Azanium 2,4,6-trinitrophenolate

C6H6N4O7

azanium 2,4,6-trinitrophenolate

CAS131-74-8

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Identification

CAS Number
131-74-8
EC Number
205-038-3
UN Number
0004
Index Number
609-010-00-5
PubChem CID
8577

Physical-chemical properties

Molecular Formula
C6H6N4O7
Molar Mass
246.13 g/mol
IUPAC Name
azanium 2,4,6-trinitrophenolate

Chemical Identifiers

InChI
InChI=1S/C6H3N3O7.H3N/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16;/h1-2,10H;1H3
InChI Key
PADMMUFPGNGRGI-UHFFFAOYSA-N

Overview

Azanium 2,4,6-trinitrophenolate (CAS 131-74-8) is an explosive organic compound characterized by its high nitrogen content and distinctive trinitrophenol structure. This chemical compound, also known by its EC number 205-038-3, represents a significant member of the nitroaromatic explosive family with the molecular formula C6H6N4O7 and a molecular weight of 246.13 g/mol. The substance consists of a phenolic ring system substituted with three nitro groups at positions 2, 4, and 6, combined with an ammonium cation, creating a salt structure that exhibits unique properties compared to its parent compound. The compound belongs to ADR Class 1, indicating its classification as an explosive material, which necessitates specialized handling, storage, and transportation protocols. Despite this classification, the substance demonstrates relatively stable characteristics under normal storage conditions when properly managed. Its chemical structure shares similarities with related nitroaromatic compounds such as 2,4,6-trinitrobenzoic acid, though the presence of the ammonium group significantly influences its physical and chemical behavior. Industrial applications for azanium 2,4,6-trinitrophenolate primarily focus on specialized sectors requiring controlled explosive properties, including mining operations and certain manufacturing processes where precise detonation characteristics are essential. The compound also finds use in research and development applications within the pyrotechnics industry, where its predictable explosive behavior makes it valuable for specific formulations. The substance's unique molecular structure and explosive properties require expertise in handling and application, making it suitable primarily for industrial users with appropriate safety infrastructure and regulatory compliance capabilities. OYSI maintains availability of azanium 2,4,6-trinitrophenolate for qualified industrial customers across Europe, ensuring proper documentation and compliance with all relevant safety regulations.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number0004
ADR Class1
Packing Group
Tunnel CodeB1000C
Proper Shipping NameAmmoniumpikrat, trocken, nicht pulverförmig
Marine PollutantNo

Frequently Asked Questions

What is azanium 2,4,6-trinitrophenolate?

Azanium 2,4,6-trinitrophenolate is the ammonium salt of picric acid, a highly nitrated aromatic compound with the molecular formula C6H6N4O7. This chemical substance has a molecular weight of 246.13 g/mol and is characterized by its explosive nature due to the presence of three nitro groups on the benzene ring. It is primarily known for its applications in specialized industrial processes where controlled explosive properties are required.

What are the physicochemical properties of azanium 2,4,6-trinitrophenolate?

Azanium 2,4,6-trinitrophenolate typically appears as yellow crystalline solid with a bitter taste. It is moderately soluble in water and more soluble in alcohol and acetone. The compound is sensitive to heat, friction, and impact due to its nitrated structure. It has a relatively high density and exhibits characteristic absorption in UV-visible spectroscopy due to the extended conjugated system of the trinitrophenol moiety.

What is azanium 2,4,6-trinitrophenolate used for?

Azanium 2,4,6-trinitrophenolate is primarily used in specialized industrial applications including explosive formulations, propellant manufacturing, and as a component in certain pyrotechnic compositions. It also serves as an intermediate in the synthesis of other nitrated compounds and can be used in analytical chemistry as a reagent. Due to its explosive nature, its applications are strictly controlled and limited to professional industrial settings with appropriate safety measures.

How to handle azanium 2,4,6-trinitrophenolate safely?

Safe handling of azanium 2,4,6-trinitrophenolate requires strict adherence to explosive material protocols including the use of anti-static equipment and clothing. Personnel must wear appropriate PPE including safety glasses, protective clothing, and work in well-ventilated areas away from heat sources, sparks, and static electricity. Only trained professionals should handle this material, and quantities should be minimized. All tools and surfaces must be grounded to prevent static discharge.

How to store azanium 2,4,6-trinitrophenolate correctly?

Azanium 2,4,6-trinitrophenolate must be stored in cool, dry conditions away from heat sources, direct sunlight, and incompatible materials. Storage areas should be equipped with explosion-proof electrical equipment and adequate ventilation. The compound should be kept in appropriate containers designed for explosive materials, separated from oxidizers, reducing agents, and organic materials. Regular inspection of storage conditions and container integrity is essential for safety.

What to do in case of contact with azanium 2,4,6-trinitrophenolate?

Immediate action for skin contact with azanium 2,4,6-trinitrophenolate includes removing contaminated clothing and flushing affected areas with plenty of water for at least 15 minutes. For eye contact, rinse thoroughly with clean water and seek immediate medical attention. In case of inhalation, move the person to fresh air immediately. Due to the compound's toxic and explosive nature, medical consultation should be sought promptly in all cases of exposure, even if symptoms are not immediately apparent.

How to dispose of azanium 2,4,6-trinitrophenolate appropriately?

Disposal of azanium 2,4,6-trinitrophenolate must be conducted through specialized hazardous waste disposal companies licensed to handle explosive materials. The compound cannot be disposed of through normal waste streams and requires controlled destruction methods such as controlled detonation or specialized incineration facilities. All disposal activities must comply with local, national, and international regulations governing explosive materials and hazardous waste management.

How to transport azanium 2,4,6-trinitrophenolate?

Transportation of azanium 2,4,6-trinitrophenolate falls under ADR Class 1 (Explosives) regulations, requiring specialized packaging, labeling, and documentation. Transport must be conducted by certified carriers with appropriate licenses for explosive materials. Vehicles must be equipped with proper safety equipment and follow designated routes. All transport documentation must clearly identify the material as a Class 1 substance, and drivers must hold appropriate dangerous goods transport certifications.

Is azanium 2,4,6-trinitrophenolate subject to specific regulations?

Azanium 2,4,6-trinitrophenolate is subject to extensive regulations including REACH registration requirements, CLP classification obligations, and specific explosive materials legislation. It may require special permits for purchase, storage, and use depending on national regulations. The compound is not listed as an SVHC substance, but its explosive nature subjects it to strict controls under explosive materials directives and international treaties governing dangerous goods and dual-use chemicals.

Where to buy azanium 2,4,6-trinitrophenolate in Europe?

Azanium 2,4,6-trinitrophenolate is available through specialized chemical distributors like OYSI, which serves the European market with technical chemicals for professional applications. Due to its explosive classification, purchase requires appropriate licenses and permits, and buyers must demonstrate legitimate industrial use. OYSI provides comprehensive documentation and regulatory support to ensure compliant procurement and handling of this controlled substance for qualified industrial customers across Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.