N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine

C10H28N6

CAS4067-16-7
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
4067-16-7
EC Number
223-775-9
UN Number
2735
Index Number
612-064-00-2
PubChem CID
19990

Physical-chemical properties

Molecular Formula
C10H28N6
Molar Mass
232.37 g/mol
IUPAC Name
N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine

Chemical Identifiers

InChI
InChI=1S/C10H28N6/c11-1-3-13-5-7-15-9-10-16-8-6-14-4-2-12/h13-16H,1-12H2
InChI Key
LSHROXHEILXKHM-UHFFFAOYSA-N

Overview

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine (CAS 4067-16-7) is a polyethylene polyamine featuring multiple reactive amino groups and excellent chelating properties. This hexavalent polyamine compound, with molecular formula C10H28N6 and molecular weight 232.37 g/mol, represents a significant member of the polyethylene polyamine family used extensively in industrial chemistry. Also identified by EC number 223-775-9, this substance exhibits exceptional reactivity due to its six amino functional groups distributed along a flexible ethylene chain backbone. The compound's structure enables it to form stable complexes with metal ions and participate in various cross-linking reactions. Safety considerations are paramount when handling this material, as it is classified as corrosive to skin (Skin Corr. 1B) and may cause skin sensitization (Skin Sens. 1). The substance also presents environmental hazards, being classified as Aquatic Acute 1 and Aquatic Chronic 1, requiring careful containment and disposal procedures. Transport regulations classify it under ADR Class 8, reflecting its corrosive nature. Primary industrial applications include epoxy resin curing systems, where its multiple amino groups provide exceptional cross-linking density and mechanical properties. The compound serves as an effective chelating agent in water treatment and metal processing applications, competing with other specialty chemicals like 3-[[bis(2-ethylhexyl)amino]methyl]-1,3-benzothiazole-2-thione in certain metal complexation applications. Additionally, it functions as an intermediate in the synthesis of specialty polymers and surfactants. OYSI maintains reliable inventory of this technical-grade polyamine for European industrial customers requiring consistent quality and regulatory compliance.

Safety & Classification

Danger
Classification:

Skin Corr. 1B; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2735
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NamePentaethylenhexamin
Marine PollutantNo

Frequently Asked Questions

What is N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is a polyethylene polyamine compound with CAS number 4067-16-7. This chemical substance contains multiple amino groups in its structure, giving it strong basic properties. With a molecular formula of C10H28N6 and molecular weight of 232.37 g/mol, it belongs to the family of aliphatic polyamines. The compound is classified as corrosive and sensitizing, requiring careful handling in industrial applications.

What are the physicochemical properties of N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is typically a viscous liquid at room temperature with a characteristic amine odor. The compound exhibits high water solubility due to its multiple amino groups, which can form hydrogen bonds with water molecules. Its basic nature results in high pH values in aqueous solutions. The presence of six nitrogen atoms in the molecular structure contributes to its strong nucleophilic and chelating properties.

What is N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine used for?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine serves as a curing agent for epoxy resins and as a crosslinking agent in polymer chemistry. It functions as a chelating agent in water treatment applications and metal complex formation. The compound is utilized in the production of specialized coatings, adhesives, and sealants. Its multiple reactive amino groups make it valuable for synthesizing other nitrogen-containing compounds and as an intermediate in chemical manufacturing processes.

How to handle N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine safely?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine requires strict safety measures due to its Skin Corr. 1B and Skin Sens. 1 classifications. Use full chemical-resistant PPE including nitrile gloves, safety goggles, and face protection. Work in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid direct skin and eye contact as the substance can cause severe burns and sensitization. Emergency eyewash stations and safety showers should be readily accessible when handling this corrosive material.

How to store N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine correctly?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine must be stored in tightly sealed containers made of compatible materials in a cool, dry, well-ventilated area. Keep away from incompatible substances such as strong acids, oxidizing agents, and moisture-sensitive materials. Store separately from food, feed, and drinking water. The storage area should be equipped with appropriate containment measures to prevent environmental release. Temperature control is important to maintain product stability and prevent degradation.

What to do in case of contact with N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

Immediate action is required for contact with N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine due to its corrosive nature. For skin contact, immediately remove contaminated clothing and rinse affected area with copious amounts of water for at least 15 minutes. For eye contact, flush immediately with water for at least 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Seek immediate medical attention for all exposure routes. Do not induce vomiting if ingested.

How to dispose of N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine appropriately?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine waste must be disposed of through licensed hazardous waste disposal facilities in accordance with local, national, and EU regulations. The substance cannot be discharged to sewers or waterways due to its Aquatic Acute 1 and Aquatic Chronic 1 classifications. Waste containers should be properly labeled and segregated from other waste streams. Consider neutralization or treatment options before disposal where technically feasible and permitted by regulations.

How to transport N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is classified as ADR Class 8 (Corrosive substances), Packing Group II, indicating high corrosivity. Transportation requires appropriate UN-specification packaging, proper labeling with corrosive hazard labels, and transport documents. Vehicles must carry appropriate emergency equipment and drivers need ADR certification. The substance must be segregated from incompatible materials during transport and protected from damage that could cause leakage.

Is N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine subject to specific regulations?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is subject to REACH regulation requiring registration for manufacture or import above 1 tonne per year. Under CLP regulation, it must be classified and labeled with Danger signal word and pictograms GHS05, GHS07, and GHS09. The substance is not currently listed as SVHC but may be subject to additional restrictions due to its environmental hazard classifications. Industrial users must implement appropriate risk management measures and exposure controls.

Where to buy N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine in Europe?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this compound to industrial customers across Europe with appropriate documentation including safety data sheets and certificates of analysis. As a professional chemical distributor, OYSI ensures compliance with European regulations and provides technical support for proper handling and application. Contact OYSI directly for availability, specifications, and regulatory documentation for your specific application requirements.

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N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is a dangerous good. We support you with labeling, packaging, and transport documentation.

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Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.