2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid

C14H16N4O9S3

CAS27624-67-5
GHS01 Gefahrensymbol: Explosionsgefährlich – Explodierende Bombe
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
27624-67-5
EC Number
424-870-1
UN Number
Index Number
607-554-00-8
PubChem CID
12081157

Physical-chemical properties

Molecular Formula
C14H16N4O9S3
Molar Mass
480.50 g/mol
IUPAC Name
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid

Chemical Identifiers

InChI
InChI=1S/C14H16N4O9S3/c15-11-7-12(16)14(29(21,22)23)8-13(11)18-17-9-1-3-10(4-2-9)28(19,20)6-5-27-30(24,25)26/h1-4,7-8H,5-6,15-16H2,(H,21,22,23)(H,24,25,26)
InChI Key
UDNJZJOGKPSADD-UHFFFAOYSA-N

Overview

2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid (CAS 27624-67-5) is an azo dye compound with explosive properties and strong sulfonating characteristics. This highly specialized chemical compound represents a unique class of azo dyes characterized by its complex molecular structure containing multiple sulfonic acid groups and amino substituents. With a molecular formula of C14H16N4O9S3 and molecular weight of 480.5 g/mol, this substance exhibits distinctive properties that make it valuable for specific industrial applications while requiring careful handling protocols. The compound's most notable characteristic is its classification as an explosive material (Expl. 1.1) combined with severe eye damage potential (Eye Dam. 1), requiring strict safety measures during storage, handling, and transportation. The presence of GHS01 and GHS05 pictograms on safety documentation emphasizes the critical importance of proper protective equipment and trained personnel when working with this material. Additionally, its aquatic chronic toxicity classification (Aquatic Chronic 3) necessitates environmental protection measures. The azo diazenyl bridge in its structure provides chromophoric properties typical of dye compounds, while the sulfonic acid groups contribute to water solubility and reactivity. Unlike simpler compounds such as 2,2-dibromo-2-nitroethanol, this complex molecule offers multifunctional capabilities in specialized applications. Primary industrial applications include advanced dye synthesis, specialized chemical intermediates production, and research applications in materials science. The compound serves particularly well in processes requiring both coloring properties and specific reactivity patterns from its sulfonic acid functionalities. OYSI maintains availability of this specialized compound for qualified industrial customers meeting appropriate safety and handling requirements.

Safety & Classification

Danger
Classification:

Expl. 1.1; Eye Dam. 1; Aquatic Chronic 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H201

Explosive; mass explosion hazard.

H318

Causes serious eye damage.

H412

Harmful to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Frequently Asked Questions

What is 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid?

2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid is a complex organic compound with CAS number 27624-67-5 and molecular formula C14H16N4O9S3. This substance belongs to the azo dye family, characterized by its diazenyl functional group linking two aromatic systems. With a molecular weight of 480.5 g/mol, it contains multiple sulfonic acid groups and amino substituents, making it highly polar and water-soluble.

What are the physicochemical properties of 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid?

2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid typically appears as a colored solid due to its azo structure. The presence of multiple sulfonic acid groups makes it highly water-soluble and hygroscopic. The compound has a molecular weight of 480.5 g/mol and contains three sulfur atoms within its structure. Its polar nature and ionic character result in good solubility in polar solvents, particularly water and alcohols.

What is 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid used for?

2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid is primarily used as a dye intermediate and colorant in textile and chemical industries. Its azo structure provides chromophoric properties essential for coloring applications. The compound serves as a building block for more complex dye formulations and may be used in specialized chemical synthesis. Its multiple functional groups make it suitable for chemical modifications and coupling reactions in industrial processes.

How to handle 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid safely?

2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid requires extreme caution due to its explosive properties (Expl. 1.1) and eye damage potential (Eye Dam. 1). Essential PPE includes explosion-proof equipment, safety goggles, chemical-resistant gloves, and protective clothing. Work in well-ventilated areas away from ignition sources, heat, and friction. Handle quantities as small as possible and follow strict protocols for explosive materials. Ensure emergency procedures are in place and personnel are trained in explosive substance handling.

How to store 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid correctly?

2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid must be stored in specialized explosive-rated facilities meeting regulatory requirements for Class 1.1 explosives. Store in original containers in cool, dry conditions away from heat sources, friction, and incompatible materials. Maintain strict inventory control and limit quantities. Ensure proper grounding of equipment and explosion-proof electrical installations. Regular inspection of storage conditions and containers is essential to prevent deterioration that could increase explosion risk.

What to do in case of contact with 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid?

Immediate action is crucial following contact with 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid due to its eye damage potential. For eye contact, flush immediately with large amounts of clean water for at least 15 minutes and seek urgent medical attention. For skin contact, remove contaminated clothing and wash thoroughly with soap and water. In case of ingestion or inhalation, seek immediate medical care. Never induce vomiting. Inform medical personnel about the substance's explosive and corrosive properties.

How to dispose of 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid appropriately?

2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid disposal requires specialized explosive waste management procedures due to its Class 1.1 explosive classification. Contact certified hazardous waste disposal companies experienced in explosive materials handling. Never attempt disposal through standard chemical waste streams or sewerage systems. The substance may also pose aquatic environmental risks (Aquatic Chronic 3). Follow local and international regulations for explosive waste disposal, including proper documentation and tracking throughout the disposal process.

How to transport 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid?

2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid transport requires compliance with dangerous goods regulations due to its explosive nature. Transportation must follow ADR/IMDG/IATA guidelines for Class 1.1 explosives, requiring specialized packaging, labeling, and documentation. Only qualified carriers with explosive materials permits can transport this substance. Vehicles must meet explosive transport specifications with proper placarding. Quantities are strictly limited, and specific routing requirements may apply. Coordination with authorities may be necessary for transport approval.

Is 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid subject to specific regulations?

2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid is subject to extensive regulations due to its explosive classification and hazardous properties. Under EU CLP Regulation, it requires specific hazard labeling with GHS01 and GHS05 pictograms. REACH registration may be required for commercial use. The substance is not currently listed as SVHC. Explosive regulations under national and international law apply for storage, handling, and transport. Environmental regulations may restrict discharge due to its aquatic toxicity classification.

Where to buy 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid in Europe?

2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid is available through OYSI, a specialized European distributor of chemical products with expertise in handling hazardous materials. Due to the substance's explosive classification, purchase requires compliance with strict regulatory requirements and proper licensing. OYSI can provide guidance on regulatory compliance, safe handling procedures, and appropriate packaging options. Contact OYSI directly to discuss your specific requirements, as this substance requires specialized handling and may have restricted availability due to its hazardous nature.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.