Octadecan-1-amine

C18H39N

octadecan-1-amine

CAS124-30-1
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
124-30-1
EC Number
204-695-3
UN Number
3077
Index Number
612-282-00-8
PubChem CID
15793

Physical-chemical properties

Molecular Formula
C18H39N
Molar Mass
269.50 g/mol
IUPAC Name
octadecan-1-amine

Chemical Identifiers

InChI
InChI=1S/C18H39N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h2-19H2,1H3
InChI Key
REYJJPSVUYRZGE-UHFFFAOYSA-N

Overview

Octadecan-1-amine (CAS 124-30-1) is a long-chain primary aliphatic amine with surfactant and corrosion inhibition properties. This eighteen-carbon primary amine represents a significant member of the fatty amine family, characterized by its linear alkyl chain structure and terminal amino group. The compound exhibits typical properties of long-chain aliphatic amines, including surface-active behavior, emulsification capabilities, and strong basicity. Its substantial molecular weight of 269.5 g/mol and hydrophobic alkyl backbone contribute to its unique amphiphilic nature, making it valuable in various industrial formulations. From a safety perspective, octadecan-1-amine requires careful handling due to its classification under multiple hazard categories. The compound presents risks including skin irritation, serious eye damage, and potential long-term organ effects. Its environmental impact is notable, with acute and chronic aquatic toxicity classifications requiring appropriate containment and disposal measures. The substance falls under ADR Class 9 for transportation, indicating miscellaneous dangerous goods classification. Key industrial applications include its use as a corrosion inhibitor in metalworking fluids and oil field chemicals, where its long alkyl chain provides excellent film-forming properties on metal surfaces. The compound also serves as an intermediate in the synthesis of quaternary ammonium compounds and specialty surfactants. In flotation processes, octadecan-1-amine functions as a collector agent for mineral processing operations. Unlike structurally different compounds such as benzene-1,4-diol or complex esters like (1R,2S,5R)-5-methyl-2-propan-2-ylcyclohexyl 2,2-dihydroxyacetate, octadecan-1-amine's linear structure provides distinct performance characteristics in surface modification applications. OYSI maintains reliable supply chains for octadecan-1-amine, supporting European customers with technical-grade material for industrial applications.

Safety & Classification

Danger
Classification:

Asp. Tox. 1; STOT RE 2; Skin Irrit. 2; Eye Dam. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H304

May be fatal if swallowed and enters airways.

H373

May cause damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameOctadecylamin
Marine PollutantNo

Frequently Asked Questions

What is octadecan-1-amine?

Octadecan-1-amine is a long-chain primary aliphatic amine with the molecular formula C18H39N and CAS number 124-30-1. This organic compound has a molecular weight of 269.5 g/mol and consists of an 18-carbon alkyl chain terminated with an amino group. It belongs to the fatty amine family and is classified as a hazardous substance with multiple safety concerns including eye damage, skin irritation, and aquatic toxicity.

What are the physicochemical properties of octadecan-1-amine?

Octadecan-1-amine is typically a waxy solid at room temperature due to its long hydrocarbon chain structure. It appears as a white to off-white crystalline or waxy material with a characteristic amine odor. The compound has limited solubility in water due to its hydrophobic alkyl chain but dissolves well in organic solvents. Its melting point is relatively high due to intermolecular hydrogen bonding between amine groups.

What is octadecan-1-amine used for?

Octadecan-1-amine is primarily used as a surfactant and emulsifier in various industrial applications. It serves as an intermediate in the production of quaternary ammonium compounds, corrosion inhibitors, and fabric softeners. The compound is also utilized in the manufacture of flotation agents for mineral processing, antistatic agents, and as a raw material for producing specialty chemicals in pharmaceutical and cosmetic industries.

How to handle octadecan-1-amine safely?

Octadecan-1-amine requires careful handling due to its classification as Danger with multiple hazard classes. Always wear appropriate PPE including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas or use local exhaust ventilation to minimize inhalation exposure. Avoid generating dust or vapors, and ensure emergency eyewash stations and safety showers are readily accessible.

How to store octadecan-1-amine correctly?

Octadecan-1-amine should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and store separately from incompatible materials such as strong acids, oxidizing agents, and reactive metals. Use original containers or compatible materials resistant to amines. Maintain storage temperature below 25°C to prevent degradation and ensure proper containment to prevent environmental release.

What to do in case of contact with octadecan-1-amine?

Octadecan-1-amine contact requires immediate action due to its eye damage and skin irritation potential. For eye contact, rinse immediately with plenty of water for at least 15 minutes and seek medical attention urgently. If skin contact occurs, wash thoroughly with soap and water. In case of inhalation, move to fresh air immediately. For ingestion, do not induce vomiting and seek medical advice. Always consult safety data sheets for complete first aid procedures.

How to dispose of octadecan-1-amine appropriately?

Octadecan-1-amine disposal must comply with local and national waste regulations due to its hazardous classification. The compound cannot be disposed of in regular waste streams and requires treatment as hazardous chemical waste. Contact licensed waste disposal companies for proper handling and disposal. Small quantities may be neutralized under controlled conditions, but incineration at approved facilities is typically the preferred method. Prevent environmental release due to its aquatic toxicity.

How to transport octadecan-1-amine?

Octadecan-1-amine is classified under ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation. Packages must be properly labeled with appropriate hazard markings and transported according to dangerous goods regulations. Use UN-approved packaging suitable for Class 9 materials and ensure proper documentation including transport documents and emergency response information. Drivers must have appropriate dangerous goods training certification.

Is octadecan-1-amine subject to particular regulations?

Octadecan-1-amine is subject to various European regulations including REACH registration requirements and CLP classification as a hazardous substance. It is not currently listed as an SVHC (Substance of Very High Concern). Users must comply with occupational health and safety regulations, environmental protection laws, and proper hazard communication requirements. Industrial users may need to implement risk management measures and report usage under REACH obligations.

Where to buy octadecan-1-amine in Europe?

Octadecan-1-amine is available through OYSI, a European distributor of technical chemicals serving industrial customers across Europe. As a specialized chemical distributor, OYSI provides quality products with proper documentation including safety data sheets and certificates of analysis. The compound is typically available in various packaging sizes to meet different industrial requirements. Contact OYSI directly for availability, specifications, and technical support for your specific applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.