2,3,4,6-tetrachlorophenol

C6H2Cl4O

CAS58-90-2
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
58-90-2
EC Number
200-402-8
UN Number
2020
Index Number
604-013-00-8
PubChem CID
6028

Physical-chemical properties

Molecular Formula
C6H2Cl4O
Molar Mass
231.90 g/mol
IUPAC Name
2,3,4,6-tetrachlorophenol

Chemical Identifiers

InChI
InChI=1S/C6H2Cl4O/c7-2-1-3(8)6(11)5(10)4(2)9/h1,11H
InChI Key
VGVRPFIJEJYOFN-UHFFFAOYSA-N

Overview

2,3,4,6-tetrachlorophenol (CAS 58-90-2) is a chlorinated phenolic compound with antimicrobial properties and high environmental persistence. This halogenated aromatic compound belongs to the tetrachlorophenol family and serves as an important intermediate in various industrial chemical processes. With its molecular formula C6H2Cl4O and molecular weight of 231.9 g/mol, 2,3,4,6-tetrachlorophenol exhibits the characteristic properties of heavily chlorinated phenols, including enhanced chemical stability and bioaccumulation potential compared to less substituted compounds like phenylhydrazine. The substance presents significant safety considerations due to its acute toxicity (Acute Tox. 3) and potential for skin and eye irritation. Its environmental impact profile is particularly notable, classified as Aquatic Acute 1 and Aquatic Chronic 1, indicating high toxicity to aquatic organisms with lasting effects. The compound requires careful handling protocols and falls under ADR transport class 6.1, reflecting its toxic nature during shipping and storage. In industrial applications, 2,3,4,6-tetrachlorophenol functions primarily as a chemical intermediate in the synthesis of other chlorinated compounds and as a preservative agent in specialized formulations. The compound also finds use in the production of pesticides and wood treatment products, where its antimicrobial properties provide effective protection against biological degradation. Given its regulatory classification and environmental persistence, proper handling procedures, appropriate personal protective equipment, and compliance with local environmental regulations are essential when working with this material. OYSI maintains availability of 2,3,4,6-tetrachlorophenol for qualified industrial customers with appropriate handling capabilities and regulatory compliance.

Safety & Classification

Danger
Classification:

Acute Tox. 3 *; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H301

Toxic if swallowed.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2020
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping Name2,3,4,6-Tetrachlorphenol, fest, frei von TCDD
Marine PollutantNo

Frequently Asked Questions

What is 2,3,4,6-tetrachlorophenol?

2,3,4,6-tetrachlorophenol is an organochlorine compound with the molecular formula C6H2Cl4O and CAS number 58-90-2. This chemical substance belongs to the chlorinated phenol family, featuring four chlorine atoms attached to a phenol ring at positions 2, 3, 4, and 6. With a molecular weight of 231.9 g/mol, it is classified as a hazardous substance requiring careful handling due to its acute toxicity and environmental impact.

What are the physicochemical properties of 2,3,4,6-tetrachlorophenol?

2,3,4,6-tetrachlorophenol typically appears as a crystalline solid at room temperature with a characteristic phenolic odor. The compound has limited water solubility but dissolves well in organic solvents such as alcohols and ethers. Its high chlorine content contributes to its stability and persistence in the environment. The molecular structure with four chlorine substituents affects its melting point, boiling point, and vapor pressure characteristics.

What is 2,3,4,6-tetrachlorophenol used for?

2,3,4,6-tetrachlorophenol is primarily used as an intermediate in chemical synthesis and as a precursor for manufacturing other chlorinated organic compounds. It finds applications in the production of pesticides, herbicides, and wood preservatives. The compound is also utilized in research and analytical chemistry as a reference standard. Its antimicrobial properties make it useful in certain industrial preservation applications where chemical stability is required.

How to handle 2,3,4,6-tetrachlorophenol safely?

2,3,4,6-tetrachlorophenol requires strict safety precautions due to its Acute Tox. 3 classification and irritant properties. Essential protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas or use fume hoods to avoid inhalation. Never eat, drink, or smoke when handling this substance. Wash hands thoroughly after use and ensure emergency eyewash stations are accessible.

How to store 2,3,4,6-tetrachlorophenol correctly?

2,3,4,6-tetrachlorophenol should be stored in tightly sealed, original containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers protected from light and moisture to prevent degradation. Store separately from strong oxidizing agents, bases, and metals. Ensure storage areas are equipped with appropriate spill containment measures and maintain proper inventory records due to its hazardous classification.

What to do in case of contact with 2,3,4,6-tetrachlorophenol?

2,3,4,6-tetrachlorophenol contact requires immediate first aid measures. For skin contact, remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes while holding eyelids open. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek medical attention. Always consult a physician after any significant exposure.

How to dispose of 2,3,4,6-tetrachlorophenol appropriately?

2,3,4,6-tetrachlorophenol disposal must comply with local and European waste regulations due to its hazardous classification. The substance cannot be disposed of in regular waste streams and requires treatment by licensed hazardous waste disposal companies. Incineration at high temperatures in approved facilities is typically the preferred disposal method. Empty containers should also be treated as hazardous waste. Consult local authorities for specific disposal requirements and authorized waste handlers.

How to transport 2,3,4,6-tetrachlorophenol?

2,3,4,6-tetrachlorophenol is classified under ADR Class 6.1 (toxic substances) Packing Group III for transportation. Packages must display appropriate hazard labels including GHS06 and GHS09 pictograms with 'Danger' signal word. Transport documents must include proper shipping names, UN numbers, and hazard classifications. Vehicles must carry appropriate emergency equipment and drivers require ADR training. Ensure packages are properly sealed and protected from damage during transit.

Is 2,3,4,6-tetrachlorophenol subject to specific regulations?

2,3,4,6-tetrachlorophenol is subject to European REACH regulation and CLP classification requirements. The substance displays GHS06 and GHS09 pictograms indicating acute toxicity and environmental hazards. It carries multiple hazard classifications including Acute Tox. 3, skin and eye irritation, and aquatic toxicity. While not currently listed as an SVHC, it requires safety data sheets, proper labeling, and compliance with occupational exposure limits where established by member states.

Where to buy 2,3,4,6-tetrachlorophenol in Europe?

2,3,4,6-tetrachlorophenol is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this substance with complete regulatory documentation, safety data sheets, and proper hazard labeling in compliance with European standards. As a professional chemical distributor, OYSI ensures product quality, regulatory compliance, and safe packaging for industrial customers across Europe. Contact OYSI directly for availability, specifications, and ordering information for your specific requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.