Molecular hydrogen
H2
molecular hydrogen
Consulting for Molecular hydrogen
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Identification
- CAS Number
- 1333-74-0
- EC Number
- 215-605-7
- UN Number
- 1966
- Index Number
- 001-001-00-9
- PubChem CID
- 783
Physical-chemical properties
- Molecular Formula
- H2
- Molar Mass
- 2.02 g/mol
- IUPAC Name
- molecular hydrogen
Chemical Identifiers
- InChI
- InChI=1S/H2/h1H
- InChI Key
- UFHFLCQGNIYNRP-UHFFFAOYSA-N
Overview
Molecular hydrogen (CAS 1333-74-0) is the lightest diatomic gas with exceptional flammability properties and versatile industrial applications. This colorless, odorless gas represents the simplest and most abundant element in the universe, consisting of two hydrogen atoms bonded together with the molecular formula H2. With a molecular weight of just 2.016 g/mol, molecular hydrogen exhibits unique physical and chemical characteristics that make it invaluable across numerous industrial sectors. The substance's extremely low density allows it to diffuse rapidly through materials and escape containment more easily than other gases, requiring specialized handling protocols. From a safety perspective, molecular hydrogen is classified as a highly flammable gas (Flam. Gas 1) and pressurized gas (Press. Gas) under GHS classification, displaying both flame and gas cylinder pictogrammes. Its wide flammability range of 4-75% in air, combined with a low ignition energy, necessitates stringent fire prevention measures during storage and handling. The gas burns with a nearly invisible flame, adding complexity to safety protocols in industrial environments. Key industrial applications include chemical synthesis processes, particularly in hydrogenation reactions and ammonia production, petroleum refining operations for hydrodesulfurization and hydrocracking, and as a reducing agent in metallurgical processes. The electronics industry utilizes high-purity molecular hydrogen for semiconductor manufacturing, while emerging applications in fuel cell technology and energy storage continue to expand market demand. Unlike heavier hydrocarbons such as prop-1-ene or methoxymethane, molecular hydrogen offers superior diffusion properties and clean combustion characteristics. OYSI provides reliable supply of technical-grade molecular hydrogen to meet diverse European industrial requirements, ensuring consistent quality and regulatory compliance for professional applications.
Safety & Classification
Flam. Gas 1; Press. Gas
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Extremely flammable gas.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Transport (ADR)
| UN Number | 1966 |
| ADR Class | 2 |
| Packing Group | |
| Tunnel Code | B/D |
| Proper Shipping Name | Wasserstoff, tiefgekühlt, flüssig |
| Marine Pollutant | No |
Frequently Asked Questions
What is molecular hydrogen?
Molecular hydrogen is the simplest and lightest chemical element in its diatomic form, consisting of two hydrogen atoms bonded together (H2). With a molecular weight of 2.016 g/mol and CAS number 1333-74-0, it represents the most abundant element in the universe. This colorless, odorless gas is classified as a flammable gas under GHS regulations and requires careful handling due to its highly combustible nature and pressurized storage requirements.
What are the physicochemical properties of molecular hydrogen?
Molecular hydrogen is a colorless, odorless, and tasteless gas at room temperature and atmospheric pressure. It has an extremely low density, making it the lightest of all gases, and is poorly soluble in water. The gas has a very low boiling point (-252.9°C) and melting point (-259.1°C). Its small molecular size allows it to diffuse rapidly through many materials, and it burns with a nearly invisible pale blue flame in daylight.
What is molecular hydrogen used for?
Molecular hydrogen serves multiple industrial applications including chemical synthesis, particularly in ammonia production for fertilizers and methanol manufacturing. It is extensively used in petroleum refining for hydrocracking and desulfurization processes. Other applications include metal processing, electronics manufacturing for semiconductor production, food industry for hydrogenation of oils, and increasingly in fuel cell technology for clean energy generation. Research applications in laboratories also utilize hydrogen for various analytical and synthetic procedures.
How to handle molecular hydrogen safely?
Molecular hydrogen requires strict safety protocols due to its flammable gas classification (Flam. Gas 1). Always use appropriate personal protective equipment including safety glasses and flame-resistant clothing. Ensure adequate ventilation to prevent accumulation, as hydrogen can form explosive mixtures with air. Eliminate all ignition sources including static electricity, open flames, and hot surfaces. Use proper gas handling equipment, check for leaks regularly using appropriate detection methods, and never work alone when handling pressurized hydrogen systems.
How to store molecular hydrogen correctly?
Molecular hydrogen must be stored in appropriate pressure vessels designed for compressed gases, following ADR Class 2 requirements. Store cylinders in well-ventilated, dry areas away from heat sources, oxidizing agents, and ignition sources. Maintain storage temperature below 50°C and protect from direct sunlight. Ensure cylinders are secured upright and separated from incompatible materials. Regular inspection of storage equipment is essential due to hydrogen's tendency to embrittle certain metals over time.
What to do in case of contact with molecular hydrogen?
Molecular hydrogen itself is non-toxic, but exposure risks include asphyxiation and cold burns from pressurized gas release. In case of suspected inhalation in confined spaces, immediately move the person to fresh air and seek medical attention if breathing difficulties occur. For cold burns from pressurized gas contact, treat as frostbite by warming affected areas gradually with lukewarm water. Never attempt to stop large gas leaks directly; evacuate the area and contact emergency services while ensuring no ignition sources are present.
How to dispose of molecular hydrogen appropriately?
Molecular hydrogen disposal must comply with local environmental regulations and waste management requirements. Small quantities can be safely vented in well-ventilated outdoor areas away from ignition sources, allowing the gas to disperse harmlessly into the atmosphere. For larger quantities or pressurized containers, contact licensed waste disposal companies experienced in handling compressed gases. Empty cylinders should be returned to suppliers when possible, as they can be refilled and reused, supporting environmental sustainability.
How to transport molecular hydrogen?
Molecular hydrogen transport follows ADR Class 2 dangerous goods regulations for compressed gases. Proper packaging in DOT-approved pressure vessels is mandatory, with appropriate labeling including GHS02 and GHS04 pictograms and "Danger" signal word. Vehicles must carry appropriate emergency equipment and documentation. Drivers require dangerous goods training certification. Ensure adequate ventilation during transport and avoid routes through tunnels or densely populated areas when possible. Emergency response information must be readily available during transport.
Is molecular hydrogen subject to specific regulations?
Molecular hydrogen is regulated under multiple frameworks including CLP regulation for classification and labeling, showing Flam. Gas 1 and Press. Gas classifications with GHS02 and GHS04 pictograms. ADR regulations govern its transport as Class 2 dangerous goods. REACH registration applies for commercial use above tonnage thresholds. It is not classified as a SVHC substance. National regulations may impose additional requirements for storage, handling, and workplace exposure limits in industrial settings.
Where to buy molecular hydrogen in Europe?
Molecular hydrogen is available through OYSI, a trusted European distributor of technical chemicals serving industrial customers across the continent. OYSI provides high-quality molecular hydrogen with proper documentation, safety data sheets, and regulatory compliance support. As a specialized chemical distributor, OYSI ensures reliable supply chains and technical expertise to support your specific application requirements. Contact OYSI directly for availability, specifications, and delivery options tailored to your location and quantity needs.
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Molecular hydrogen is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.