Pentachloro-lambda5-stibane

Cl5Sb

pentachloro-lambda5-stibane

CAS7647-18-9
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7647-18-9
EC Number
231-601-8
UN Number
1730
Index Number
051-002-00-3
PubChem CID
24294

Physical-chemical properties

Molecular Formula
Cl5Sb
Molar Mass
299.00 g/mol
IUPAC Name
pentachloro-lambda5-stibane

Chemical Identifiers

InChI
InChI=1S/5ClH.Sb/h5*1H;/q;;;;;+5/p-5
InChI Key
VMPVEPPRYRXYNP-UHFFFAOYSA-I

Overview

Pentachloro-lambda5-stibane (CAS 7647-18-9) is an antimony pentachloride compound with highly corrosive properties and significant industrial applications. This inorganic antimony compound, also known by its IUPAC designation pentachloro-lambda5-stibane, represents a critical chemical intermediate in various industrial processes. With the molecular formula Cl5Sb and a molar mass of 299 g/mol, this pentavalent antimony halide exhibits characteristic properties that make it valuable for specialized chemical applications while requiring careful handling due to its hazardous nature. The compound presents significant safety considerations, classified under the GHS system with Skin Corr. 1B and Aquatic Chronic 2 hazard classes. The "Danger" signal word and associated pictogrammes GHS05 and GHS09 indicate its corrosive nature and environmental hazards. Transportation falls under ADR Class 8, reflecting its corrosive classification and the need for specialized handling protocols during shipping and storage. In terms of chemical behavior, pentachloro-lambda5-stibane demonstrates strong Lewis acid properties, making it useful as a catalyst and chemical intermediate. Unlike related antimony compounds such as trichlorostibane, this pentachloride form offers enhanced reactivity for specific synthetic applications. Industrial applications primarily include its use as a catalyst in organic synthesis reactions, as a chemical intermediate in the production of antimony-containing compounds, and in specialized metallurgical processes where antimony chemistry is required. The compound's corrosive nature necessitates appropriate safety measures including proper ventilation, personal protective equipment, and environmental containment systems. Its aquatic chronic toxicity classification also requires careful consideration of environmental impact and waste management protocols. OYSI maintains reliable supply chains for pentachloro-lambda5-stibane to support European industrial customers requiring this specialized antimony compound.

Safety & Classification

Danger
Classification:

Skin Corr. 1B; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1730
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameAntimonpentachlorid, flüssig
Marine PollutantNo

Frequently Asked Questions

What is pentachloro-lambda5-stibane?

Pentachloro-lambda5-stibane is an inorganic antimony compound with the chemical formula Cl5Sb and CAS number 7647-18-9. This substance has a molecular weight of 299 g/mol and belongs to the family of antimony halides. It is classified as a corrosive substance with environmental hazard properties, requiring careful handling and storage. The compound exhibits typical characteristics of antimony pentahalides and is used in specialized industrial applications where antimony chemistry is required.

What are the physicochemical properties of pentachloro-lambda5-stibane?

Pentachloro-lambda5-stibane is an antimony pentachloride compound that typically appears as a yellowish or colorless liquid at room temperature. The substance has a molecular weight of 299 g/mol and tends to be highly reactive with moisture, producing corrosive hydrogen chloride vapors. It exhibits high solubility in polar organic solvents and reacts vigorously with water. The compound has a characteristic pungent odor and demonstrates typical Lewis acid behavior due to the antimony center.

What is pentachloro-lambda5-stibane used for?

Pentachloro-lambda5-stibane is primarily used as a catalyst and reagent in organic synthesis reactions, particularly in polymerization processes and as a Lewis acid catalyst. It serves as an intermediate in the production of other antimony compounds and specialty chemicals. The substance finds applications in the electronics industry for semiconductor processing and in certain pharmaceutical synthesis routes. Its strong Lewis acid properties make it valuable for specific chemical transformations requiring antimony-based catalysis.

How to handle pentachloro-lambda5-stibane safely?

Pentachloro-lambda5-stibane requires strict safety measures due to its corrosive nature (Skin Corr. 1B classification). Personnel must wear full chemical-resistant PPE including acid-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation of vapors. Avoid contact with skin, eyes, and clothing. Keep away from moisture and incompatible materials. Emergency eyewash stations and safety showers should be readily accessible when handling this substance.

How to store pentachloro-lambda5-stibane correctly?

Pentachloro-lambda5-stibane must be stored in tightly sealed, corrosion-resistant containers in a cool, dry, well-ventilated area away from moisture and heat sources. The storage area should be equipped with appropriate containment measures and kept separate from incompatible materials such as water, alcohols, and reducing agents. Containers should be clearly labeled and stored in secondary containment systems to prevent environmental release. Regular inspection of containers for signs of corrosion or leakage is essential for safe storage.

What to do in case of contact with pentachloro-lambda5-stibane?

Immediate action is required due to the corrosive nature of pentachloro-lambda5-stibane. For skin contact, immediately remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse thoroughly with water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. Seek immediate medical attention in all cases of exposure. Do not induce vomiting if ingested and provide supportive care until medical help arrives.

How to dispose of pentachloro-lambda5-stibane properly?

Pentachloro-lambda5-stibane must be disposed of as hazardous waste through licensed waste management companies in accordance with local and European regulations. The substance cannot be discharged to sewers, soil, or water bodies due to its corrosive and environmentally hazardous properties. Neutralization should only be performed by qualified personnel using appropriate containment and safety measures. Empty containers may also require special handling and disposal as they may retain hazardous residues. Always consult local environmental authorities for specific disposal requirements.

How to transport pentachloro-lambda5-stibane?

Pentachloro-lambda5-stibane is classified as ADR Class 8 (corrosive substances) Packing Group II, requiring specialized transport procedures. The substance must be packaged in UN-approved containers designed for corrosive liquids and properly labeled with appropriate hazard placards. Transport vehicles must carry emergency response information and appropriate neutralizing agents. Only certified carriers experienced in handling corrosive chemicals should transport this substance. All transport documentation must comply with ADR regulations and include proper shipping names and hazard classifications.

Is pentachloro-lambda5-stibane subject to specific regulations?

Pentachloro-lambda5-stibane is subject to REACH regulation requiring registration for import/manufacture above 1 ton per year in the EU. Under CLP regulation, it must be classified and labeled as Skin Corr. 1B and Aquatic Chronic 2 with appropriate hazard pictogrammes (GHS05, GHS09). The substance is not currently listed as an SVHC (Substance of Very High Concern). Users must comply with occupational exposure limits, environmental discharge restrictions, and maintain safety data sheets. Industrial users may need to implement risk management measures and conduct chemical safety assessments.

Where to buy pentachloro-lambda5-stibane in Europe?

Pentachloro-lambda5-stibane is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides this specialized antimony compound with full regulatory compliance including proper documentation, safety data sheets, and transport arrangements. As an established chemical distributor, OYSI ensures product quality and regulatory compliance for professional users requiring this specialized substance. Contact OYSI directly for availability, technical specifications, and delivery options tailored to your specific industrial requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.