1-ethyl-1-methylpiperidin-1-ium iodide

C8H18IN

CAS4186-71-4
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
4186-71-4
EC Number
407-780-5
UN Number
3077
Index Number
613-146-00-0
PubChem CID
20153

Physical-chemical properties

Molecular Formula
C8H18IN
Molar Mass
255.14 g/mol
IUPAC Name
1-ethyl-1-methylpiperidin-1-ium iodide

Chemical Identifiers

InChI
InChI=1S/C8H18N.HI/c1-3-9(2)7-5-4-6-8-9;/h3-8H2,1-2H3;1H/q+1;/p-1
InChI Key
RWPRNPXSHGRVPR-UHFFFAOYSA-M

Overview

1-ethyl-1-methylpiperidin-1-ium iodide (CAS 4186-71-4) is a quaternary ammonium salt with ionic liquid properties and organic synthesis applications. This piperidinium-based ionic compound represents a specialized quaternary ammonium iodide salt featuring a six-membered saturated nitrogen heterocycle with ethyl and methyl substituents. With the molecular formula C8H18IN and a molecular weight of 255.14 g/mol, this substance exhibits the characteristic properties of ionic liquids, including thermal stability, low volatility, and distinctive electrochemical behavior that make it valuable in various technical applications. The compound is classified under acute toxicity category 4 and chronic aquatic toxicity category 2, requiring appropriate handling precautions as indicated by its warning signal word and GHS07/GHS09 pictograms. As a Class 9 ADR substance, it requires specific transport considerations for safe logistics management. The piperidinium cation structure provides enhanced stability compared to simpler quaternary ammonium compounds, while the iodide counterion contributes to its solubility characteristics and reactivity profile. Industrial applications typically include use as an ionic liquid medium for organic synthesis reactions, electrochemical processes, and as a phase transfer catalyst in chemical manufacturing. The compound's unique properties also make it suitable for specialized extraction processes and as an electrolyte component in certain electrochemical systems. Like other quaternary ammonium salts such as benzyl(tributyl)azanium compounds, it demonstrates effectiveness in facilitating reactions between polar and non-polar phases. OYSI maintains reliable supply chains for 1-ethyl-1-methylpiperidin-1-ium iodide to support European industrial customers requiring consistent quality and technical support for their specialized chemical processes.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameN-Ethyl-N-methylpiperidiniumiodid
Marine PollutantNo

Frequently Asked Questions

What is 1-ethyl-1-methylpiperidin-1-ium iodide?

1-ethyl-1-methylpiperidin-1-ium iodide is a quaternary ammonium compound with the molecular formula C8H18IN and CAS number 4186-71-4. This ionic liquid belongs to the piperidinium family and has a molecular weight of 255.14 g/mol. It is classified as a hazardous substance with acute toxicity and chronic aquatic toxicity properties, requiring careful handling in industrial applications.

What are the physicochemical properties of 1-ethyl-1-methylpiperidin-1-ium iodide?

1-ethyl-1-methylpiperidin-1-ium iodide is an ionic compound that typically appears as a solid at room temperature. As a quaternary ammonium salt, it exhibits high thermal stability and ionic conductivity. The compound contains both hydrophobic alkyl chains and a hydrophilic ionic center, influencing its solubility characteristics. Its physicochemical properties make it suitable for specialized chemical applications requiring ionic functionality.

What is 1-ethyl-1-methylpiperidin-1-ium iodide used for?

1-ethyl-1-methylpiperidin-1-ium iodide serves as an ionic liquid in various industrial applications including electrochemistry, catalysis, and organic synthesis. It functions as a solvent, electrolyte, or reaction medium in chemical processes requiring non-volatile, thermally stable ionic environments. The compound is particularly valuable in research and development applications where traditional organic solvents are unsuitable due to volatility or environmental concerns.

How to handle 1-ethyl-1-methylpiperidin-1-ium iodide safely?

Safe handling of 1-ethyl-1-methylpiperidin-1-ium iodide requires appropriate personal protective equipment including gloves, safety glasses, and laboratory coats due to its Acute Tox. 4 classification. Work in well-ventilated areas and avoid direct contact with skin, eyes, and mucous membranes. Follow standard laboratory safety protocols, use fume hoods when necessary, and ensure emergency eyewash stations and safety showers are accessible.

How to store 1-ethyl-1-methylpiperidin-1-ium iodide correctly?

Proper storage of 1-ethyl-1-methylpiperidin-1-ium iodide requires keeping containers tightly sealed in a cool, dry, well-ventilated area away from incompatible materials. Store in original containers with proper labeling including hazard pictograms GHS07 and GHS09. Maintain storage temperatures within recommended ranges and protect from moisture, direct sunlight, and sources of ignition. Implement appropriate containment measures to prevent environmental release.

What to do in case of contact with 1-ethyl-1-methylpiperidin-1-ium iodide?

Immediate first aid measures for 1-ethyl-1-methylpiperidin-1-ium iodide contact include flushing affected skin or eyes with plenty of water for at least 15 minutes. Remove contaminated clothing and seek medical attention if irritation persists. In case of inhalation, move to fresh air immediately. If ingested, rinse mouth with water and seek immediate medical advice. Do not induce vomiting unless directed by medical personnel.

How to dispose of 1-ethyl-1-methylpiperidin-1-ium iodide properly?

Proper disposal of 1-ethyl-1-methylpiperidin-1-ium iodide must comply with local, national, and European waste regulations due to its hazardous classification. Contact licensed waste disposal companies specialized in chemical waste management. Do not discharge into drains, waterways, or soil due to its Aquatic Chronic 2 classification. Maintain waste documentation and follow packaging requirements for hazardous waste transport and disposal.

How to transport 1-ethyl-1-methylpiperidin-1-ium iodide?

Transportation of 1-ethyl-1-methylpiperidin-1-ium iodide follows ADR Class 9 (Miscellaneous Dangerous Substances), Packing Group III regulations. Use appropriate UN-specification packaging and ensure proper labeling with hazard identification numbers and shipping names. Transport documentation must include safety data sheets and emergency response information. Drivers require ADR certification and vehicles must carry appropriate safety equipment for Class 9 substances.

Is 1-ethyl-1-methylpiperidin-1-ium iodide subject to special regulations?

1-ethyl-1-methylpiperidin-1-ium iodide is subject to REACH registration requirements and CLP classification regulations within the European Union. It is not currently listed as a Substance of Very High Concern (SVHC). Suppliers must provide safety data sheets and ensure proper classification with Warning signal word and appropriate GHS pictograms. Import/export may require additional documentation depending on destination country regulations.

Where to buy 1-ethyl-1-methylpiperidin-1-ium iodide in Europe?

1-ethyl-1-methylpiperidin-1-ium iodide is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides comprehensive support including technical documentation, safety data sheets, and regulatory compliance assistance for industrial customers. Contact OYSI's technical sales team for availability, packaging options, and delivery throughout Europe. Professional handling and logistics support ensure safe and compliant chemical supply chain management.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.