4,4,5,5-tetrachloro-1,3-dioxolan-2-one
C3Cl4O3
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Identification
- CAS Number
- 22432-68-4
- EC Number
- 404-060-2
- UN Number
- 2927
- Index Number
- 602-075-00-0
- PubChem CID
- 2724978
Physical-chemical properties
- Molecular Formula
- C3Cl4O3
- Molar Mass
- 225.80 g/mol
- IUPAC Name
- 4,4,5,5-tetrachloro-1,3-dioxolan-2-one
Chemical Identifiers
- InChI
- InChI=1S/C3Cl4O3/c4-2(5)3(6,7)10-1(8)9-2
- InChI Key
- TXQPIYKVIOKFAB-UHFFFAOYSA-N
Overview
4,4,5,5-tetrachloro-1,3-dioxolan-2-one (CAS 22432-68-4) is a highly chlorinated cyclic carbonate compound with significant reactivity and acute toxicity properties. This specialized chemical compound represents an important member of the chlorinated cyclic carbonates family, featuring a unique five-membered ring structure with four chlorine substituents. The tetrachlorinated dioxolanone structure imparts distinctive chemical properties that make it valuable for specific industrial applications, particularly where controlled reactivity and selective chemical transformations are required. The compound's molecular formula C3Cl4O3 and molecular weight of 225.8 g/mol reflect its highly halogenated nature, which contributes to its enhanced reactivity profile compared to non-chlorinated analogues. This high degree of chlorination places it in a similar category to other reactive chlorinated compounds used in industrial synthesis, though with distinct advantages due to its cyclic carbonate functionality. Safety considerations are paramount when handling this material, as evidenced by its classification under Acute Tox. 2 and Skin Corr. 1B categories. The compound requires careful handling protocols due to its corrosive nature and acute toxicity potential, necessitating appropriate personal protective equipment and controlled storage conditions. Its ADR Class 6.1 classification reflects the serious nature of these hazards during transportation and storage. Primary industrial applications include its use as an intermediate in pharmaceutical synthesis, as a specialty reagent in polymer chemistry, and as a building block for advanced materials requiring specific chlorinated functionalities. Unlike simpler chlorinated compounds such as chloromethylbenzene, this dioxolanone offers unique reactivity patterns that enable selective chemical transformations. OYSI maintains reliable supply chains for 4,4,5,5-tetrachloro-1,3-dioxolan-2-one to support European industrial customers requiring this specialized chemical intermediate.
Safety & Classification
Acute Tox. 2 *; Acute Tox. 4 *; Skin Corr. 1B
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2927 |
| ADR Class | 6.1 |
| Packing Group | II |
| Tunnel Code | D/E |
| Proper Shipping Name | 4,4,5,5-Tetrachlor-1,3-dioxolan-2-on |
| Marine Pollutant | No |
Frequently Asked Questions
What is 4,4,5,5-tetrachloro-1,3-dioxolan-2-one?
4,4,5,5-tetrachloro-1,3-dioxolan-2-one is an organochlorine compound with the molecular formula C3Cl4O3 and CAS number 22432-68-4. This chemical belongs to the dioxolanone family, featuring a five-membered ring structure containing oxygen atoms and four chlorine substituents. With a molecular weight of 225.8 g/mol, it is classified as a highly hazardous substance requiring careful handling due to its acute toxicity and corrosive properties.
What are the physicochemical properties of 4,4,5,5-tetrachloro-1,3-dioxolan-2-one?
4,4,5,5-tetrachloro-1,3-dioxolan-2-one is a chlorinated organic compound with significant molecular weight due to its four chlorine atoms. The presence of multiple electronegative chlorine atoms and the cyclic structure with oxygen heteroatoms influences its physical properties. As a halogenated compound, it likely exhibits limited water solubility but good solubility in organic solvents. The exact physical state, color, and odor characteristics should be confirmed through technical documentation for specific applications.
What is 4,4,5,5-tetrachloro-1,3-dioxolan-2-one used for?
4,4,5,5-tetrachloro-1,3-dioxolan-2-one serves as a specialized chemical intermediate in organic synthesis and industrial applications. Its unique structure with multiple chlorine atoms and the dioxolanone ring makes it valuable for specific chemical transformations. Due to its hazardous classification, its use is typically restricted to professional industrial settings where proper safety measures can be implemented. Applications may include specialized synthesis processes requiring chlorinated intermediates.
How to handle 4,4,5,5-tetrachloro-1,3-dioxolan-2-one safely?
4,4,5,5-tetrachloro-1,3-dioxolan-2-one requires extreme caution due to its Acute Tox. 2, Acute Tox. 4, and Skin Corr. 1B classifications. Essential PPE includes chemical-resistant gloves, safety goggles, face shield, and protective clothing to prevent skin contact. Work must be conducted in well-ventilated areas or under fume hoods to avoid inhalation. Emergency eyewash stations and safety showers should be readily accessible, and personnel must be trained in emergency procedures.
How to store 4,4,5,5-tetrachloro-1,3-dioxolan-2-one correctly?
4,4,5,5-tetrachloro-1,3-dioxolan-2-one must be stored in tightly sealed, chemically compatible containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Given its corrosive nature, storage containers should be resistant to chemical attack. The storage area should be equipped with appropriate containment measures and restricted to authorized personnel only. Regular container inspections are essential to prevent leakage and ensure containment integrity.
What to do in case of contact with 4,4,5,5-tetrachloro-1,3-dioxolan-2-one?
Immediate action is critical due to the substance's acute toxicity and corrosive properties. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water for at least 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting. Seek immediate medical attention in all cases and provide safety data sheet to medical personnel.
How to dispose of 4,4,5,5-tetrachloro-1,3-dioxolan-2-one appropriately?
4,4,5,5-tetrachloro-1,3-dioxolan-2-one disposal must comply with local, national, and EU hazardous waste regulations due to its toxic and corrosive classification. The substance requires treatment as hazardous waste and must be disposed of through licensed hazardous waste management facilities. Incineration at high temperatures in approved facilities may be suitable, but thermal destruction parameters must account for chlorine content to prevent formation of hazardous combustion products.
How to transport 4,4,5,5-tetrachloro-1,3-dioxolan-2-one?
4,4,5,5-tetrachloro-1,3-dioxolan-2-one is classified as ADR Class 6.1 (toxic substances), Packing Group II, indicating significant transport hazards. Transportation requires UN-approved packaging suitable for toxic substances, proper hazard labeling with GHS06 and GHS05 pictograms, and appropriate shipping documentation. Drivers must hold ADR certification for Class 6.1 substances. Emergency response information must accompany shipments, and transport vehicles require appropriate placarding and emergency equipment.
Is 4,4,5,5-tetrachloro-1,3-dioxolan-2-one subject to specific regulations?
4,4,5,5-tetrachloro-1,3-dioxolan-2-one is subject to comprehensive EU chemical regulations including REACH registration requirements and CLP classification obligations. While not currently identified as an SVHC substance, its Acute Tox. 2 and Skin Corr. 1B classifications impose strict handling, labeling, and safety data sheet requirements. Users must ensure compliance with occupational exposure limits, transport regulations (ADR), and waste disposal directives applicable to toxic and corrosive substances.
Where to buy 4,4,5,5-tetrachloro-1,3-dioxolan-2-one in Europe?
4,4,5,5-tetrachloro-1,3-dioxolan-2-one is available through OYSI, a specialized European distributor of technical chemicals. As a highly hazardous substance, procurement is typically restricted to qualified industrial users who can demonstrate appropriate handling capabilities and regulatory compliance. OYSI provides technical support and ensures proper documentation including safety data sheets and certificates of analysis. Contact OYSI directly to discuss specific requirements, quantities, and delivery options for this specialized chemical.
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4,4,5,5-tetrachloro-1,3-dioxolan-2-one is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.