 2835
- PubChem CID
- 26266
Physical-chemical properties
- Molecular Formula
- AlH4Na
- Molar Mass
- 54.00 g/mol
- IUPAC Name
- sodium alumanuide
Chemical Identifiers
- InChI
- InChI=1S/Al.Na.4H/q-1;+1;;;;
- InChI Key
- MNYCIYRTKITUKR-UHFFFAOYSA-N
Overview
Sodium alumanuide (CAS 13770-96-2) is a highly reactive hydride compound with powerful reducing properties and water-reactive characteristics. Sodium alumanuide, also known by its molecular formula AlH4Na, represents one of the most important hydride reducing agents in modern chemistry and industrial applications. With a molecular weight of 54.003 g/mol, this white crystalline compound demonstrates exceptional reactivity, particularly with water and other protic solvents, making it a valuable yet challenging material to handle in industrial settings. The compound belongs to the family of complex metal hydrides, sharing similar reactive characteristics with related substances like potassium;sodium compounds, though sodium alumanuide exhibits distinctly more aggressive reducing behavior. Its classification under ADR Class 4.3 reflects its dangerous goods status due to its water-reactive nature, which can generate flammable hydrogen gas upon contact with moisture. This property necessitates strict handling protocols and specialized storage conditions in inert, dry atmospheres. In industrial applications, sodium alumanuide serves primarily as a powerful reducing agent in organic synthesis, particularly for the reduction of carbonyl compounds to alcohols. The pharmaceutical industry utilizes this compound for selective reductions in drug synthesis, while the fine chemicals sector employs it for producing specialized intermediates. Additionally, it finds application in metal processing where precise reduction reactions are required. The compound's high reactivity and specialized handling requirements make it suitable primarily for controlled industrial environments with appropriate safety infrastructure. Its effectiveness as a reducing agent, combined with its selectivity in certain reactions, maintains its position as an essential chemical reagent despite handling challenges. OYSI provides sodium alumanuide to qualified industrial customers with comprehensive technical support and safety documentation.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 2835 |
| ADR Class | 4.3 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Natriumaluminiumhydrid |
| Marine Pollutant | No |
Frequently Asked Questions
What is sodium alumanide?
Sodium alumanide is an inorganic chemical compound with the formula AlH4Na and CAS number 13770-96-2. It belongs to the family of metal hydrides and has a molecular weight of 54.003 g/mol. This compound is characterized by its aluminum-hydrogen framework stabilized by sodium cations. Sodium alumanide serves as an important reducing agent in various chemical processes and is commonly used in industrial applications requiring controlled hydrogen release or metal reduction reactions.
What are the physicochemical properties of sodium alumanide?
Sodium alumanide is a white to off-white crystalline solid at room temperature with high reactivity towards moisture and air. The compound is highly soluble in polar aprotic solvents and reacts vigorously with water, releasing hydrogen gas. It exhibits strong reducing properties due to its hydride functionality. The material is sensitive to atmospheric conditions and must be handled under inert atmosphere to prevent decomposition and maintain its chemical integrity.
What is sodium alumanide used for?
Sodium alumanide is primarily used as a powerful reducing agent in organic synthesis and metal processing applications. It serves in pharmaceutical manufacturing for the reduction of carbonyl compounds and in the production of fine chemicals. The compound is also utilized in hydrogen storage research and as a precursor for aluminum-based materials. Industrial applications include metal surface treatment, catalysis, and specialized chemical transformations requiring controlled hydrogen delivery under mild conditions.
How to handle sodium alumanide safely?
Sodium alumanide requires careful handling using appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Work must be conducted in well-ventilated areas or under inert atmosphere to prevent moisture contact. Avoid any exposure to water or humid conditions as this causes vigorous hydrogen evolution. Use non-sparking tools and ensure proper grounding to prevent static discharge. Emergency eyewash stations and safety showers should be readily accessible during handling operations.
How to store sodium alumanide correctly?
Sodium alumanide must be stored in tightly sealed containers under inert atmosphere, typically nitrogen or argon, to prevent moisture contact and decomposition. Storage areas should be cool, dry, and well-ventilated, away from heat sources and incompatible materials. The compound is incompatible with water, alcohols, acids, and oxidizing agents. Containers should be clearly labeled and stored in designated chemical storage areas with appropriate fire suppression systems and spill containment measures.
What to do in case of contact with sodium alumanide?
Sodium alumanide contact requires immediate action depending on the exposure route. For skin contact, remove contaminated clothing and flush affected area with large amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water and seek medical attention. If inhaled, move to fresh air and monitor for respiratory distress. For ingestion, do not induce vomiting and seek immediate medical care. Always consult safety data sheets for specific first aid measures.
How to dispose of sodium alumanide appropriately?
Sodium alumanide disposal requires specialized hazardous waste handling procedures due to its reactive nature and hydrogen evolution potential. Small quantities can be carefully quenched with appropriate alcohols under controlled conditions by trained personnel. Larger amounts must be disposed of through licensed hazardous waste contractors. Never dispose of in regular waste streams or pour down drains. Consult local environmental regulations and waste management authorities for specific disposal requirements and approved facilities.
How to transport sodium alumanide?
Sodium alumanide is classified under ADR Class 4.3 (substances which, in contact with water, emit flammable gases) with Packing Group II, indicating moderate danger level. Transportation requires UN-approved packaging designed for water-reactive materials. Proper shipping documentation, labeling, and placarding are mandatory. Vehicles must be equipped with appropriate fire extinguishing equipment and emergency response information. Only certified carriers experienced in hazardous materials transport should handle shipments of this compound.
Is sodium alumanide subject to specific regulations?
Sodium alumanide is subject to various chemical regulations including REACH registration requirements for commercial use in the European Union. The compound is not classified as a Substance of Very High Concern (SVHC) under current regulations. However, its reactive nature subjects it to specific handling, storage, and transport regulations under ADR and local chemical safety laws. Users must comply with workplace safety regulations and may require permits for storage and use in certain jurisdictions.
Where to buy sodium alumanide in Europe?
Sodium alumanide is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers across the continent. OYSI provides reliable supply chains for reactive chemicals with proper packaging, documentation, and regulatory compliance. As a professional chemical distributor, OYSI ensures quality standards and provides technical support for customers requiring sodium alumanide for their applications. Contact OYSI directly for availability, specifications, and ordering information tailored to your specific requirements.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.