Sodium azanide

H2NNa

sodium azanide

CAS7782-92-5

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Identification

CAS Number
7782-92-5
EC Number
231-971-0
UN Number
1390
PubChem CID
24533

Physical-chemical properties

Molecular Formula
H2NNa
Molar Mass
39.01 g/mol
IUPAC Name
sodium azanide

Chemical Identifiers

InChI
InChI=1S/H2N.Na/h1H2;/q-1;+1
InChI Key
ODZPKZBBUMBTMG-UHFFFAOYSA-N

Overview

Sodium azanide (CAS 7782-92-5) is an inorganic sodium compound with strong reducing properties and high reactivity with water. Sodium azanide represents a specialized inorganic chemical compound characterized by its distinctive molecular structure combining sodium with the azanide ion. This white to off-white crystalline solid exhibits exceptional chemical reactivity, particularly in the presence of moisture and water, making it a compound that requires careful handling and specialized storage conditions. The substance belongs to the broader family of alkali metal compounds and shares certain reactive characteristics with other sodium-based reducing agents. As an ADR Class 4.3 material, sodium azanide demonstrates significant reactivity with water, generating flammable gases upon contact with moisture. This classification underscores the importance of maintaining strictly anhydrous conditions during storage, handling, and transportation. The compound's strong reducing properties make it valuable in specific industrial processes where controlled reduction reactions are required under inert atmosphere conditions. The industrial applications of sodium azanide primarily center around specialized chemical synthesis processes, particularly in the production of nitrogen-containing organic compounds and as a reducing agent in metallurgical applications. Its unique reactivity profile also makes it useful in certain pharmaceutical intermediate synthesis where selective reduction capabilities are essential. Like other highly reactive compounds such as potassium;sodium alloys, sodium azanide requires specialized equipment and expertise for safe handling. Safety protocols for sodium azanide handling must address its water-reactive nature, requiring implementation of moisture-exclusion techniques and appropriate personal protective equipment. Storage facilities must maintain dry, inert atmospheres to prevent unwanted reactions. OYSI supplies sodium azanide to qualified industrial customers with the technical support and safety documentation necessary for proper handling and application in specialized chemical processes.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1390
ADR Class4.3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameNatriumamid, fest
Marine PollutantNo

Frequently Asked Questions

What is sodium azanide?

Sodium azanide is an inorganic compound with the chemical formula H2NNa and CAS number 7782-92-5. It has a molecular weight of 39.013 g/mol and belongs to the family of sodium compounds. This chemical substance is characterized by its reactive nature and specific handling requirements due to its chemical properties.

What are the physicochemical properties of sodium azanide?

Sodium azanide is a solid compound at room temperature with high reactivity toward water and moisture. It typically appears as a white to off-white crystalline powder and is highly hygroscopic, meaning it readily absorbs moisture from air. The compound decomposes in contact with water, releasing ammonia gas and forming sodium hydroxide.

What is sodium azanide used for?

Sodium azanide serves as a strong base and nucleophile in organic synthesis reactions. It is primarily used in pharmaceutical manufacturing, fine chemical production, and as an intermediate in the synthesis of various nitrogen-containing compounds. The compound is also employed in specialized research applications and as a reagent in analytical chemistry.

How to handle sodium azanide safely?

Sodium azanide requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation of decomposition products. Avoid contact with water, acids, and oxidizing agents during handling to prevent hazardous reactions.

How to store sodium azanide correctly?

Sodium azanide must be stored in tightly sealed, moisture-proof containers in a cool, dry place away from incompatible materials. Keep containers away from water sources, acids, and oxidizing substances. Storage areas should be well-ventilated and equipped with appropriate fire safety measures. Regular container inspection is recommended to ensure integrity.

What to do in case of contact with sodium azanide?

Immediate removal from exposure is essential if contact with sodium azanide occurs. For skin contact, rinse thoroughly with plenty of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, flush with water immediately and seek medical attention. If inhaled, move to fresh air and consult medical personnel if symptoms persist.

How to dispose of sodium azanide appropriately?

Sodium azanide disposal must comply with local and national hazardous waste regulations. The compound should never be disposed of through regular waste streams or sewage systems. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may require neutralization under controlled conditions by trained personnel before disposal.

How to transport sodium azanide?

Sodium azanide is classified under ADR Class 4.3 (substances which, in contact with water, emit flammable gases) with Packing Group II. Transport requires appropriate UN specification packaging, proper labeling, and documentation. Vehicles must be equipped with suitable safety equipment, and drivers need ADR certification for dangerous goods transport.

Is sodium azanide subject to specific regulations?

Sodium azanide is regulated under various chemical safety frameworks including REACH registration requirements in Europe. It is not classified as a Substance of Very High Concern (SVHC) according to current data. However, users must comply with national chemical safety regulations, workplace safety standards, and environmental protection requirements applicable in their jurisdiction.

Where to buy sodium azanide in Europe?

Sodium azanide is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers. OYSI provides reliable supply chains and technical support for chemical procurement across Europe. Contact OYSI directly for availability, specifications, packaging options, and delivery arrangements to your specific location.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.