Molecular hydrogen
H2
molecular hydrogen
Consulting for Molecular hydrogen
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Identification
- CAS Number
- 1333-74-0
- EC Number
- 215-605-7
- UN Number
- 1966
- Index Number
- 001-001-00-9
- PubChem CID
- 783
Physical-chemical properties
- Molecular Formula
- H2
- Molar Mass
- 2.02 g/mol
- IUPAC Name
- molecular hydrogen
Chemical Identifiers
- InChI
- InChI=1S/H2/h1H
- InChI Key
- UFHFLCQGNIYNRP-UHFFFAOYSA-N
Overview
Molecular hydrogen (CAS 1333-74-0) is the simplest diatomic molecule consisting of two hydrogen atoms with exceptional lightness and high flammability characteristics. As the lightest element in the periodic table, molecular hydrogen represents a fundamental chemical compound with significant industrial importance across multiple sectors. This colorless, odorless gas exists naturally as H2 molecules and demonstrates unique properties that make it both valuable and potentially hazardous in industrial applications. With a molecular weight of only 2.016 g/mol, hydrogen gas exhibits remarkable diffusion rates and buoyancy characteristics that distinguish it from other industrial gases. The safety profile of molecular hydrogen requires careful consideration due to its classification as a flammable gas category 1 and pressurized gas. The GHS02 and GHS04 pictograms indicate both fire hazard and pressure-related risks, necessitating appropriate handling procedures and storage conditions. Hydrogen's wide flammability range and low ignition energy make proper ventilation and explosion-proof equipment essential in processing environments. Primary industrial applications include chemical synthesis processes, particularly in hydrogenation reactions, metal processing for heat treatment and atmosphere control, and increasingly in fuel cell technology for clean energy applications. Unlike heavier hydrocarbons such as prop-1-ene or methoxymethane, molecular hydrogen offers unique advantages in applications requiring high purity reducing atmospheres and minimal molecular weight impact. The compound's role in emerging hydrogen economy initiatives has expanded its relevance beyond traditional chemical manufacturing into energy storage and transportation sectors. OYSI provides molecular hydrogen to European industrial customers, supporting diverse applications from pharmaceutical synthesis to advanced materials processing with reliable supply chain management.
Safety & Classification
Flam. Gas 1; Press. Gas
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Extremely flammable gas.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Transport (ADR)
| UN Number | 1966 |
| ADR Class | 2 |
| Packing Group | |
| Tunnel Code | B/D |
| Proper Shipping Name | Wasserstoff, tiefgekühlt, flüssig |
| Marine Pollutant | No |
Frequently Asked Questions
What is molecular hydrogen?
Molecular hydrogen is the simplest and lightest chemical element in its diatomic form, with the molecular formula H2 and CAS number 1333-74-0. It consists of two hydrogen atoms bonded together, forming a colorless, odorless, and highly flammable gas. With a molecular weight of 2.016 g/mol, it is the lightest molecule in existence and serves as a clean energy carrier and industrial reducing agent in various applications.
What are the physicochemical properties of molecular hydrogen?
Molecular hydrogen is a colorless, odorless, and tasteless gas under standard conditions. It has an extremely low density of 0.0899 g/L at STP, making it 14 times lighter than air. H2 is poorly soluble in water and has a very low boiling point of -252.8°C. It exhibits high flammability with a wide explosive range (4-75% in air) and burns with an almost invisible pale blue flame.
What is molecular hydrogen used for?
Molecular hydrogen serves multiple industrial applications including hydrogenation processes in food industry, petroleum refining for fuel production, and ammonia synthesis for fertilizers. It acts as a reducing agent in metallurgy for metal processing and semiconductor manufacturing. Additionally, H2 is increasingly used as a clean fuel for fuel cells in automotive and energy storage applications, producing only water as a byproduct when consumed.
How to handle molecular hydrogen safely?
Molecular hydrogen requires careful handling due to its extreme flammability and pressurized gas classification. Always use appropriate personal protective equipment including safety glasses and protective clothing. Ensure adequate ventilation to prevent accumulation, eliminate all ignition sources, and use spark-proof equipment. Handle cylinders carefully, secure them upright, and never allow the gas to reach concentrations above 4% in air to prevent explosive atmospheres.
How to store molecular hydrogen correctly?
Molecular hydrogen must be stored in properly designed pressure vessels in well-ventilated areas away from heat sources, flames, and oxidizing materials. Storage areas should be cool, dry, and equipped with hydrogen detection systems. Cylinders must remain upright, properly secured, and protected from physical damage. Ensure separation from incompatible materials like oxidizers and maintain storage temperatures within manufacturer specifications to prevent pressure buildup.
What to do in case of contact with molecular hydrogen?
Molecular hydrogen exposure primarily involves inhalation risks and fire hazards rather than direct toxicity. In case of gas leak, immediately evacuate the area, eliminate ignition sources, and ensure adequate ventilation. If someone experiences dizziness or asphyxiation symptoms from oxygen displacement, move them to fresh air immediately. For fire situations, shut off gas supply if safely possible and use appropriate fire suppression methods while calling emergency services.
How to dispose of molecular hydrogen appropriately?
Molecular hydrogen disposal must comply with local environmental regulations and waste management procedures. Small quantities can be safely vented in well-ventilated outdoor areas away from ignition sources, as H2 is environmentally benign. For larger amounts or pressurized containers, contact specialized waste management companies experienced in handling flammable gases. Never attempt to dispose of pressurized cylinders without proper depressurization by qualified personnel.
How to transport molecular hydrogen?
Molecular hydrogen is classified as ADR Class 2 dangerous goods for transportation, requiring compliance with international transport regulations. It must be shipped in UN-approved pressure vessels with proper labeling including GHS02 and GHS04 pictograms and 'Danger' signal word. Vehicles must be equipped with appropriate safety equipment, and drivers require hazardous materials certification. Ensure proper documentation and emergency response information accompany all shipments.
Is molecular hydrogen subject to specific regulations?
Molecular hydrogen is regulated under various European frameworks including CLP regulation for classification as Flam. Gas 1 and Press. Gas with 'Danger' signal word. It falls under REACH registration requirements but is not classified as a Substance of Very High Concern (SVHC). Industrial users must comply with ATEX directives for explosive atmosphere prevention and occupational safety regulations for handling flammable gases in workplace environments.
Where to buy molecular hydrogen in Europe?
Molecular hydrogen is available through OYSI, a specialized European distributor of technical chemicals and industrial gases. As an established supplier in the European market, OYSI can provide molecular hydrogen in various purities and packaging options to meet specific industrial requirements. Contact OYSI directly for detailed product specifications, availability, and delivery options across European markets for your hydrogen gas supply needs.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.