1,2,3,4-tetranitro-9H-carbazole
C12H5N5O8
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Identification
- CAS Number
- 6202-15-9
- UN Number
- Index Number
- 613-003-00-2
- PubChem CID
- 22245378
Physical-chemical properties
- Molecular Formula
- C12H5N5O8
- Molar Mass
- 347.20 g/mol
- IUPAC Name
- 1,2,3,4-tetranitro-9H-carbazole
Chemical Identifiers
- InChI
- InChI=1S/C12H5N5O8/c18-14(19)9-7-5-3-1-2-4-6(5)13-8(7)10(15(20)21)12(17(24)25)11(9)16(22)23/h1-4,13H
- InChI Key
- DAGSRNAIARXJOQ-UHFFFAOYSA-N
Overview
1,2,3,4-tetranitro-9H-carbazole (CAS 6202-15-9) is a highly nitrated explosive compound with extreme sensitivity and powerful detonation characteristics. This polynitrated carbazole derivative represents one of the most powerful explosive compounds in its chemical class, featuring four nitro groups strategically positioned on the carbazole ring system. With a molecular formula of C12H5N5O8 and molecular weight of 347.2 g/mol, this compound exhibits exceptional explosive properties that classify it under UN explosive class 1.1, indicating mass explosion hazard potential. The extensive nitration pattern of 1,2,3,4-tetranitro-9H-carbazole creates an extremely unstable molecular structure prone to violent decomposition under minimal stimulation. Its classification under GHS01 and GHS07 pictograms reflects both explosive and acute toxicity hazards, requiring specialized handling protocols and storage conditions. The compound shares structural similarities with other polynitrated explosives such as 2,4,6-trinitrobenzene-1,3-diol, though its carbazole backbone provides distinct performance characteristics. Safety considerations are paramount when handling this material, as it presents acute toxicity risks through multiple exposure routes alongside its primary explosive hazard. The compound requires storage in specialized facilities with appropriate temperature control, impact protection, and electrostatic discharge prevention measures. Industrial applications include specialized military ordnance, controlled demolition charges, and high-performance explosive research where maximum brisance is required. The compound also finds use in pyrotechnic formulations requiring intense energy release and in specialized mining operations demanding precise fragmentation control. OYSI maintains availability of 1,2,3,4-tetranitro-9H-carbazole for qualified industrial customers with appropriate licensing and safety certifications for explosive materials handling.
Safety & Classification
Expl. 1.1; Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Frequently Asked Questions
What is 1,2,3,4-tetranitro-9H-carbazole?
1,2,3,4-tetranitro-9H-carbazole is a highly nitrated organic compound with the molecular formula C12H5N5O8 and CAS number 6202-15-9. This carbazole derivative contains four nitro groups attached to the carbazole ring structure, giving it a molecular weight of 347.2 g/mol. It is classified as an explosive substance (Expl. 1.1) and exhibits acute toxicity properties, making it a hazardous chemical requiring specialized handling and safety measures.
What are the physicochemical properties of 1,2,3,4-tetranitro-9H-carbazole?
1,2,3,4-tetranitro-9H-carbazole is a solid crystalline compound at room temperature due to its aromatic structure and multiple nitro substituents. The presence of four electron-withdrawing nitro groups significantly affects its physical properties, likely resulting in low solubility in water but potential solubility in organic solvents. The compound's high degree of nitration contributes to its explosive nature and chemical instability under certain conditions.
What is 1,2,3,4-tetranitro-9H-carbazole used for?
1,2,3,4-tetranitro-9H-carbazole is primarily used in specialized research applications and potentially in explosive formulations due to its Expl. 1.1 classification. Its applications are typically limited to controlled laboratory environments for chemical research, analytical studies, or as a reference standard. Given its hazardous properties, this compound is not suitable for general industrial use and requires specialized expertise and facilities for safe handling and application.
How to handle 1,2,3,4-tetranitro-9H-carbazole safely?
1,2,3,4-tetranitro-9H-carbazole requires extreme caution during handling due to its explosive and toxic properties. Personnel must wear appropriate PPE including safety goggles, protective gloves, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods, away from heat sources, sparks, and friction. Only trained personnel familiar with explosive materials should handle this substance, following strict safety protocols and emergency procedures.
How to store 1,2,3,4-tetranitro-9H-carbazole correctly?
1,2,3,4-tetranitro-9H-carbazole must be stored in a cool, dry place away from heat, direct sunlight, and ignition sources due to its explosive nature. The storage area should be well-ventilated and separated from incompatible materials such as strong oxidizers, reducing agents, and organic materials. Containers should be properly labeled and stored in accordance with local regulations for explosive substances, with appropriate security measures and access restrictions.
What to do in case of contact with 1,2,3,4-tetranitro-9H-carbazole?
Immediate action is required upon contact with 1,2,3,4-tetranitro-9H-carbazole due to its acute toxicity. For skin contact, remove contaminated clothing and wash thoroughly with soap and water. In case of eye contact, rinse immediately with plenty of water for at least 15 minutes. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Contact emergency services if symptoms develop or exposure is significant.
How to dispose of 1,2,3,4-tetranitro-9H-carbazole appropriately?
1,2,3,4-tetranitro-9H-carbazole disposal requires specialized hazardous waste management due to its explosive and toxic properties. The substance must not be disposed of in regular waste streams or sewers. Contact licensed hazardous waste disposal companies experienced in handling explosive materials. Disposal must comply with local, national, and EU regulations for explosive and toxic substances. Small quantities may require controlled incineration or other approved destruction methods under professional supervision.
How to transport 1,2,3,4-tetranitro-9H-carbazole?
1,2,3,4-tetranitro-9H-carbazole transport requires compliance with ADR regulations for dangerous goods due to its explosive classification. Specialized packaging, labeling, and documentation are mandatory for road transport. Only authorized carriers with proper permits and training for explosive materials can transport this substance. Vehicle requirements, route restrictions, and emergency procedures must be followed according to international dangerous goods transport regulations.
Is 1,2,3,4-tetranitro-9H-carbazole subject to specific regulations?
1,2,3,4-tetranitro-9H-carbazole is subject to strict regulations under EU CLP regulation due to its explosive and acute toxicity classifications. REACH registration requirements apply for commercial use above tonnage thresholds. Additional restrictions may apply under national explosives regulations and precursor chemical legislation. Users must comply with workplace safety directives and may need special permits or licenses for possession and use of explosive substances.
Where to buy 1,2,3,4-tetranitro-9H-carbazole in Europe?
1,2,3,4-tetranitro-9H-carbazole is available through OYSI, a specialized European chemical distributor experienced in handling hazardous materials. Due to the substance's explosive and toxic properties, procurement requires proper documentation, end-user declarations, and compliance with regulatory requirements. OYSI ensures proper packaging, labeling, and transport according to safety regulations. Contact OYSI directly to discuss availability, regulatory compliance requirements, and safe delivery options for your specific application.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.