1,1,1,3,3-pentafluorobutane

C4H5F5

CAS406-58-6
GHS02 Gefahrensymbol: Entzündbar – Flamme
Danger

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Identification

CAS Number
406-58-6
EC Number
430-250-1
UN Number
1993
Index Number
602-102-00-6
PubChem CID
67884

Physical-chemical properties

Molecular Formula
C4H5F5
Molar Mass
148.07 g/mol
IUPAC Name
1,1,1,3,3-pentafluorobutane

Chemical Identifiers

InChI
InChI=1S/C4H5F5/c1-3(5,6)2-4(7,8)9/h2H2,1H3
InChI Key
WZLFPVPRZGTCKP-UHFFFAOYSA-N

Overview

1,1,1,3,3-pentafluorobutane (CAS 406-58-6) is a fluorinated organic compound featuring five fluorine atoms attached to a four-carbon chain structure. This specialized fluorinated hydrocarbon represents an important class of organofluorine compounds widely utilized in industrial applications. With the molecular formula C4H5F5 and a molecular weight of 148.07 g/mol, 1,1,1,3,3-pentafluorobutane exhibits unique properties derived from its multiple fluorine substitutions on the butane backbone. The strategic placement of fluorine atoms at positions 1, 1, 1, 3, and 3 creates a compound with distinctive chemical and physical characteristics that distinguish it from conventional hydrocarbons. The substance is classified as a flammable liquid under GHS Category 2, requiring careful handling protocols and appropriate safety measures. Its hazard classification necessitates storage and transport under ADR Class 3 regulations, with the danger signal word and GHS02 pictogram indicating fire hazard potential. Despite its flammability classification, the fluorine content provides enhanced chemical stability and resistance to degradation compared to non-fluorinated analogs. In industrial applications, 1,1,1,3,3-pentafluorobutane serves as a valuable intermediate in fluorochemical synthesis, specialty solvent formulations, and as a component in heat transfer fluids. Its properties make it suitable for applications requiring thermal stability and chemical inertness, distinguishing it from simpler compounds like 1-chlorobutane or ethyl propanoate which lack the fluorine-enhanced characteristics. The compound's unique fluorination pattern enables its use in specialized cleaning applications and as a precursor for advanced materials production. OYSI maintains reliable supply chains for this technical fluorochemical to support European industrial customers requiring consistent quality and regulatory compliance.

Safety & Classification

Danger
Classification:

Flam. Liq. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number1993
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping Name1,1,1,3,3-Pentafluorbutan
Marine PollutantNo

Frequently Asked Questions

What is 1,1,1,3,3-pentafluorobutane?

1,1,1,3,3-pentafluorobutane is a fluorinated organic compound with the molecular formula C4H5F5 and CAS number 406-58-6. This synthetic chemical features five fluorine atoms attached to a four-carbon chain, giving it unique properties typical of fluorinated compounds. With a molecular weight of 148.07 g/mol, it belongs to the family of hydrofluorocarbons (HFCs) and is classified as a flammable liquid requiring careful handling and storage procedures.

What are the physicochemical properties of 1,1,1,3,3-pentafluorobutane?

1,1,1,3,3-pentafluorobutane is a colorless liquid at room temperature with low viscosity typical of fluorinated compounds. The presence of multiple fluorine atoms gives it low surface tension and reduced intermolecular forces compared to non-fluorinated analogs. It exhibits limited solubility in water due to its hydrophobic fluorinated structure but shows good compatibility with organic solvents. The compound has a relatively low boiling point and high vapor pressure.

What is 1,1,1,3,3-pentafluorobutane used for?

1,1,1,3,3-pentafluorobutane serves as a specialty solvent in various industrial applications, particularly in electronics cleaning and precision degreasing operations. It functions as an intermediate in the synthesis of other fluorinated compounds and specialty chemicals. The compound is also utilized in aerosol formulations and as a component in specialized cleaning systems where its unique solvency properties and low surface tension are advantageous for removing contaminants from sensitive surfaces.

How to handle 1,1,1,3,3-pentafluorobutane safely?

1,1,1,3,3-pentafluorobutane must be handled with appropriate safety precautions due to its Flam. Liq. 2 classification. Work in well-ventilated areas or under fume extraction to prevent vapor accumulation. Wear appropriate personal protective equipment including safety glasses, chemical-resistant gloves, and flame-resistant clothing. Eliminate all ignition sources including static electricity, sparks, and open flames. Use non-sparking tools and ensure proper grounding of equipment to prevent static discharge during handling operations.

How to store 1,1,1,3,3-pentafluorobutane correctly?

1,1,1,3,3-pentafluorobutane requires storage in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Store in tightly sealed, compatible containers to prevent vapor loss and contamination. Keep away from oxidizing agents and incompatible materials. Maintain storage temperature below flash point and ensure adequate fire protection systems are in place. Use appropriate secondary containment and ensure storage areas comply with local fire safety regulations for flammable liquids.

What to do in case of contact with 1,1,1,3,3-pentafluorobutane?

Immediate action is required upon contact with 1,1,1,3,3-pentafluorobutane to minimize potential health effects. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move person to fresh air and monitor breathing. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult safety data sheet for specific first aid measures.

How to dispose of 1,1,1,3,3-pentafluorobutane properly?

1,1,1,3,3-pentafluorobutane disposal must comply with local, national, and international waste regulations as it is classified as hazardous waste. Contact licensed waste disposal companies specialized in handling fluorinated organic compounds. Do not discharge into drains, waterways, or soil. Consider recovery and recycling options where available. Incineration should only be performed at authorized high-temperature facilities equipped with appropriate emission control systems to prevent release of hydrogen fluoride and other toxic combustion products.

How to transport 1,1,1,3,3-pentafluorobutane?

1,1,1,3,3-pentafluorobutane is classified under ADR Class 3, Group II, requiring specific transport procedures for flammable liquids. Use approved packaging and containers designed for Group II flammable liquids. Vehicles must display appropriate hazard placards and carry emergency response information. Drivers require ADR training certification. Ensure proper loading, securing, and documentation procedures are followed. Transport during cooler periods when possible and avoid routes through densely populated areas or environmentally sensitive zones.

Is 1,1,1,3,3-pentafluorobutane subject to specific regulations?

1,1,1,3,3-pentafluorobutane is subject to multiple regulatory frameworks including REACH registration requirements in the European Union. It falls under CLP regulation for classification and labeling as Flam. Liq. 2 with GHS02 pictogram. The compound is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with national chemical safety regulations, workplace exposure limits, and environmental protection requirements. Regular review of regulatory status is recommended as fluorinated compounds face increasing scrutiny.

Where to buy 1,1,1,3,3-pentafluorobutane in Europe?

1,1,1,3,3-pentafluorobutane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides comprehensive support including technical documentation, safety data sheets, and regulatory compliance assistance. As a professional chemical distributor, OYSI ensures proper handling, packaging, and transportation of this flammable liquid according to ADR regulations. Contact OYSI directly for availability, technical specifications, and delivery options for your specific industrial applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.