1,2,3,4-tetrahydronaphthalene

C10H12

CAS119-64-2
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
119-64-2
EC Number
204-340-2
UN Number
3082
Index Number
601-045-00-4
PubChem CID
8404

Physical-chemical properties

Molecular Formula
C10H12
Molar Mass
132.20 g/mol
IUPAC Name
1,2,3,4-tetrahydronaphthalene

Chemical Identifiers

InChI
InChI=1S/C10H12/c1-2-6-10-8-4-3-7-9(10)5-1/h1-2,5-6H,3-4,7-8H2
InChI Key
CXWXQJXEFPUFDZ-UHFFFAOYSA-N

Overview

1,2,3,4-Tetrahydronaphthalene (CAS 119-64-2) is a saturated bicyclic hydrocarbon with solvent properties and aromatic characteristics derived from naphthalene reduction. This chemical compound, also known by its CAS number 119-64-2 and EC number 204-340-2, represents a partially hydrogenated derivative of naphthalene where four hydrogen atoms have been added to one of the benzene rings. With a molecular formula of C10H12 and molecular weight of 132.2 g/mol, tetrahydronaphthalene exhibits unique properties that bridge aromatic and aliphatic hydrocarbon characteristics. The substance presents moderate safety considerations, classified under GHS pictograms GHS07 and GHS09 with a "Warning" signal word. Its hazard profile includes skin and eye irritation properties (Skin Irrit. 2; Eye Irrit. 2) and aquatic chronic toxicity (Aquatic Chronic 2). Transport classification falls under ADR Class 9, indicating miscellaneous dangerous substances requiring appropriate handling protocols. In industrial applications, 1,2,3,4-tetrahydronaphthalene serves primarily as a chemical intermediate in organic synthesis and as a specialized solvent for various chemical processes. Its unique bicyclic structure makes it valuable in the production of fine chemicals and pharmaceutical intermediates. The compound also finds use in research applications where its specific solvent properties are required. Within the broader context of organic chemistry, it shares certain applications with related compounds such as methyl (2E)-2-benzylidene-3-oxobutanoate in specialized synthesis processes. The substance requires careful handling with appropriate personal protective equipment and environmental precautions due to its irritant properties and potential aquatic impact. OYSI maintains availability of 1,2,3,4-tetrahydronaphthalene for qualified industrial customers across European markets.

Safety & Classification

Warning
Classification:

Skin Irrit. 2; Eye Irrit. 2; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3082
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping Name1,2,3,4-Tetrahydronaphthalin
Marine PollutantNo

Frequently Asked Questions

What is 1,2,3,4-tetrahydronaphthalene?

1,2,3,4-tetrahydronaphthalene is a partially hydrogenated aromatic compound derived from naphthalene with the molecular formula C10H12. Also known as tetralin, this organic solvent consists of a benzene ring fused to a cyclohexane ring. It has a molecular weight of 132.2 g/mol and is classified as mildly hazardous with skin and eye irritation properties, as well as chronic aquatic toxicity.

What are the physicochemical properties of 1,2,3,4-tetrahydronaphthalene?

1,2,3,4-tetrahydronaphthalene is a colorless to pale yellow liquid at room temperature with a characteristic aromatic odor. It has a boiling point of approximately 207°C and a density of about 0.97 g/cm³. The compound is practically insoluble in water but readily soluble in most organic solvents including alcohols, ethers, and hydrocarbons, making it an effective industrial solvent.

What is 1,2,3,4-tetrahydronaphthalene used for?

1,2,3,4-tetrahydronaphthalene is primarily used as an industrial solvent for resins, waxes, and oils in various manufacturing processes. It serves as a hydrogen donor in catalytic processes and as an intermediate in organic synthesis. The compound is also utilized in the production of specialty chemicals, as a dehydrogenation catalyst support, and in research applications requiring a stable aromatic solvent with moderate reactivity.

How to handle 1,2,3,4-tetrahydronaphthalene safely?

1,2,3,4-tetrahydronaphthalene should be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas or under fume extraction to avoid inhalation. Avoid sources of ignition and static electricity. Use non-sparking tools and ensure proper grounding of equipment during transfer operations to minimize fire risks.

How to store 1,2,3,4-tetrahydronaphthalene correctly?

1,2,3,4-tetrahydronaphthalene should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers away from incompatible materials such as strong oxidizing agents and acids. Store in appropriate secondary containment to prevent environmental release. Maintain storage temperatures below 25°C and ensure containers are properly labeled according to CLP regulations.

What to do in case of contact with 1,2,3,4-tetrahydronaphthalene?

In case of skin contact with 1,2,3,4-tetrahydronaphthalene, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15-20 minutes and seek medical attention. If inhaled, move to fresh air and seek medical advice if symptoms persist. Remove contaminated clothing before reuse.

How to dispose of 1,2,3,4-tetrahydronaphthalene properly?

1,2,3,4-tetrahydronaphthalene must be disposed of as hazardous waste according to local and European waste regulations. Contact licensed waste management companies for proper disposal through incineration at authorized facilities. Do not discharge into drains, soil, or water bodies due to its aquatic toxicity classification. Contaminated containers should also be treated as hazardous waste and disposed of accordingly.

How to transport 1,2,3,4-tetrahydronaphthalene?

1,2,3,4-tetrahydronaphthalene is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. It requires appropriate UN-specification packaging and proper shipping documentation including dangerous goods declarations. Vehicles must carry appropriate emergency equipment and drivers need ADR certification. Transport in accordance with European ADR regulations and ensure proper labeling and placarding of transport units.

Is 1,2,3,4-tetrahydronaphthalene subject to specific regulations?

1,2,3,4-tetrahydronaphthalene is regulated under European REACH and CLP regulations, requiring registration for commercial use and proper classification labeling. It is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with safety data sheet requirements and workplace exposure limits. Industrial users should implement appropriate risk management measures and may need to notify authorities depending on usage quantities and applications.

Where to buy 1,2,3,4-tetrahydronaphthalene in Europe?

1,2,3,4-tetrahydronaphthalene is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides high-quality chemical products with complete documentation including safety data sheets and certificates of analysis. Contact OYSI's technical team for availability, specifications, and delivery options tailored to your specific industrial requirements and location within Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.