2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine

C9H14N2S2

CAS106264-79-3
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
106264-79-3
EC Number
403-240-8
UN Number
3082
Index Number
612-113-00-8
PubChem CID
86262

Physical-chemical properties

Molecular Formula
C9H14N2S2
Molar Mass
214.40 g/mol
IUPAC Name
2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine

Chemical Identifiers

InChI
InChI=1S/C9H14N2S2/c1-5-8(10)6(12-2)4-7(13-3)9(5)11/h4H,10-11H2,1-3H3
InChI Key
TXDBDYPHJXUHEO-UHFFFAOYSA-N

Overview

2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine (CAS 106264-79-3) is an aromatic diamine compound featuring methylsulfanyl substituents with specialized industrial applications. This aromatic diamine derivative represents a specialized chemical intermediate characterized by its unique molecular structure containing both amino and methylthio functional groups. With the molecular formula C9H14N2S2 and a molecular weight of 214.4 g/mol, this compound exhibits distinctive chemical properties that make it valuable for specific industrial synthesis processes. The presence of two amino groups in positions 1 and 3 of the benzene ring, combined with methylsulfanyl groups at positions 4 and 6, creates a molecule with multiple reactive sites suitable for complex chemical transformations. From a safety perspective, 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine is classified under several hazard categories including Acute Toxicity Category 4, Skin Sensitization Category 1, and Aquatic toxicity concerns for both acute and chronic exposure. The compound requires careful handling protocols and displays GHS07 and GHS09 pictograms with a "Warning" signal word. Transportation falls under ADR Class 9, indicating miscellaneous dangerous substances requiring appropriate shipping precautions. Industrial applications primarily focus on its role as an intermediate in specialty chemical synthesis, particularly in the development of advanced materials and pharmaceutical intermediates. The compound's unique substitution pattern makes it valuable for creating complex aromatic systems. Unlike simpler aromatic amines such as 1-N-phenyl-4-N-propan-2-ylbenzene-1,4-diamine, this methylsulfanyl-substituted derivative offers enhanced selectivity in specific synthetic pathways. Applications include polymer chemistry, where its multiple functional groups enable crosslinking reactions, and as a building block for heterocyclic compound synthesis. OYSI provides reliable access to 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine for qualified industrial customers across Europe, ensuring consistent quality and regulatory compliance for specialized chemical manufacturing requirements.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3082
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping Name6-Methyl-2,4-bis(methylthio)-phenylen-1,3-diamin
Marine PollutantNo

Frequently Asked Questions

What is 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine?

2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine is an organic chemical compound with CAS number 106264-79-3 and molecular formula C9H14N2S2. This aromatic diamine derivative contains two methylsulfanyl groups and has a molecular weight of 214.4 g/mol. It belongs to the family of substituted benzene diamines and is classified as a hazardous substance requiring careful handling due to its toxicity and environmental impact.

What are the physicochemical properties of 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine?

2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine has a molecular formula of C9H14N2S2 with a molar mass of 214.4 g/mol. The compound features a benzene ring substituted with two amino groups, one methyl group, and two methylsulfanyl groups. As an aromatic diamine, it typically exists as a solid at room temperature. Specific physical properties such as melting point, boiling point, and solubility data would need to be confirmed through technical documentation.

What is 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine used for?

2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine is primarily used as a chemical intermediate in organic synthesis and pharmaceutical manufacturing. Its diamine structure makes it valuable for producing polymers, dyes, and other complex organic compounds. The presence of methylsulfanyl groups provides specific reactivity for specialized chemical reactions. Industrial applications may include use in research and development, fine chemical production, and as a building block for advanced materials synthesis.

How to handle 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine safely?

2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine requires careful handling due to its Acute Tox. 4 and Skin Sens. 1 classifications. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation. Prevent skin and eye contact, and avoid ingestion. The substance carries Warning signal word and GHS07 pictogram, indicating moderate hazard level requiring standard laboratory safety precautions.

How to store 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine correctly?

2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine should be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers tightly closed and properly labeled. Due to its environmental hazard classification (Aquatic Acute 1, Aquatic Chronic 1), ensure secondary containment to prevent environmental release. Store away from oxidizing agents and strong acids. Maintain proper inventory records and ensure storage areas comply with local chemical storage regulations and fire safety requirements.

What to do in case of contact with 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine?

Immediate action is required upon contact with 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine. For skin contact, immediately remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. For eye contact, flush with water immediately and seek medical attention. If inhaled, move to fresh air. If ingested, do not induce vomiting and seek immediate medical attention. Due to its skin sensitization properties, monitor for allergic reactions and consult medical professionals promptly.

How to dispose of 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine appropriately?

2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine must be disposed of as hazardous waste through authorized waste management companies. Due to its aquatic toxicity classification, prevent release to waterways or soil. Contact licensed hazardous waste disposal services for proper treatment and disposal. Do not discharge to sewers or the environment. Maintain proper waste documentation and follow local, national, and EU waste regulations. Empty containers should also be treated as hazardous waste unless properly decontaminated.

How to transport 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine?

2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III. Transportation requires proper dangerous goods packaging, labeling, and documentation according to ADR regulations. Use UN-approved packaging and ensure proper placarding of vehicles. Shipping documents must include proper shipping names and hazard classifications. Only trained personnel should handle transportation, and emergency response information must be available during transport. Follow all applicable international dangerous goods regulations.

Is 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine subject to specific regulations?

2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine is subject to REACH registration requirements in the EU and must comply with CLP classification and labeling regulations. The substance is not currently listed as SVHC (Substance of Very High Concern). Users must follow occupational health and safety regulations, environmental protection laws, and dangerous goods transport regulations. Safety data sheets must be provided to downstream users, and proper risk assessments are required for workplace use.

Where to buy 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine in Europe?

2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides reliable supply chains for laboratory and industrial customers across Europe, ensuring proper handling, documentation, and regulatory compliance. As a professional chemical distributor, OYSI can provide technical support, safety data sheets, and certificates of analysis. Contact OYSI directly for availability, specifications, and pricing information for this specialized chemical intermediate.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.