2,4-diisocyanato-1-methylbenzene
C9H6N2O2
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Identification
- CAS Number
- 584-84-9
- EC Number
- 209-544-5
- UN Number
- 2078
- Index Number
- 615-006-00-4
- PubChem CID
- 11443
Physical-chemical properties
- Molecular Formula
- C9H6N2O2
- Molar Mass
- 174.16 g/mol
- IUPAC Name
- 2,4-diisocyanato-1-methylbenzene
Chemical Identifiers
- InChI
- InChI=1S/C9H6N2O2/c1-7-2-3-8(10-5-12)4-9(7)11-6-13/h2-4H,1H3
- InChI Key
- DVKJHBMWWAPEIU-UHFFFAOYSA-N
Overview
2,4-diisocyanato-1-methylbenzene (CAS 584-84-9) is an aromatic diisocyanate compound with highly reactive isocyanate functional groups and significant industrial applications. This organic compound, also known by its IUPAC designation 2,4-diisocyanato-1-methylbenzene, represents a crucial building block in the polyurethane and polymer chemistry industry. With a molecular formula of C9H6N2O2 and molecular weight of 174.16 g/mol, this substance belongs to the family of aromatic diisocyanates, characterized by two highly reactive NCO groups attached to a methylated benzene ring. The compound's structure provides excellent reactivity for polymerization reactions while maintaining thermal stability in finished products. Safety considerations are paramount when handling this material, as it carries multiple hazard classifications including carcinogenicity (Category 2), acute toxicity, respiratory sensitization, and skin sensitization properties. The substance requires careful handling protocols due to its Classification 6.1 status under ADR transport regulations and displays GHS08 and GHS06 pictograms with a "Danger" signal word. Unlike simpler aromatic compounds such as chloromethylbenzene or N-methylaniline, this diisocyanate demands specialized storage conditions and employee protection measures. Primary industrial applications include polyurethane foam production, elastomer manufacturing, and specialty coating formulations. The compound serves as a key intermediate in producing flexible polyurethane foams for automotive, furniture, and construction industries. Additionally, it functions as a crosslinking agent in high-performance adhesives and sealants where chemical resistance and durability are essential. OYSI maintains reliable supply chains for 2,4-diisocyanato-1-methylbenzene, ensuring consistent availability for European industrial customers requiring this specialized chemical intermediate.
Safety & Classification
Carc. 2; Acute Tox. 2 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Resp. Sens. 1; Skin Sens. 1; Aqu...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Suspected of causing cancer.
Fatal if inhaled.
May cause respiratory irritation.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Harmful to aquatic life with long lasting effects.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
Skin Contact
Measures if substance contacts the skin
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2078 |
| ADR Class | 6.1 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | Toluendiisocyanat, technisch, flüssig |
| Marine Pollutant | No |
Frequently Asked Questions
What is 2,4-diisocyanato-1-methylbenzene?
2,4-diisocyanato-1-methylbenzene is an aromatic diisocyanate compound with the molecular formula C9H6N2O2 and CAS number 584-84-9. This organic chemical belongs to the isocyanate family and has a molecular weight of 174.16 g/mol. It is classified as a hazardous substance with multiple health risks including carcinogenic properties, acute toxicity, and respiratory sensitization potential, requiring careful handling in industrial applications.
What are the physicochemical properties of 2,4-diisocyanato-1-methylbenzene?
2,4-diisocyanato-1-methylbenzene is typically a liquid at room temperature with characteristic chemical properties common to aromatic isocyanates. As an organic compound containing reactive isocyanate groups, it exhibits high reactivity with water and alcohols. The substance requires careful handling due to its volatile nature and tendency to react with moisture in air, forming polyurea compounds and releasing carbon dioxide.
What is 2,4-diisocyanato-1-methylbenzene used for?
2,4-diisocyanato-1-methylbenzene is primarily used as a chemical intermediate in the production of polyurethane materials. It serves as a building block for manufacturing flexible and rigid polyurethane foams, coatings, adhesives, and elastomers. The compound is also utilized in specialized chemical synthesis processes and as a crosslinking agent in various polymer applications within the chemical and materials industries.
How to handle 2,4-diisocyanato-1-methylbenzene safely?
2,4-diisocyanato-1-methylbenzene must be handled with appropriate respiratory protection including full-face respirators with organic vapor cartridges. Chemical-resistant gloves, protective clothing, and eye protection are mandatory due to its skin and eye irritation properties. Work should be conducted in well-ventilated areas or under fume hoods, as the substance can cause respiratory sensitization and has acute toxicity potential.
How to store 2,4-diisocyanato-1-methylbenzene correctly?
2,4-diisocyanato-1-methylbenzene should be stored in tightly sealed containers in a cool, dry place away from moisture and heat sources. The storage area must be well-ventilated and separated from incompatible materials such as water, alcohols, and strong bases. Containers should be made of suitable materials resistant to isocyanates, and storage temperatures should be controlled to prevent decomposition or unwanted reactions.
What to do in case of contact with 2,4-diisocyanato-1-methylbenzene?
In case of skin contact with 2,4-diisocyanato-1-methylbenzene, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water. For eye contact, flush immediately with clean water for at least 15 minutes. If inhaled, move the person to fresh air immediately. Due to its acute toxicity classification, seek immediate medical attention in all cases of exposure and provide safety data sheet information to medical personnel.
How to dispose of 2,4-diisocyanato-1-methylbenzene appropriately?
2,4-diisocyanato-1-methylbenzene must be disposed of as hazardous waste according to local and national regulations. The substance cannot be discharged into sewers or water systems due to its environmental hazard classification. Disposal should be carried out by licensed waste management companies specialized in handling toxic and carcinogenic materials, following proper neutralization procedures when applicable.
How to transport 2,4-diisocyanato-1-methylbenzene?
2,4-diisocyanato-1-methylbenzene is classified as ADR Class 6.1 (Toxic substances) Packing Group II for transportation. It must be packaged in approved containers meeting UN specifications and labeled with appropriate hazard placards. Transport vehicles require proper documentation including transport documents and emergency response information. Only trained personnel should handle the transportation, following all dangerous goods regulations for toxic substances.
Is 2,4-diisocyanato-1-methylbenzene subject to specific regulations?
2,4-diisocyanato-1-methylbenzene is subject to extensive regulatory oversight under REACH and CLP regulations in Europe. Its classification as Carcinogenic Category 2 and Respiratory Sensitizer Category 1 places it under strict labeling and handling requirements. The substance requires safety data sheets, appropriate hazard communication, and may be subject to authorization or restriction procedures depending on its intended use and exposure scenarios.
Where to buy 2,4-diisocyanato-1-methylbenzene in Europe?
2,4-diisocyanato-1-methylbenzene is available through OYSI, a specialized European distributor of technical chemicals. As a professional chemical supplier, OYSI can provide this regulated substance to qualified industrial customers with appropriate documentation and safety requirements. Due to its hazardous classification, purchases typically require verification of proper handling capabilities and intended use documentation from buyers.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.