Sodium alumanuide

AlH4Na

sodium alumanuide

CAS13770-96-2

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Identification

CAS Number
13770-96-2
EC Number
237-400-1
UN Number
2835
PubChem CID
26266

Physical-chemical properties

Molecular Formula
AlH4Na
Molar Mass
54.00 g/mol
IUPAC Name
sodium alumanuide

Chemical Identifiers

InChI
InChI=1S/Al.Na.4H/q-1;+1;;;;
InChI Key
MNYCIYRTKITUKR-UHFFFAOYSA-N

Overview

Sodium alumanuide (CAS 13770-96-2) is a metal hydride compound with the molecular formula AlH4Na, serving as a powerful reducing agent in chemical synthesis. This white crystalline solid, also known by its IUPAC name sodium alumanuide, represents one of the most important hydride reducing agents in modern chemistry. With a molecular weight of 54.003 g/mol, this compound belongs to the family of complex metal hydrides that have revolutionized synthetic chemistry since their discovery. The compound consists of aluminum hydride anions (AlH4-) paired with sodium cations, creating a highly reactive material that must be handled with appropriate safety precautions. The safety profile of sodium alumanuide requires careful consideration, as it is classified under ADR class 4.3, indicating its nature as a substance that emits flammable gases when in contact with water. This water-reactive characteristic demands storage under inert atmospheres and specialized handling procedures. The compound shares chemical similarities with other alkali metal compounds like potassium;sodium systems, though its hydride nature makes it distinctly more reactive than simple metal alloys. Sodium alumanuide finds extensive application in organic synthesis as a selective reducing agent, particularly in pharmaceutical manufacturing where precise reduction reactions are critical. The compound also serves as a hydrogen source in specialized applications and plays a role in metallurgical processes requiring controlled reduction conditions. Additionally, it functions as a catalyst in certain polymerization reactions where its unique electronic properties prove advantageous. OYSI provides sodium alumanuide to European industrial customers, ensuring proper packaging and documentation compliance with regulatory requirements for this specialized chemical compound.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2835
ADR Class4.3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameNatriumaluminiumhydrid
Marine PollutantNo

Frequently Asked Questions

What is sodium alumanuide?

Sodium alumanuide is an inorganic chemical compound with the molecular formula AlH4Na and CAS number 13770-96-2. It belongs to the family of complex metal hydrides and has a molecular weight of 54.003 g/mol. This compound serves as a powerful reducing agent in various chemical processes and organic synthesis applications, particularly valued for its ability to donate hydride ions in chemical reactions.

What are the physicochemical properties of sodium alumanuide?

Sodium alumanuide is typically a white to off-white crystalline solid at room temperature. The compound is highly reactive with water and moisture, decomposing readily to release hydrogen gas. It exhibits good solubility in ethereal solvents like tetrahydrofuran and diethyl ether, but reacts violently with protic solvents. The substance is odorless when pure but may release characteristic odors upon decomposition or reaction with atmospheric moisture.

What is sodium alumanuide used for?

Sodium alumanuide is primarily used as a reducing agent in organic synthesis and pharmaceutical manufacturing. It serves as an effective hydride donor for the reduction of carbonyl compounds, esters, and other organic functional groups. The compound finds applications in fine chemical production, research laboratories, and specialized industrial processes where selective reduction reactions are required. Its high reactivity makes it valuable for specific synthetic transformations in chemical manufacturing.

How to handle sodium alumanuide safely?

Sodium alumanuide must be handled under strictly inert atmosphere conditions using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent accumulation of hydrogen gas. Avoid contact with water, alcohols, and other protic substances. Use dry, inert gas techniques and ensure all equipment is thoroughly dried before use to prevent dangerous reactions.

How to store sodium alumanuide correctly?

Sodium alumanuide must be stored in tightly sealed containers under inert atmosphere, typically nitrogen or argon gas. Keep the material in a cool, dry place away from moisture, heat sources, and incompatible materials such as water, alcohols, acids, and oxidizing agents. Storage areas should be well-ventilated and equipped with appropriate fire suppression systems. Regular inspection of container integrity is essential to prevent moisture ingress and subsequent decomposition.

What to do in case of contact with sodium alumanuide?

In case of skin contact with sodium alumanuide, immediately remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. For eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician and provide them with the safety data sheet.

How to dispose of sodium alumanuide appropriately?

Sodium alumanuide waste must be disposed of according to local and national hazardous waste regulations. The material should be carefully quenched with appropriate alcohols under controlled conditions by trained personnel, followed by neutralization. Never dispose of unreacted material in regular waste streams or pour down drains. Contact licensed hazardous waste disposal companies and provide them with detailed information about the chemical composition and quantities involved.

How to transport sodium alumanuide?

Sodium alumanuide is classified as ADR Class 4.3 (substances which, in contact with water, emit flammable gases), Packing Group II. Transport requires appropriate UN-approved packaging designed for water-reactive substances. Vehicles must carry proper documentation, emergency response information, and appropriate firefighting equipment. Drivers need ADR certification, and the material must be protected from moisture during transport. Proper labeling and placarding according to ADR regulations is mandatory.

Is sodium alumanuide subject to specific regulations?

Sodium alumanuide is subject to standard chemical regulations including REACH registration requirements in the European Union. While it is not classified as a Substance of Very High Concern (SVHC), it must comply with CLP regulation requirements for classification, labeling, and packaging. Users must follow occupational health and safety regulations, transport regulations (ADR), and local environmental protection laws. Proper safety data sheets must accompany all shipments and be available to users.

Where to buy sodium alumanuide in Europe?

Sodium alumanuide is available through OYSI, a specialized European distributor of technical chemicals and laboratory reagents. As an established chemical distributor, OYSI can provide this compound with appropriate documentation, safety data sheets, and regulatory compliance information. Contact OYSI directly for availability, specifications, and ordering information. Ensure your application and handling capabilities are appropriate for this reactive chemical before procurement.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.