Copper(1+) thiocyanate

CCuNS

copper(1+) thiocyanate

CAS1111-67-7
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
1111-67-7
EC Number
214-183-1
UN Number
3077
Index Number
029-015-00-0
PubChem CID
61264

Physical-chemical properties

Molecular Formula
CCuNS
Molar Mass
121.63 g/mol
IUPAC Name
copper(1+) thiocyanate

Chemical Identifiers

InChI
InChI=1S/CHNS.Cu/c2-1-3;/h3H;/q;+1/p-1
InChI Key
PDZKZMQQDCHTNF-UHFFFAOYSA-M

Overview

Copper(1+) thiocyanate (CAS 1111-67-7) is an inorganic copper compound with notable aquatic toxicity and specialized industrial applications. This white to pale yellow crystalline compound represents an important member of the copper thiocyanate family, where copper exists in its +1 oxidation state. With the molecular formula CCuNS and a molecular weight of 121.63 g/mol, copper(1+) thiocyanate exhibits unique coordination chemistry properties that make it valuable in various industrial processes. The compound forms through the reaction of copper(I) salts with thiocyanate ions, resulting in a stable complex that demonstrates distinctive solubility characteristics in different solvents. From a safety perspective, copper(1+) thiocyanate carries significant environmental hazard classifications, specifically Aquatic Acute 1 and Aquatic Chronic 1, indicating both immediate and long-term toxicity to aquatic organisms. The compound displays the GHS09 environmental hazard pictogram with a "Warning" signal word, and is classified under ADR Class 9 for transport purposes. Proper handling requires consideration of its environmental impact and implementation of appropriate containment measures to prevent release into water systems. Industrial applications of copper(1+) thiocyanate include its use as a catalyst in organic synthesis reactions, particularly in copper-mediated coupling processes. The compound also finds application in analytical chemistry as a reagent for specific detection methods and in specialized electroplating formulations where controlled copper deposition is required. Unlike more complex compounds such as N-benzyl-2-[4-fluoro-3-(trifluoromethyl)phenoxy]butanamide used in pharmaceutical applications, copper(1+) thiocyanate serves primarily in inorganic synthesis and catalytic processes. OYSI supplies copper(1+) thiocyanate to meet the demanding requirements of European technical and research applications.

Safety & Classification

Warning
Classification:

Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameKupfer(I)-thiocyanat
Marine PollutantNo

Frequently Asked Questions

What is copper(1+) thiocyanate?

Copper(1+) thiocyanate is an inorganic chemical compound with the molecular formula CCuNS and CAS number 1111-67-7. This copper salt contains copper in its +1 oxidation state bound to thiocyanate ions. With a molecular weight of 121.63 g/mol, it appears as a crystalline solid and is classified as hazardous to aquatic environments, requiring careful handling in industrial applications.

What are the physicochemical properties of copper(1+) thiocyanate?

Copper(1+) thiocyanate is a solid crystalline compound at room temperature, typically appearing as white to pale yellow crystals. It has limited solubility in water but may dissolve in certain organic solvents. The compound is relatively stable under normal conditions but can decompose upon heating, releasing toxic gases including hydrogen cyanide and sulfur oxides.

What is copper(1+) thiocyanate used for?

Copper(1+) thiocyanate is primarily used in analytical chemistry as a reagent for detecting and quantifying various substances. It serves applications in electroplating processes, as a catalyst in organic synthesis reactions, and in specialized industrial processes requiring copper-thiocyanate chemistry. The compound is also utilized in research laboratories for chemical analysis and synthesis work.

How to handle copper(1+) thiocyanate safely?

Copper(1+) thiocyanate requires careful handling with appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and lab coats. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation. Avoid skin and eye contact, and never ingest the material. Emergency eyewash stations and safety showers should be readily accessible when working with this compound.

How to store copper(1+) thiocyanate correctly?

Copper(1+) thiocyanate should be stored in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep containers tightly sealed to prevent moisture absorption and contamination. Store separately from strong acids, bases, and oxidizing agents to prevent dangerous reactions. Ensure storage areas have appropriate spill containment measures due to its aquatic toxicity classification.

What to do in case of contact with copper(1+) thiocyanate?

Copper(1+) thiocyanate exposure requires immediate action depending on the route of contact. For skin contact, remove contaminated clothing and rinse affected areas with plenty of water for at least 15 minutes. If eye contact occurs, flush immediately with water and seek medical attention. In case of inhalation, move to fresh air immediately and consult medical personnel if symptoms develop.

How to dispose of copper(1+) thiocyanate appropriately?

Copper(1+) thiocyanate disposal must comply with local environmental regulations due to its aquatic toxicity classification under GHS09. The compound cannot be disposed of through regular waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies experienced in handling copper compounds and cyanide-containing materials for proper treatment and disposal according to regulatory requirements.

How to transport copper(1+) thiocyanate?

Copper(1+) thiocyanate is classified under ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. This classification requires appropriate packaging, labeling, and documentation during shipping. Packages must display proper hazard labels and shipping names, and transport vehicles need suitable safety equipment. Consult current ADR regulations for specific packaging and documentation requirements.

Is copper(1+) thiocyanate subject to particular regulations?

Copper(1+) thiocyanate is subject to various chemical regulations including REACH registration requirements in Europe and CLP classification standards. The compound is classified as Aquatic Acute 1 and Aquatic Chronic 1, requiring specific labeling with GHS09 pictograms and 'Warning' signal words. It is not currently listed as a Substance of Very High Concern (SVHC) under REACH regulations.

Where to buy copper(1+) thiocyanate in Europe?

Copper(1+) thiocyanate is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers across the continent. OYSI provides reliable supply chains, proper documentation, and regulatory compliance support for chemical procurement. Contact OYSI directly for availability, technical specifications, and pricing information tailored to your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.