Carbon monoxide;nickel

C4NiO4

carbon monoxide;nickel

CAS13463-39-3
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
13463-39-3
EC Number
236-669-2
UN Number
1259
Index Number
028-001-00-1
PubChem CID
26039

Physical-chemical properties

Molecular Formula
C4NiO4
Molar Mass
170.73 g/mol
IUPAC Name
carbon monoxide;nickel

Chemical Identifiers

InChI
InChI=1S/4CO.Ni/c4*1-2;
InChI Key
AWDHUGLHGCVIEG-UHFFFAOYSA-N

Overview

Carbon monoxide;nickel (CAS 13463-39-3) is a nickel carbonyl complex with highly toxic and flammable properties used in specialized industrial applications. This organometallic compound, also known by its EC number 236-669-2, represents a critical substance in industrial chemistry with significant safety considerations. With a molecular formula of C4NiO4 and molecular weight of 170.73 g/mol, carbon monoxide;nickel forms part of the nickel carbonyl family of compounds that exhibit unique catalytic and chemical properties. The substance presents multiple hazard classifications including flammable liquid category 2, carcinogenic category 2, reproductive toxicity category 1B, and acute toxicity category 2. Its danger signal word and associated GHS pictograms (GHS02, GHS08, GHS06, GHS09) reflect the serious health and environmental risks associated with handling this material. The compound falls under ADR transport class 6.1, emphasizing its toxic nature and requiring specialized shipping protocols. Safety management is paramount when working with carbon monoxide;nickel due to its carcinogenic and reproductive toxicity properties. Unlike simpler compounds such as (E)-but-2-enal, this organometallic substance requires sophisticated containment and handling procedures. The material also poses significant aquatic toxicity risks, classified as both acute and chronic category 1 for aquatic environments. Primary industrial applications include specialized catalytic processes, chemical synthesis intermediates, and research applications in organometallic chemistry. The compound's unique coordination chemistry makes it valuable in specific metallurgical processes and advanced materials development. OYSI maintains this specialized chemical product for qualified industrial customers requiring certified organometallic compounds for technical applications.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Carc. 2; Repr. 1B; Acute Tox. 2 *; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H351

Suspected of causing cancer.

H330

Fatal if inhaled.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1259
ADR Class6.1
Packing GroupI
Tunnel CodeC/D
Proper Shipping NameNickeltetracarbonyl
Marine PollutantNo

Frequently Asked Questions

What is carbon monoxide;nickel?

Carbon monoxide;nickel is a highly toxic organometallic compound with the formula C4NiO4 and molecular weight of 170.73 g/mol. This substance consists of nickel coordinated with carbon monoxide ligands, forming a volatile metal carbonyl complex. It appears as a colorless to pale yellow liquid or solid depending on conditions. The compound is extremely hazardous, classified as carcinogenic, reproductive toxicant, and acutely toxic, requiring strict safety protocols during handling and use.

What are the physicochemical properties of carbon monoxide;nickel?

Carbon monoxide;nickel exhibits properties typical of metal carbonyl compounds, being volatile and thermally unstable. The compound has a molecular formula of C4NiO4 with a molar mass of 170.73 g/mol. It is classified as a flammable liquid (category 2), indicating relatively low flash point and vapor pressure. The substance is likely to have limited water solubility but good solubility in organic solvents. Its volatility contributes significantly to its acute toxicity hazard profile.

What is carbon monoxide;nickel used for?

Carbon monoxide;nickel serves primarily as a catalyst in various industrial chemical processes, particularly in carbonylation reactions and organic synthesis. The compound is utilized in specialized metallurgical applications and as an intermediate in nickel refining processes. Due to its extreme toxicity and carcinogenic properties, its industrial use is strictly regulated and limited to controlled environments with appropriate safety measures. Professional applications require specialized expertise and comprehensive risk management protocols.

How to handle carbon monoxide;nickel safely?

Carbon monoxide;nickel requires extreme safety precautions due to its acute toxicity, carcinogenic, and reproductive hazards. Personnel must wear full protective equipment including respiratory protection, chemical-resistant gloves, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Given its flammable nature, eliminate ignition sources and use explosion-proof equipment. Only trained professionals should handle this substance following strict safety protocols and emergency procedures.

How to store carbon monoxide;nickel correctly?

Carbon monoxide;nickel must be stored in a cool, dry, well-ventilated area away from heat sources, ignition sources, and incompatible materials. Use appropriate secondary containment and ensure containers are properly sealed to prevent vapor escape. Storage areas should have restricted access with appropriate hazard signage. The substance should be kept away from oxidizing agents and stored in compliance with local regulations for toxic and carcinogenic materials. Regular inspection of storage conditions and container integrity is essential.

What to do in case of contact with carbon monoxide;nickel?

Immediate action is critical due to the substance's acute toxicity. For skin contact, remove contaminated clothing and rinse thoroughly with water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek urgent medical attention. For eye contact, flush with clean water for at least 15 minutes. In all cases of exposure, obtain immediate medical attention and inform healthcare providers of the specific substance and its hazardous properties. Have safety data sheets readily available.

How to dispose of carbon monoxide;nickel appropriately?

Carbon monoxide;nickel disposal requires specialized hazardous waste management due to its toxic, carcinogenic, and environmental hazard classifications. The substance cannot be disposed of through normal waste streams and must be handled by licensed hazardous waste disposal companies. Follow local and European waste regulations including proper classification, packaging, and documentation. Consider recovery or recycling options for nickel content where feasible. Disposal must comply with environmental protection requirements given its aquatic toxicity classification.

How to transport carbon monoxide;nickel?

Carbon monoxide;nickel is classified under ADR Class 6.1 (toxic substances), Packing Group I, indicating maximum transport restrictions due to high toxicity. Transport requires specialized packaging, proper hazard labeling, and documentation including transport emergency cards. Only authorized carriers with appropriate permits can transport this substance. Vehicles must be equipped with appropriate safety equipment and emergency response materials. Compliance with international dangerous goods regulations is mandatory for cross-border transport within Europe.

Is carbon monoxide;nickel subject to specific regulations?

Carbon monoxide;nickel is subject to extensive regulatory oversight under European chemicals legislation including REACH registration requirements and CLP classification obligations. Due to its carcinogenic and reproductive toxicity properties, it may face restrictions on use and require authorization under REACH. The substance must comply with occupational exposure limits and workplace safety regulations. Although not currently listed as SVHC, its hazardous properties necessitate strict compliance with industrial emissions and environmental protection standards.

Where to buy carbon monoxide;nickel in Europe?

Carbon monoxide;nickel is available through specialized chemical distributors like OYSI, which serves the European market with technical-grade chemicals. Due to the substance's extreme hazards and regulatory requirements, purchase is typically restricted to qualified industrial users with appropriate safety infrastructure and permits. Suppliers must ensure proper classification, safety documentation, and compliance with transport regulations. Contact OYSI's technical team for availability, specifications, and regulatory guidance for this highly controlled substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.