Borane
B2H6
borane
Consulting for Borane
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Identification
- CAS Number
- 19287-45-7
- EC Number
- 242-940-6
- UN Number
- 1911
- PubChem CID
- 12544637
Physical-chemical properties
- Molecular Formula
- B2H6
- Molar Mass
- 27.67 g/mol
- IUPAC Name
- borane
Chemical Identifiers
- InChI
- InChI=1S/2BH3/h2*1H3
- InChI Key
- NTJHUEGHVSASEP-UHFFFAOYSA-N
Overview
Borane (CAS 19287-45-7) is a highly reactive boron hydride compound with the molecular formula B2H6, characterized by its exceptional reducing properties and pyrophoric nature. This colorless, toxic gas represents one of the most important boron-containing compounds in industrial chemistry, serving as a fundamental building block for numerous synthetic processes. With a molecular weight of 27.67 g/mol, borane exists primarily as diborane (B2H6) under normal conditions, featuring a unique bridged molecular structure that distinguishes it from conventional hydrides. The compound exhibits remarkable chemical reactivity, particularly as a powerful reducing agent and hydroboration catalyst. Borane demonstrates extreme sensitivity to air and moisture, igniting spontaneously upon contact with oxygen, which necessitates careful handling under inert atmospheric conditions. Its classification under ADR Class 2 reflects its gaseous nature and associated transport hazards. Unlike related compounds such as nitrous oxide, which serves primarily as an oxidizing agent, borane functions exclusively as a reducing species in chemical reactions. The compound finds extensive application in organic synthesis, particularly in hydroboration reactions for alkene functionalization and the preparation of organoborane intermediates. Pharmaceutical and fine chemical manufacturers utilize borane for selective reductions of carbonyl compounds and the synthesis of complex molecular frameworks. Additionally, the semiconductor industry employs borane as a doping agent in the production of specialized electronic materials. Borane's unique reactivity profile, while similar to other reactive hydrides like iodane in terms of handling requirements, offers distinct synthetic advantages in controlled chemical environments. OYSI maintains reliable supply chains for borane and related specialty chemicals, supporting diverse industrial applications across Europe with appropriate safety protocols and technical expertise.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 1911 |
| ADR Class | 2 |
| Packing Group | |
| Tunnel Code | D |
| Proper Shipping Name | Diboran, unter Druck verflüssigt |
| Marine Pollutant | No |
Frequently Asked Questions
What is borane?
Borane is a chemical compound with the molecular formula B2H6, also known as diborane. This compound consists of two boron atoms bonded to six hydrogen atoms, forming a unique electron-deficient structure. With a molecular weight of 27.67 g/mol and CAS number 19287-45-7, borane is the simplest boron hydride compound and serves as an important reagent in synthetic chemistry and industrial applications.
What are the physicochemical properties of borane?
Borane (B2H6) is a colorless gas at room temperature with a sweet, sickly odor. It has a molecular weight of 27.67 g/mol and is highly reactive due to its electron-deficient structure. The compound is pyrophoric, meaning it ignites spontaneously in air, and reacts violently with water. Borane is soluble in organic solvents but decomposes in polar protic solvents, making it unstable under ambient conditions.
What is borane used for?
Borane is primarily used as a powerful reducing agent in organic synthesis and pharmaceutical manufacturing. It serves as a key reagent in hydroboration reactions for alkene functionalization and in the reduction of carbonyl compounds. Industrial applications include semiconductor manufacturing, where it acts as a dopant source, and in the production of advanced materials. Borane is also utilized in research laboratories for specialized synthetic transformations.
How to handle borane safely?
Borane must be handled under strictly controlled conditions due to its pyrophoric nature. Work should be conducted in an inert atmosphere using specialized glove boxes or Schlenk techniques. Essential PPE includes chemical-resistant gloves, safety goggles, and flame-resistant laboratory coats. Handle only in well-ventilated areas away from ignition sources, moisture, and incompatible materials. Emergency fire suppression equipment should be readily available during handling operations.
How to store borane correctly?
Borane requires storage under anhydrous, inert atmosphere conditions, typically in sealed containers under nitrogen or argon gas. Store in a cool, dry location away from heat sources, open flames, and moisture. The compound must be kept separate from oxidizing agents, water, alcohols, and other reactive materials. Use only approved containers designed for pyrophoric materials and ensure proper labeling and inventory management in specialized chemical storage areas.
What to do in case of contact with borane?
Borane exposure requires immediate emergency response due to its reactive nature. For skin contact, remove contaminated clothing and flush affected areas with copious amounts of water for at least 15 minutes. In case of inhalation, move the person to fresh air immediately and seek medical attention. For eye contact, rinse thoroughly with water and obtain immediate medical care. Never use water on borane fires - use appropriate dry chemical extinguishers instead.
How to dispose of borane appropriately?
Borane disposal must follow strict hazardous waste regulations due to its reactive properties. Small quantities should be carefully quenched using appropriate neutralizing agents under controlled conditions by trained personnel. Larger amounts require professional hazardous waste disposal services licensed to handle pyrophoric materials. Never dispose of borane in regular waste streams or sewers. Contact local environmental authorities for specific disposal requirements and approved waste management facilities.
How to transport borane?
Borane is classified under ADR Class 2 (gases) for transportation purposes, requiring specialized handling during shipping. The compound must be transported in approved pressure vessels designed for pyrophoric gases, with proper hazard labeling and documentation. Only authorized carriers experienced in handling dangerous goods should transport borane. Shipments require compliance with international dangerous goods regulations and may need special permits depending on quantity and destination.
Is borane subject to specific regulations?
Borane is regulated under various chemical safety frameworks including REACH registration requirements in Europe and similar chemical inventory systems globally. While not classified as an SVHC (Substance of Very High Concern), its reactive nature subjects it to strict handling and storage regulations. Users must comply with workplace safety standards, environmental protection laws, and transportation regulations. Regular safety assessments and proper documentation are mandatory for commercial use.
Where to buy borane in Europe?
Borane is available through specialized chemical distributors like OYSI, which serves the European market with high-quality chemical products. As a professional chemical distributor, OYSI can provide borane with proper documentation, safety data sheets, and regulatory compliance support. Due to its hazardous nature, borane is typically available only to qualified industrial users and research institutions with appropriate handling facilities and safety protocols in place.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.