N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine

C10H28N6

CAS4067-16-7
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
4067-16-7
EC Number
223-775-9
UN Number
2735
Index Number
612-064-00-2
PubChem CID
19990

Physical-chemical properties

Molecular Formula
C10H28N6
Molar Mass
232.37 g/mol
IUPAC Name
N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine

Chemical Identifiers

InChI
InChI=1S/C10H28N6/c11-1-3-13-5-7-15-9-10-16-8-6-14-4-2-12/h13-16H,1-12H2
InChI Key
LSHROXHEILXKHM-UHFFFAOYSA-N

Overview

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine (CAS 4067-16-7) is a polyethyleneamine compound with multiple reactive amino groups and strong chelating properties. This hexafunctional amine, also known by its molecular formula C10H28N6, represents a significant member of the polyethyleneamine family used extensively in industrial applications. With a molecular weight of 232.37 g/mol, this compound features six amino groups distributed along its ethylene-bridged chain structure, providing exceptional reactivity and versatility in chemical processes. The multiple nitrogen centers enable strong coordination with metal ions, making it particularly valuable as a chelating agent and complexing compound. From a safety perspective, this substance requires careful handling due to its corrosive nature (Skin Corr. 1B) and potential for skin sensitization (Skin Sens. 1). The compound carries danger pictogrammes GHS05, GHS07, and GHS09, indicating corrosive, harmful, and environmental hazard properties respectively. Its classification as ADR Class 8 reflects its corrosive transportation requirements, while its aquatic toxicity classifications (Aquatic Acute 1; Aquatic Chronic 1) necessitate proper environmental controls during use and disposal. Primary industrial applications include metal treatment processes where its chelating properties prove essential, epoxy curing systems where the multiple amino groups serve as effective crosslinking agents, and specialized chemical synthesis as a building block for more complex molecules. Unlike simpler compounds such as 1-dodecylpyrrolidin-2-one, this polyamine's multiple functional groups enable more sophisticated chemical modifications and applications. OYSI maintains reliable supplies of this specialized polyethyleneamine for European industrial customers requiring consistent quality and technical support.

Safety & Classification

Danger
Classification:

Skin Corr. 1B; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2735
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NamePentaethylenhexamin
Marine PollutantNo

Frequently Asked Questions

What is N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is a polyamine compound with the molecular formula C10H28N6 and CAS number 4067-16-7. This chemical features multiple amino groups connected by ethylene bridges, giving it strong basic properties and high reactivity. With a molecular weight of 232.37 g/mol, it belongs to the family of linear polyethyleneamines and exhibits significant biological activity due to its multiple nitrogen centers.

What are the physicochemical properties of N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is typically a viscous liquid at room temperature with a characteristic amine odor. The compound is highly soluble in water and polar solvents due to its multiple amino groups, which can form hydrogen bonds. It exhibits strong alkaline properties and readily absorbs moisture and carbon dioxide from air. The presence of six nitrogen atoms makes it highly reactive toward acids and electrophiles.

What is N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine used for?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is primarily used as a curing agent for epoxy resins and as a cross-linking agent in polymer chemistry. It serves as an intermediate in the synthesis of chelating agents and specialty chemicals. The compound finds applications in the production of adhesives, coatings, and composites where its multiple amino groups provide excellent bonding properties. It may also be used in water treatment applications as a complexing agent.

How to safely handle N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine requires careful handling due to its corrosive properties (Skin Corr. 1B) and sensitizing potential (Skin Sens. 1). Wear chemical-resistant gloves, safety goggles, and protective clothing when handling. Work in well-ventilated areas or under fume extraction to avoid inhalation. Avoid direct skin and eye contact as the substance can cause severe burns. Use appropriate respiratory protection if aerosols may be generated during use.

How to properly store N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine should be stored in tightly sealed containers in a cool, dry place away from heat sources and incompatible materials. Keep containers protected from moisture and carbon dioxide to prevent degradation. Store away from acids, oxidizing agents, and reactive metals. Ensure adequate ventilation in storage areas and maintain temperatures below 25°C when possible. Use corrosion-resistant containers such as polyethylene or specially lined steel drums.

What to do in case of contact with N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

Immediate action is required due to the corrosive nature of N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine. For skin contact, immediately flush with copious amounts of water for at least 15 minutes while removing contaminated clothing. For eye contact, rinse immediately with water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. If swallowed, do not induce vomiting and seek immediate medical care. Always consult a physician after any exposure.

How to properly dispose of N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine must be disposed of as hazardous waste in accordance with local and national regulations. Due to its aquatic toxicity classification (Aquatic Acute 1, Aquatic Chronic 1), prevent release to waterways and soil. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small laboratory quantities may require neutralization before disposal. Empty containers should also be treated as hazardous waste due to residual contamination.

How to transport N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is classified as ADR Class 8 (corrosive substances), Packing Group II, indicating moderate danger level. Transportation requires appropriate UN-specification packaging designed for corrosive liquids. Vehicles must display proper hazard placards and carry emergency response information. Drivers need ADR training certification for dangerous goods transport. Ensure packages are properly labeled with GHS pictograms (GHS05, GHS07, GHS09) and handle with appropriate precautions during loading and unloading operations.

Is N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine subject to specific regulations?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is regulated under the CLP Regulation with classification as Skin Corr. 1B, Skin Sens. 1, and Aquatic toxicity categories. It falls under REACH registration requirements for import and manufacture in the EU. The substance is not currently listed as an SVHC (Substance of Very High Concern). Users must comply with occupational exposure limits and provide appropriate safety data sheets. Environmental discharge may be restricted due to its aquatic toxicity classification.

Where to buy N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine in Europe?

N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this polyamine compound with full regulatory compliance documentation including safety data sheets and certificates of analysis. As experienced chemical distributors, OYSI ensures proper packaging, labeling, and transportation according to ADR regulations. Contact OYSI directly for availability, technical specifications, and pricing information for your specific application requirements.

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N'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine is a dangerous good. We support you with labeling, packaging, and transport documentation.

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Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.