2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid
C14H16N4O9S3
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Identification
- CAS Number
- 27624-67-5
- EC Number
- 424-870-1
- UN Number
- Index Number
- 607-554-00-8
- PubChem CID
- 12081157
Physical-chemical properties
- Molecular Formula
- C14H16N4O9S3
- Molar Mass
- 480.50 g/mol
- IUPAC Name
- 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid
Chemical Identifiers
- InChI
- InChI=1S/C14H16N4O9S3/c15-11-7-12(16)14(29(21,22)23)8-13(11)18-17-9-1-3-10(4-2-9)28(19,20)6-5-27-30(24,25)26/h1-4,7-8H,5-6,15-16H2,(H,21,22,23)(H,24,25,26)
- InChI Key
- UDNJZJOGKPSADD-UHFFFAOYSA-N
Overview
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid (CAS 27624-67-5) is an azo compound featuring dual amino groups and sulfonic acid functionalities with explosive properties. This complex aromatic compound belongs to the azo dye family, characterized by its distinctive diazenyl linkage connecting two benzene ring systems. With a molecular formula of C14H16N4O9S3 and molecular weight of 480.5 g/mol, this substance exhibits significant structural complexity through its multiple functional groups including amino substituents, sulfonic acid groups, and sulfonylethyl chains. The presence of these diverse functional groups contributes to its unique chemical reactivity and application potential. The compound presents notable safety considerations, classified under GHS hazard categories including explosive properties (Expl. 1.1), serious eye damage potential (Eye Dam. 1), and chronic aquatic toxicity (Aquatic Chronic 3). The danger signal word and associated pictogrammes GHS01 and GHS05 emphasize the need for proper handling protocols and safety equipment when working with this material. Unlike simpler compounds such as 2,2-dibromo-2-nitroethanol, this azo derivative requires specialized storage and handling procedures due to its explosive classification. Industrial applications typically center around specialized dye intermediate synthesis, advanced materials development, and research applications requiring specific azo functionality. The compound's unique combination of amino and sulfonic acid groups makes it valuable for creating complex colorant systems and functional materials. Its structural similarity to other technical azo compounds enables its use in developing specialized chemical formulations where conventional dyes prove inadequate. OYSI maintains availability of this specialized azo compound for qualified industrial customers requiring technical-grade materials for research and manufacturing applications.
Safety & Classification
Expl. 1.1; Eye Dam. 1; Aquatic Chronic 3
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Frequently Asked Questions
What is 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid?
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid is a complex organic sulfonic acid compound with CAS number 27624-67-5. This chemical features a molecular formula of C14H16N4O9S3 and a molecular weight of 480.5 g/mol. It contains multiple functional groups including amino groups, sulfonic acid groups, and an azo linkage, making it a versatile chemical intermediate with specific industrial applications requiring careful handling due to its explosive and corrosive properties.
What are the physicochemical properties of 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid?
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid exhibits properties typical of sulfonated aromatic compounds with a molecular weight of 480.5 g/mol. The presence of multiple sulfonic acid groups suggests high water solubility and ionic character. The azo linkage typically imparts color properties to the compound. Due to its complex structure containing amino and sulfonic acid functionalities, it likely exists as a solid at room temperature with hygroscopic tendencies and requires specific storage conditions to maintain stability.
What is 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid used for?
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid serves primarily as a chemical intermediate in specialized industrial processes. Its complex structure with azo linkage and multiple functional groups makes it valuable in advanced chemical synthesis applications. The compound may be utilized in the production of specialty chemicals, research applications, or as a precursor for more complex molecular structures. Its specific applications require expert knowledge and controlled handling procedures due to its hazardous classification and explosive properties.
How to handle 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid safely?
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid requires extreme caution during handling due to its Expl. 1.1 and Eye Dam. 1 classifications. Essential PPE includes explosion-proof equipment, safety goggles or face shields for eye protection, chemical-resistant gloves, and protective clothing. Work must be conducted in controlled environments away from ignition sources, heat, and friction. Personnel should be trained in explosive material handling procedures and emergency response protocols. All handling operations should follow strict safety protocols to prevent accidental detonation or severe eye damage.
How to store 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid correctly?
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid must be stored in specialized facilities designed for explosive materials (Expl. 1.1). Storage requires temperature-controlled environments, away from heat sources, friction, impact, and incompatible materials. The storage area must comply with explosive storage regulations, featuring appropriate containment, ventilation, and safety systems. Containers should be properly labeled, sealed to prevent moisture absorption, and regularly inspected. Access should be restricted to trained personnel only, with emergency procedures readily available for explosive material incidents.
What to do in case of contact with 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid?
Immediate action is critical following contact with 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid due to its Eye Dam. 1 classification. For eye contact, flush immediately with large amounts of water for at least 15 minutes and seek emergency medical attention as permanent eye damage may occur. For skin contact, remove contaminated clothing and wash thoroughly with water. In case of inhalation or ingestion, move to fresh air and seek immediate medical attention. Never attempt to handle spills without proper training and equipment due to explosive hazard. Contact emergency services if necessary.
How to dispose of 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid properly?
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid disposal requires specialized hazardous waste management due to its explosive and corrosive properties. Disposal must comply with local and European waste regulations for explosive materials and hazardous chemicals. Only licensed waste disposal companies with explosive material handling capabilities should manage disposal. The compound cannot be disposed of through regular chemical waste streams due to explosion risk. Proper documentation, classification as hazardous waste, and adherence to ADR transport regulations during disposal transport are mandatory. Consult regulatory authorities for specific disposal requirements.
How to transport 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid?
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid transportation requires strict adherence to ADR regulations for explosive materials. Specialized packaging designed for explosive substances is mandatory, along with proper hazard labeling displaying GHS01 and GHS05 pictograms. Transport vehicles must be equipped for explosive cargo with appropriate safety equipment and trained drivers certified for dangerous goods transport. Documentation must include proper shipping names, hazard classifications, and emergency response information. Only authorized carriers with explosive material transport permits may handle shipment, following designated routes and safety protocols throughout the transport process.
Is 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid subject to special regulations?
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid is subject to extensive regulatory oversight under European legislation. It falls under CLP regulation with Danger signal word and specific hazard classifications (Expl. 1.1, Eye Dam. 1, Aquatic Chronic 3). REACH regulation applies for registration, evaluation, and authorization requirements. The compound is not currently listed as SVHC but requires compliance with explosive material regulations, occupational safety standards, and environmental protection measures. Additional permits may be required for handling, storage, and transport of explosive materials under national legislation in EU member states.
Where to buy 2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid in Europe?
2,4-diamino-5-[[4-(2-sulfooxyethylsulfonyl)phenyl]diazenyl]benzenesulfonic acid is available through OYSI, a specialized European distributor of technical chemicals with expertise in hazardous materials. As a professional chemical supplier, OYSI provides proper documentation, safety data sheets, and regulatory compliance support for this explosive compound. Due to the specialized nature and hazardous classification of this substance, procurement requires verification of proper handling capabilities, storage facilities, and regulatory permits. OYSI ensures appropriate packaging, transport arrangements, and technical support for customers requiring this specialized chemical intermediate across European markets.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.