1,2,3,4-tetranitro-9H-carbazole

C12H5N5O8

CAS6202-15-9
GHS01 Gefahrensymbol: Explosionsgefährlich – Explodierende Bombe
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
6202-15-9
UN Number
Index Number
613-003-00-2
PubChem CID
22245378

Physical-chemical properties

Molecular Formula
C12H5N5O8
Molar Mass
347.20 g/mol
IUPAC Name
1,2,3,4-tetranitro-9H-carbazole

Chemical Identifiers

InChI
InChI=1S/C12H5N5O8/c18-14(19)9-7-5-3-1-2-4-6(5)13-8(7)10(15(20)21)12(17(24)25)11(9)16(22)23/h1-4,13H
InChI Key
DAGSRNAIARXJOQ-UHFFFAOYSA-N

Overview

1,2,3,4-tetranitro-9H-carbazole (CAS 6202-15-9) is a highly nitrated heterocyclic aromatic compound with explosive properties and significant toxicity hazards. This polynitrated carbazole derivative represents a specialized class of energetic materials characterized by its four nitro groups positioned on the benzene ring portion of the carbazole structure. With a molecular formula of C12H5N5O8 and molecular weight of 347.2 g/mol, this compound exhibits the typical properties associated with heavily nitrated organic compounds. The presence of multiple nitro substituents imparts considerable explosive potential to the molecule, necessitating classification under explosive category 1.1 according to GHS standards. The compound's hazard profile includes both explosive and acute toxicity classifications, requiring careful handling protocols and specialized storage conditions. Its classification as Explosive 1.1 indicates mass explosion potential, while the multiple Acute Tox. 4 classifications across different exposure routes underscore the comprehensive toxicity concerns. The associated GHS01 and GHS07 pictograms reflect these explosive and health hazards respectively. Like other polynitrated compounds such as 2,4,6-trinitrobenzene-1,3-diol, this carbazole derivative finds applications primarily in specialized energetic formulations and research applications. Industrial uses typically include explosive compositions for mining operations, military applications, and specialized pyrotechnic formulations where controlled energy release is required. The compound may also serve as an intermediate in the synthesis of other energetic materials or as a research standard in explosives analysis. OYSI maintains availability of 1,2,3,4-tetranitro-9H-carbazole for qualified industrial customers requiring this specialized energetic compound for legitimate applications.

Safety & Classification

Danger
Classification:

Expl. 1.1; Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H201

Explosive; mass explosion hazard.

H332

Harmful if inhaled.

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Frequently Asked Questions

What is 1,2,3,4-tetranitro-9H-carbazole?

1,2,3,4-tetranitro-9H-carbazole is a highly nitrated organic compound with the molecular formula C12H5N5O8 and CAS number 6202-15-9. This carbazole derivative contains four nitro groups attached to the aromatic ring system, giving it explosive properties. With a molecular weight of 347.2 g/mol, it belongs to the class of polynitroaromatic compounds and is classified as a Category 1.1 explosive under GHS regulations.

What are the physicochemical properties of 1,2,3,4-tetranitro-9H-carbazole?

1,2,3,4-tetranitro-9H-carbazole typically appears as a crystalline solid with high density due to its multiple nitro groups. The compound exhibits limited solubility in most common solvents due to its highly nitrated structure and strong intermolecular interactions. Its physicochemical properties are dominated by the presence of four electron-withdrawing nitro groups, which significantly affect its stability, sensitivity, and reactivity compared to unsubstituted carbazole.

What is 1,2,3,4-tetranitro-9H-carbazole used for?

1,2,3,4-tetranitro-9H-carbazole is primarily used in specialized research applications and explosive formulations due to its energetic properties. Its applications are typically limited to controlled environments such as defense research, pyrotechnic development, and academic studies on energetic materials. The compound may also serve as an intermediate in the synthesis of other specialized nitroaromatic compounds for research purposes.

How to handle 1,2,3,4-tetranitro-9H-carbazole safely?

1,2,3,4-tetranitro-9H-carbazole must be handled with extreme caution due to its explosive nature and acute toxicity. Essential safety measures include wearing appropriate personal protective equipment (gloves, safety glasses, lab coat), working in well-ventilated areas or fume hoods, and avoiding friction, impact, or heat sources. Only trained personnel should handle this material, using anti-static equipment and grounding procedures to prevent accidental detonation.

How to store 1,2,3,4-tetranitro-9H-carbazole correctly?

1,2,3,4-tetranitro-9H-carbazole must be stored in approved explosive storage facilities with appropriate temperature and humidity control. The storage area should be isolated from incompatible materials, heat sources, and ignition sources. Containers should be properly labeled and stored in quantities compliant with local explosive storage regulations. Regular inspection of storage conditions and container integrity is essential to maintain safety and prevent degradation.

What to do in case of contact with 1,2,3,4-tetranitro-9H-carbazole?

Immediate action is required in case of contact with 1,2,3,4-tetranitro-9H-carbazole due to its acute toxicity classification. For skin contact, remove contaminated clothing and rinse thoroughly with water for at least 15 minutes. In case of eye contact, flush immediately with water and seek medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical care while providing safety data sheet information to medical personnel.

How to dispose of 1,2,3,4-tetranitro-9H-carbazole appropriately?

1,2,3,4-tetranitro-9H-carbazole disposal must be conducted by licensed hazardous waste specialists experienced with explosive materials. The compound cannot be disposed of through normal chemical waste streams due to its explosive classification. Disposal typically involves controlled detonation or specialized treatment at authorized facilities. All disposal activities must comply with local, national, and international regulations governing explosive waste management and require proper documentation.

How to transport 1,2,3,4-tetranitro-9H-carbazole?

Transportation of 1,2,3,4-tetranitro-9H-carbazole requires compliance with dangerous goods regulations due to its explosive classification. Special packaging, labeling with GHS01 and GHS07 pictograms, and documentation are mandatory. Transport must be conducted by certified carriers experienced with explosive materials, using appropriate vehicles and routes. Specific ADR/DOT classifications and shipping requirements must be verified with transport authorities before shipment.

Is 1,2,3,4-tetranitro-9H-carbazole subject to specific regulations?

1,2,3,4-tetranitro-9H-carbazole is subject to extensive regulations due to its explosive and toxic properties. Under REACH and CLP regulations, it requires proper classification, labeling, and safety data sheets. The compound is not currently listed as a SVHC substance, but its explosive nature subjects it to strict controls under explosive regulations, export controls, and potentially dual-use goods legislation depending on jurisdiction and intended use.

Where to buy 1,2,3,4-tetranitro-9H-carbazole in Europe?

OYSI serves as a specialized European distributor for 1,2,3,4-tetranitro-9H-carbazole, providing this highly regulated explosive compound to qualified customers. Due to the substance's explosive classification and regulatory requirements, purchases are restricted to authorized end-users with appropriate licenses and safety facilities. OYSI ensures full compliance with European regulations and provides comprehensive documentation and safety support for qualified buyers requiring this specialized chemical.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.