Copper(1+) thiocyanate

CCuNS

copper(1+) thiocyanate

CAS1111-67-7
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
1111-67-7
EC Number
214-183-1
UN Number
3077
Index Number
029-015-00-0
PubChem CID
61264

Physical-chemical properties

Molecular Formula
CCuNS
Molar Mass
121.63 g/mol
IUPAC Name
copper(1+) thiocyanate

Chemical Identifiers

InChI
InChI=1S/CHNS.Cu/c2-1-3;/h3H;/q;+1/p-1
InChI Key
PDZKZMQQDCHTNF-UHFFFAOYSA-M

Overview

Copper(1+) thiocyanate (CAS 1111-67-7) is an inorganic copper salt with distinctive coordination chemistry and specialized industrial applications. This copper-based compound, also known by its EC number 214-183-1, represents an important member of the thiocyanate family of chemicals used across various industrial sectors. With its molecular formula CCuNS and molecular weight of 121.63 g/mol, copper(1+) thiocyanate exhibits unique properties that make it valuable for specific technical applications. The compound's copper center in the +1 oxidation state provides distinct reactivity patterns compared to more common copper(II) compounds. From a safety perspective, copper(1+) thiocyanate is classified under GHS as Aquatic Acute 1 and Aquatic Chronic 1, indicating significant environmental hazards to aquatic life both in short-term and long-term exposure scenarios. The compound carries a Warning signal word and displays the GHS09 pictogram, emphasizing its environmental impact concerns. For transportation purposes, it falls under ADR Class 9 (miscellaneous dangerous substances), requiring appropriate handling protocols during shipping and storage. Industrial applications of copper(1+) thiocyanate include use as a catalyst in organic synthesis reactions, as an analytical reagent in laboratory settings, and in specialized electroplating processes. The compound's unique coordination properties also make it valuable in research applications involving copper chemistry. While structurally different from complex organic compounds like N-benzyl-2-[4-fluoro-3-(trifluoromethyl)phenoxy]butanamide, copper(1+) thiocyanate serves complementary roles in industrial chemical processes where metal-based catalysts are preferred over organic alternatives. OYSI maintains reliable supply chains for copper(1+) thiocyanate to support European industrial customers requiring consistent quality and regulatory compliance.

Safety & Classification

Warning
Classification:

Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameKupfer(I)-thiocyanat
Marine PollutantNo

Frequently Asked Questions

What is copper(1+) thiocyanate?

Copper(1+) thiocyanate is an inorganic chemical compound with the molecular formula CCuNS and CAS number 1111-67-7. This copper salt of thiocyanic acid has a molecular weight of 121.63 g/mol and belongs to the family of metal thiocyanates. It is classified as hazardous to aquatic environments and requires careful handling due to its environmental impact potential.

What are the physicochemical properties of copper(1+) thiocyanate?

Copper(1+) thiocyanate typically appears as a white to pale yellow crystalline solid at room temperature. The compound is relatively stable under normal conditions but may decompose when heated. Its solubility characteristics depend on the solvent used, with limited solubility in water. The molecular structure contains copper in the +1 oxidation state bonded to the thiocyanate group.

What is copper(1+) thiocyanate used for?

Copper(1+) thiocyanate is primarily used in analytical chemistry applications, particularly in colorimetric analysis and laboratory procedures. It serves as a reagent in chemical synthesis and can be employed in specialized industrial processes requiring copper thiocyanate compounds. The substance may also find applications in research and development activities within the chemical industry.

How to handle copper(1+) thiocyanate safely?

Copper(1+) thiocyanate requires careful handling with appropriate personal protective equipment including safety goggles, gloves, and protective clothing. Work should be conducted in well-ventilated areas or under fume extraction systems. Avoid direct contact with skin and eyes, and prevent inhalation of dust particles. The Warning signal word indicates moderate hazard levels requiring standard laboratory safety precautions.

How to store copper(1+) thiocyanate correctly?

Copper(1+) thiocyanate should be stored in tightly sealed containers in a cool, dry place away from direct sunlight and heat sources. Keep the substance in its original packaging and ensure proper labeling with hazard information. Storage areas should be well-ventilated and separated from incompatible materials. Regular inspection of containers for damage or deterioration is recommended.

What to do in case of contact with copper(1+) thiocyanate?

In case of skin contact with copper(1+) thiocyanate, immediately wash the affected area with plenty of water and soap. For eye contact, rinse thoroughly with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical assistance while providing safety data sheet information.

How to dispose of copper(1+) thiocyanate appropriately?

Copper(1+) thiocyanate must be disposed of according to local environmental regulations as hazardous waste due to its aquatic toxicity classification. Contact licensed waste disposal companies specializing in chemical waste management. Never dispose of the substance through regular waste streams or pour into drains. Packaging materials contaminated with the substance require similar hazardous waste treatment procedures.

How to transport copper(1+) thiocyanate?

Copper(1+) thiocyanate is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. This classification requires appropriate hazardous goods packaging, labeling, and documentation during transport. Shipments must comply with international dangerous goods regulations and be handled by certified dangerous goods transporters with proper training and equipment.

Is copper(1+) thiocyanate subject to specific regulations?

Copper(1+) thiocyanate is subject to CLP regulation requirements due to its aquatic toxicity classification (Aquatic Acute 1; Aquatic Chronic 1). The substance requires appropriate hazard labeling with GHS09 environmental pictogram and Warning signal word. While not listed as SVHC under REACH, suppliers must provide safety data sheets and comply with standard chemical registration requirements.

Where to buy copper(1+) thiocyanate in Europe?

Copper(1+) thiocyanate is available through OYSI, a European chemical distributor specializing in technical chemical products. OYSI provides reliable supply chains across Europe with proper documentation and regulatory compliance. Contact OYSI directly for availability, technical specifications, and delivery options to your specific European location while ensuring all transportation and handling requirements are met.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.