1,2,3,4-tetrahydronaphthalene
C10H12
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Identification
- CAS Number
- 119-64-2
- EC Number
- 204-340-2
- UN Number
- 3082
- Index Number
- 601-045-00-4
- PubChem CID
- 8404
Physical-chemical properties
- Molecular Formula
- C10H12
- Molar Mass
- 132.20 g/mol
- IUPAC Name
- 1,2,3,4-tetrahydronaphthalene
Chemical Identifiers
- InChI
- InChI=1S/C10H12/c1-2-6-10-8-4-3-7-9(10)5-1/h1-2,5-6H,3-4,7-8H2
- InChI Key
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N
Overview
1,2,3,4-Tetrahydronaphthalene (CAS 119-64-2) is a cyclic hydrocarbon solvent with aromatic properties and moderate volatility characteristics. This bicyclic organic compound, also known by its IUPAC designation 1,2,3,4-tetrahydronaphthalene, represents a partially saturated derivative of naphthalene where one of the benzene rings has been hydrogenated. With the molecular formula C10H12 and a molecular weight of 132.2 g/mol, this colorless liquid exhibits distinctive chemical properties that make it valuable across various industrial applications. The compound's structure combines the stability of an aromatic system with the reactivity potential of its saturated ring portion. From a safety perspective, 1,2,3,4-tetrahydronaphthalene is classified under the GHS system with Warning signal word, indicating moderate hazard levels. The substance presents skin and eye irritation potential (Skin Irrit. 2; Eye Irrit. 2) and shows aquatic chronic toxicity (Aquatic Chronic 2), requiring appropriate handling precautions. Its ADR classification as Class 9 miscellaneous dangerous goods necessitates proper transportation protocols. Unlike more reactive compounds such as 2-methylpropyl 2-(oxiran-2-yl)acetate, tetrahydronaphthalene's hazard profile is relatively manageable with standard industrial safety measures. Industrial applications include its use as a specialized solvent in chemical synthesis, as an intermediate in organic transformations, and in certain coating formulations where its unique solvent properties are advantageous. The compound's aromatic character combined with its partially saturated structure provides distinct dissolution characteristics compared to fully aromatic or aliphatic alternatives. OYSI maintains reliable supply channels for 1,2,3,4-tetrahydronaphthalene to support European industrial customers requiring this specialized chemical intermediate.
Safety & Classification
Skin Irrit. 2; Eye Irrit. 2; Aquatic Chronic 2
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3082 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | - |
| Proper Shipping Name | 1,2,3,4-Tetrahydronaphthalin |
| Marine Pollutant | No |
Frequently Asked Questions
What is 1,2,3,4-tetrahydronaphthalene?
1,2,3,4-tetrahydronaphthalene is an organic chemical compound with the molecular formula C10H12 and CAS number 119-64-2. It is a partially hydrogenated derivative of naphthalene, featuring a bicyclic structure where one benzene ring is fully saturated. With a molecular weight of 132.2 g/mol, this colorless to pale yellow liquid serves as an important intermediate in various chemical processes and industrial applications.
What are the physicochemical properties of 1,2,3,4-tetrahydronaphthalene?
1,2,3,4-tetrahydronaphthalene is a colorless to pale yellow liquid at room temperature with a characteristic aromatic odor. The compound has a molecular weight of 132.2 g/mol and the formula C10H12. It is relatively insoluble in water but miscible with most organic solvents including alcohols, ethers, and hydrocarbons. The substance exhibits typical properties of partially saturated aromatic hydrocarbons.
What is 1,2,3,4-tetrahydronaphthalene used for?
1,2,3,4-tetrahydronaphthalene is primarily used as a chemical intermediate in organic synthesis and as a solvent in various industrial processes. It serves as a precursor for the production of pharmaceuticals, agrochemicals, and specialty chemicals. The compound is also utilized in polymer chemistry, as a reaction medium for chemical transformations, and in the manufacture of fragrances and other fine chemicals due to its stable aromatic structure.
How to handle 1,2,3,4-tetrahydronaphthalene safely?
1,2,3,4-tetrahydronaphthalene requires careful handling as it can cause skin and eye irritation (Skin Irrit. 2; Eye Irrit. 2). Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation in work areas and avoid direct skin and eye contact. Handle in well-ventilated areas away from ignition sources, and follow good industrial hygiene practices to minimize exposure risks.
How to store 1,2,3,4-tetrahydronaphthalene correctly?
1,2,3,4-tetrahydronaphthalene should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers upright and properly labeled according to GHS requirements with Warning signal word and appropriate pictograms (GHS07, GHS09). Store away from incompatible materials and ensure secondary containment to prevent environmental release, as the substance is classified as Aquatic Chronic 2.
What to do in case of contact with 1,2,3,4-tetrahydronaphthalene?
In case of skin contact with 1,2,3,4-tetrahydronaphthalene, immediately remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with plenty of clean water for at least 15 minutes and remove contact lenses if present. If irritation persists, seek medical attention. In case of inhalation, move to fresh air immediately and consult a physician if symptoms develop.
How to dispose of 1,2,3,4-tetrahydronaphthalene properly?
1,2,3,4-tetrahydronaphthalene must be disposed of in accordance with local, national, and international regulations as hazardous waste. The substance cannot be disposed of in regular waste due to its environmental classification (Aquatic Chronic 2). Contact licensed waste disposal companies for proper treatment and disposal. Empty containers should also be handled as hazardous waste. Never discharge into drains, sewers, or the environment.
How to transport 1,2,3,4-tetrahydronaphthalene?
1,2,3,4-tetrahydronaphthalene is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. This classification requires appropriate packaging, labeling, and documentation according to dangerous goods regulations. Shipments must comply with ADR requirements including proper packaging specifications, hazard labels, and transport documentation. Only authorized carriers familiar with dangerous goods regulations should handle transportation of this substance.
Is 1,2,3,4-tetrahydronaphthalene subject to specific regulations?
1,2,3,4-tetrahydronaphthalene is subject to REACH regulation in Europe and must comply with CLP classification requirements. The substance is classified with hazard classes Skin Irrit. 2, Eye Irrit. 2, and Aquatic Chronic 2, requiring appropriate labeling with Warning signal word and GHS07/GHS09 pictograms. It is not currently listed as a Substance of Very High Concern (SVHC). Users must follow safety data sheet requirements and workplace exposure regulations.
Where to buy 1,2,3,4-tetrahydronaphthalene in Europe?
1,2,3,4-tetrahydronaphthalene is available through OYSI, a specialized European distributor of chemical products. OYSI provides this substance to industrial customers across Europe with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical distributor, OYSI ensures quality products meeting European standards and provides technical support for safe handling and application of 1,2,3,4-tetrahydronaphthalene in various industrial processes.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.